Unlock instant, AI-driven research and patent intelligence for your innovation.

Polypropylene-based wrap film

a polypropylene and wrap film technology, applied in the direction of roughening, packaging, synthetic resin layered products, etc., can solve the problems of poor gas barrier properties of resins, insufficient adhesion performance of food packaging wrap films, inferior to the above-mentioned wrap films of vinylidene chloride copolymer resin families in terms of gas barrier properties and adhesion to containers, etc., to achieve the effect of improving gas barrier properties and adhesion

Inactive Publication Date: 2005-03-24
ASAHI KASEI CHEM CORP
View PDF3 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

is to provide a non-chlorine resin film useful as a packaging film, which is improved in gas barrier properties and adhesion even when a polypropylene resin poor in gas barrier properties and adhesion is used, and further takes ease of use into account, in order to solve such problems.

Problems solved by technology

The polyolefin resins such as the polypropylene resin are poor in gas barrier properties, and adhesion on surfaces of the films is also scarcely observed, so that adhesion performance indispensable as the food packaging wrap films is insufficient.
However, they have been inferior to the above-mentioned wrap films of the vinylidene chloride copolymer resin family in terms of gas barrier properties and adhesion to containers.
However, none of them provide satisfactory films.
However, the liquid polybutene is a liquid, so that mixing thereof with the polyolefin resin results in softening of the film to cause loss of anti-drape stiffness and stiffness.
Accordingly, when the film is cut, it becomes easy to cling to fingers or goods to be packaged, resulting in unavailability thereof as a packaging film.
However, this pursues good cutting properties, so that no softening agent is contained in the film.
In this technique, the problems of the softened film and difficulty in handling at the time when the film is cut have also been left.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polypropylene-based wrap film

Examples

Experimental program
Comparison scheme
Effect test

example 1

A polypropylene resin (Noblen W531D manufactured by Sumitomo Chemical Co., Ltd., a random copolymer of propylene-ethylene-butene, MFR=9 g / 10 min), a styrene-ethylene-butylene-styrene block copolymer resin (Tuftec L515 manufactured by Asahi Kasei Corporation) as a softening agent, and further a hydrogenated dicyclopentadiene petroleum resin (MARUKAREZ H925C manufactured by Maruzen Petrochemical Co., Ltd.) as an adhering agent were blended. The polypropylene resin and the softening agent were blended at a weight ratio of 80:20 and, to 100 parts by weight of the sum of them, the adhering agent was added at a ratio of 5 parts by weight. They were put into a blender, and sufficiently mixed at ordinary temperature for 5 minutes.

The mixed pellets were put into an extruder for surface layers of a multilayer extruder apparatus for three-kind five layers of surface layers, adhesive layers and an inner layers. Further, an acid-modified polypropylene adhesive resin (Admer QF570 manufactured ...

example 2

An 11-μm thick film was obtained in the same manner as with Example 1 with the exception that the same polypropylene resin and styrene-ethylene-butylene-styrene block copolymer resin as used in the resin composition of the surface layers of Example 1 were blended at a weight ratio of 95:5 and, per 100 parts by weight of the sum of them, a mineral oil (Smoil P70 manufactured by Matsumura Oil Co., Ltd.) was further added as a liquid adhering assistant, in addition to the adhering agent of Example 1, in an amount of 10 parts by weight. The physical properties of this film were measured. As a result, the film exhibited good performance as shown in Table 2.

example 3

An 11-μm thick film was obtained in the same manner as with Example 1 with the exception that a mineral oil (Smoil P70 manufactured by Matsumura Oil Co., Ltd.) was further added as a liquid adhering assistant to the resin composition of the surface layer of Example 1 in an amount of 5 parts by weight per 100 parts by weight of the sum of the polypropylene resin and the softening agent. The physical properties of this film were measured. As a result, the film exhibited good performance as shown in Table 2.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Percent by massaaaaaaaaaa
Percent by massaaaaaaaaaa
Percent by massaaaaaaaaaa
Login to View More

Abstract

An object of the invention is to provide a non-chlorine polypropylene wrap film excellent in adhesion, transparency, heat resistance, flexibility, gas barrier properties, touch and cutting properties, and disclosed is a polypropylene wrap film, a multilayer film having a tensile modulus of 200 to 1,000 MPa, containing at least a surface layer and an inner layer having a gas barrier resin, and being stretched into a twice or more length in a machine direction and / or a transverse direction, wherein in its multilayer constitution, the surface layer is constituted by a composition comprising, for example, a mixture of a polypropylene resin, a softening agent, an adhering agent and a liquid adhering assistant at a suitable mixing ratio, and the inner layer is constituted, for example, by an ethylene-vinyl alcohol copolymer resin.

Description

TECHNICAL FIELD The present invention relates to a film for packaging goods, etc., for example, a film used for a food packaging wrap at home. In particular, the invention relates to a polypropylene wrap film having gas barrier properties, and further excellent in adhesion, transparency, heat resistance, feel such as anti-drape stiffness and stiffness, etc. BACKGROUND ART When foods are stored in food business such as restaurants and food shops, and in the general home, and further, when foods are heated in microwave ovens, thin thermoplastic resin films have hitherto been used. Of these, food packaging wrap films of the vinylidene chloride copolymer resin family combine excellent properties such as moisture resistance, oxygen gas barrier properties, heat resistance, adhesion to containers, etc. and transparency, so that they are in heavy usage as food packaging wrap films. Further, in recent years, food packaging wrap films comprising non-chlorine resins have also variously been...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B32B27/08B32B27/32
CPCB32B27/08B32B27/32C08L23/10C08L23/142C08L23/20C08L53/02Y10S428/91C08L57/02C08L2666/02Y10T428/31913Y10T428/31917Y10T428/31928Y10T428/31931Y10T428/31935Y10T428/31938B32B27/18B32B27/306B32B2038/0028B32B2307/7242B32B2318/02B32B2323/10B32B2325/00B32B2439/70
Inventor IRIYA, MASARUNAKAO, TAKASHI
Owner ASAHI KASEI CHEM CORP