Polypropylene-based wrap film
a polypropylene and wrap film technology, applied in the direction of roughening, packaging, synthetic resin layered products, etc., can solve the problems of poor gas barrier properties of resins, insufficient adhesion performance of food packaging wrap films, inferior to the above-mentioned wrap films of vinylidene chloride copolymer resin families in terms of gas barrier properties and adhesion to containers, etc., to achieve the effect of improving gas barrier properties and adhesion
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example 1
A polypropylene resin (Noblen W531D manufactured by Sumitomo Chemical Co., Ltd., a random copolymer of propylene-ethylene-butene, MFR=9 g / 10 min), a styrene-ethylene-butylene-styrene block copolymer resin (Tuftec L515 manufactured by Asahi Kasei Corporation) as a softening agent, and further a hydrogenated dicyclopentadiene petroleum resin (MARUKAREZ H925C manufactured by Maruzen Petrochemical Co., Ltd.) as an adhering agent were blended. The polypropylene resin and the softening agent were blended at a weight ratio of 80:20 and, to 100 parts by weight of the sum of them, the adhering agent was added at a ratio of 5 parts by weight. They were put into a blender, and sufficiently mixed at ordinary temperature for 5 minutes.
The mixed pellets were put into an extruder for surface layers of a multilayer extruder apparatus for three-kind five layers of surface layers, adhesive layers and an inner layers. Further, an acid-modified polypropylene adhesive resin (Admer QF570 manufactured ...
example 2
An 11-μm thick film was obtained in the same manner as with Example 1 with the exception that the same polypropylene resin and styrene-ethylene-butylene-styrene block copolymer resin as used in the resin composition of the surface layers of Example 1 were blended at a weight ratio of 95:5 and, per 100 parts by weight of the sum of them, a mineral oil (Smoil P70 manufactured by Matsumura Oil Co., Ltd.) was further added as a liquid adhering assistant, in addition to the adhering agent of Example 1, in an amount of 10 parts by weight. The physical properties of this film were measured. As a result, the film exhibited good performance as shown in Table 2.
example 3
An 11-μm thick film was obtained in the same manner as with Example 1 with the exception that a mineral oil (Smoil P70 manufactured by Matsumura Oil Co., Ltd.) was further added as a liquid adhering assistant to the resin composition of the surface layer of Example 1 in an amount of 5 parts by weight per 100 parts by weight of the sum of the polypropylene resin and the softening agent. The physical properties of this film were measured. As a result, the film exhibited good performance as shown in Table 2.
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