Method and compositions for decorating glass
a technology of vitreous articles and inks, applied in the field of vitreous articles with radiation curable inks, can solve the problems of increased potential for worker injury, high temperature ovens are expensive, and energy consumption is considered, and achieves the effects of easy stripping, excellent decorative effect, and cost competitiveness
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example 1
[0058] A white ink composition was made as follows:
gramswt %Dipentaerythritol pentaacrylate125.024.8Epoxy acrylate + tripropylene glycol acrylate227.026.8Aromatic acid methacrylate ½ ester5.05.0in ethoxylated trimethylolpropanetriacrylate3Beta carboxyethyl acrylate410.09.9Aromatic urethane acrylate with10.09.9polyacrylated polyol diluent5Titanium dioxide (pigment)17.016.9Irgacure 170063.03.0Gamma-isocyanotopropyltriethoxysilane70.50.53-methacryloxypropyl trimethoxysilane80.50.5Trimethoxysilylpropyldiethylene triamine90.50.5Fluorinated alkyl alkoxylate100.50.5BYK-033111.01.0Modaflow120.80.8
1SR399, Sartomer Company, Inc. (other polymerizable reactant)
2CN104, Sartomer Company, Inc. (other polymerizable reactant)
3SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)
4B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)
5EB-220, UCB Radcure Inc. (other polymerizable reactant)
6Ciba-Geigy Corp. Mixture of 25% by weight bis(2,6-dimethoxybenzoy...
example 2
[0060] A blue ink composition was made as follows:
gramswt %Dipentaerythritol pentaacrylate125.023.9Epoxy acrylate + tripropylene glycol acrylate227.025.8Aromatic acid methacrylate ½ ester5.04.8in ethoxylated trimethylolpropanetriacrylate3Beta carboxyethyl acrylate410.09.6Aromatic urethane acrylate with10.09.6polyacrylated polyol diluent5Ultramarine blue 50091320.019.1Irgazin blue X-3367141.00.9Irgacure 170063.02.9Gamma-isocyanotopropyltriethoxysilane70.50.53-methacryloxypropyl trimethoxysilane80.50.5Trimethoxysilylpropyldiethylene triamine90.50.5Fluorinated alkyl alkoxylate100.50.5BYK-033111.01.0Modaflow120.50.4
1SR399, Sartomer Company, Inc. (other polymerizable reactant)
2CN104, Sartomer Company, Inc. (other polymerizable reactant)
3SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)
4B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)
5EB-220, UCB Radcure Inc. (other polymerizable reactant)
6Ciba-Geigy Corp. Mixture of 25% by weight ...
example 3
[0062] A white ink composition was made as follows:
gramswt %Aromatic acid methacrylate ½ ester25.024.5in ethoxylated trimethylolpropanetriacrylateBeta carboxyethyl acrylate235.034.2Monofunctional acrylate resin315.014.7Epoxy acrylate + tripropylene glycol acrylate45.04.9Titanium dioxide15.014.7Iragacure 170053.02.9BYK-03361.01.03-methacryloxypropyl trimethoxysilane70.60.6Gamma-isocyanotopropyltriethoxysilane80.60.6Methyl diethanolamine2.01.9
1SB500 E50, Sartomer Company, Inc. (polymerizable reactant with free acid group)
2B-CEA, UCB Radcure Inc. (polymerizable reactant with free acid group)
3Aromatic oligomer containing pendant carboxy functional groups, Henkel Corporation (polymerizable reactant with free acid group)
4CN104, Sartomer Company, Inc. (other polymerizable reactant)
5Ciba-Geigy Corp. Mixture of 25% by weight bis(2,6-dimethoxybenzpyl)-2,4-,4-trimethylpentyl phosphine oxide and 75% by weight 2-hydroxy-2-methyl-1-phenyl-propan-1-one. (photoinitiator)
6BYK-Chemie, A mixtur...
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