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Method and compositions for decorating glass

a technology of vitreous articles and inks, applied in the field of vitreous articles with radiation curable inks, can solve the problems of increased potential for worker injury, high temperature ovens are expensive, and energy consumption is considered, and achieves the effects of easy stripping, excellent decorative effect, and cost competitiveness

Inactive Publication Date: 2005-05-26
DECO PATENTS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

"The invention is about a method for decorating vitreous articles using a special ink that can be applied and then removed using a process called stripping. The invention also includes a specific ink composition that contains a certain amount of acid and can be used for decorating vitreous articles. The technical effect of this invention is that it provides a way to create intricate designs on vitreous articles that can be easily removed without causing any damage."

Problems solved by technology

Second, ACL requires high temperature ovens for the baking step, which results in considerable energy usage and an increased potential for worker injury due to the high temperatures at which the process operates.
Moreover, the high temperature ovens are expensive, cumbersome pieces of equipment which re considerable floor space in factories.
For example, both paper labels and decals are expensive.
In addition, they are messy, and can easily come off upon exposure to water or other materials.
In addition, many of the adhesives used in decals become sticky when subjected to the bottle cleaning process, and cause machines, drains, etc. to be gummed up.
In addition, the method must be cost competitive when compared to paper labels and decals.

Method used

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  • Method and compositions for decorating glass
  • Method and compositions for decorating glass
  • Method and compositions for decorating glass

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0058] A white ink composition was made as follows:

gramswt %Dipentaerythritol pentaacrylate125.024.8Epoxy acrylate + tripropylene glycol acrylate227.026.8Aromatic acid methacrylate ½ ester5.05.0in ethoxylated trimethylolpropanetriacrylate3Beta carboxyethyl acrylate410.09.9Aromatic urethane acrylate with10.09.9polyacrylated polyol diluent5Titanium dioxide (pigment)17.016.9Irgacure 170063.03.0Gamma-isocyanotopropyltriethoxysilane70.50.53-methacryloxypropyl trimethoxysilane80.50.5Trimethoxysilylpropyldiethylene triamine90.50.5Fluorinated alkyl alkoxylate100.50.5BYK-033111.01.0Modaflow120.80.8

1SR399, Sartomer Company, Inc. (other polymerizable reactant)

2CN104, Sartomer Company, Inc. (other polymerizable reactant)

3SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)

4B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)

5EB-220, UCB Radcure Inc. (other polymerizable reactant)

6Ciba-Geigy Corp. Mixture of 25% by weight bis(2,6-dimethoxybenzoy...

example 2

[0060] A blue ink composition was made as follows:

gramswt %Dipentaerythritol pentaacrylate125.023.9Epoxy acrylate + tripropylene glycol acrylate227.025.8Aromatic acid methacrylate ½ ester5.04.8in ethoxylated trimethylolpropanetriacrylate3Beta carboxyethyl acrylate410.09.6Aromatic urethane acrylate with10.09.6polyacrylated polyol diluent5Ultramarine blue 50091320.019.1Irgazin blue X-3367141.00.9Irgacure 170063.02.9Gamma-isocyanotopropyltriethoxysilane70.50.53-methacryloxypropyl trimethoxysilane80.50.5Trimethoxysilylpropyldiethylene triamine90.50.5Fluorinated alkyl alkoxylate100.50.5BYK-033111.01.0Modaflow120.50.4

1SR399, Sartomer Company, Inc. (other polymerizable reactant)

2CN104, Sartomer Company, Inc. (other polymerizable reactant)

3SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)

4B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)

5EB-220, UCB Radcure Inc. (other polymerizable reactant)

6Ciba-Geigy Corp. Mixture of 25% by weight ...

example 3

[0062] A white ink composition was made as follows:

gramswt %Aromatic acid methacrylate ½ ester25.024.5in ethoxylated trimethylolpropanetriacrylateBeta carboxyethyl acrylate235.034.2Monofunctional acrylate resin315.014.7Epoxy acrylate + tripropylene glycol acrylate45.04.9Titanium dioxide15.014.7Iragacure 170053.02.9BYK-03361.01.03-methacryloxypropyl trimethoxysilane70.60.6Gamma-isocyanotopropyltriethoxysilane80.60.6Methyl diethanolamine2.01.9

1SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)

2B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)

3Aromatic oligomer containing pendant carboxy functional groups, Henkel Corporation (polymerizable reactant with free acid group)

4CN104, Sartomer Company, Inc. (other polymerizable reactant)

5Ciba-Geigy Corp. Mixture of 25% by weight bis(2,6-dimethoxybenzpyl)-2,4-,4-trimethylpentyl phosphine oxide and 75% by weight 2-hydroxy-2-methyl-1-phenyl-propan-1-one. (photoinitiator)

6BYK-Chemie, A mixtur...

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Abstract

A method for decorating a vitreous article, in particular, a glass substrate, comprising applying to the glass in a predetermined design a radiation curable ink composition which is (i) operable when cured to bond to glass, and (ii) strippable from the glass upon exposure to alkali, and curing the ink on the glass by exposing it to the radiation by which it is curable, thereby bonding the ink to the glass; and related compositions; as well as a method for stripping the decorative indicia from glass upon exposure to alkali, and the related compositions.

Description

[0001] This application is a continuation-in-part of copending U.S. Patent Application Case Docket No. Rev 97-2, filed May 23, 1997, entitled “Method and Compositions For Decorating Glass”, by inventors Melvin Edwin Kamen, and Ming Hu, for which a U.S. patent application Ser. No. ______ is not yet available.TECHNICAL FIELD [0002] The invention is in the field of decorating vitreous articles with radiation curable inks. In particular, the invention relates to decoration of vitreous articles such as glass, with radiation curable inks which, to facilitate recycling, are capable of being chemically removed from the glass upon exposure to alkali for a ed period of time. BACKGROUND OF THE INVENTION [0003] Commercial ceramic and glassware is often decorated by applying a pattern in colored ink on the surface of the substrate with screen printing, offset printing, or any other direct application technique. The glass is then baked at high temperature to bond the design or indicia to the glas...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C03C17/00C03C17/32C09D11/10
CPCB41M1/34B41M7/0081B41M7/009C09D11/101C03C17/32C03C2217/485C03C2218/355C03C17/007
Inventor KAMEN, MELVIN EDWINHU, MING
Owner DECO PATENTS INC