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Non-toxic primer powder composition for small caliber ammunition

a primer powder and composition technology, applied in the direction of explosives, instruments, sport apparatus, etc., can solve the problems of environmental hazards, dust-containing, harming the shooter,

Inactive Publication Date: 2005-10-13
POONGSAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a non-toxic primer powder composition for small caliber ammunition that does not generate heavy metal oxides upon ignition of the primer powder composition when bullet firing. The composition includes a shellac-coated potassium nitrate as an oxidizer, an initiating explosive, nitrate ester as a fuel, a shellac-coated potassium nitrate as an oxidizer, tetracene as a first sensitizer, borosilicate powder as a second sensitizer, and a chemical binder. The composition addresses the problems of conventional non-toxic primer powder compositions, such as generation of hazardous oxide-containing flying dust and corrosion in the gun, and also improves the lowered sensitivity and performance problems of a primer due to hygroscopicity of potassium nitrate. The technical effect of the invention is to provide a safer and more effective primer powder composition for small caliber ammunition.

Problems solved by technology

However, those conventional compositions have problems of, when the primer powder composition is detonated, generation of hazardous oxide-containing flying dust such as lead oxide (PbO) due to oxidation of lead styphnate, antimony oxide (Sb2O3) due to oxidation of antimony sulfide, barium oxide (BaO) due to reduction of barium nitrate.
Such oxide-containing flying dust is a toxic material, which is taken and accumulated in the human body, thus to disturb the human body function, thereby being very harmful to a shooter, particularly in indoor shooting ranges.
The oxide-containing dust also causes environmental hazards.
Regarding the toxic problem, there is a registered Korean Patent concerning a non-toxic primer powder composition, however, it has problems such that a lot of sparks are generated when firing, thereby being dangerous, and a corrosive salt, potassium chloride (KCl) is accumulated to the gun, thereby causing corrosion in the gun.
U.S. Pat. No. 5,417,160 disclose a use of potassium nitrate instead of barium nitrate, in order to prevent the generation of such hazardous oxide compounds; however it has a problem such that the sensitivity and performance of the primer is lowered, due to hygroscopicity of potassium nitrate (water solubility of 31.6 g / 100 ml, at 20□), which is a property of absorbing moisture in the air.
Another U.S. Pat. No. 6,620,267 disclose a technique of coating potassium nitrate with an insoluble material, nitrocellulose, in order to solve the problem of hygroscopicity of potassium nitrate; however, it does not sufficiently overcome said hygroscopicity problem of potassium nitrate and also has a risk of explosion of nitrocellulose which can be caused by any impact or abrasion, thereby having a serious problem in safety during working.

Method used

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  • Non-toxic primer powder composition for small caliber ammunition
  • Non-toxic primer powder composition for small caliber ammunition
  • Non-toxic primer powder composition for small caliber ammunition

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0036] On a dry basis, 30 wt % of DDNP and 7.5 wt % of tetracene was mixed together, to the resulted mixture, 37.5 wt % of a shellac-coated potassium nitrate and 17 wt % of nitrate ester were added and mixed, and then thereto 7.8 wt % of a borosilicate powder and 0.2 wt % of a chemical binder which is a mixture of arabian gum, tragacanth and gelatin with a mixing ratio of 9:5:1 were added and mixed thoroughly, in a mixer.

[0037] The shellac-coated potassium nitrate was prepared by adding 2 liter of ethyl alcohol to 1 kg of dried potassium nitrate to wet, adding 80 ml of a shellac resin solution, stirring the mixture sufficiently for one hour or more, allowing to stand it for 12 hours or more, removing the excessive ethyl alcohol, drying and sieving the resulted product.

[0038] The resulted mixture, as a primer powder, was charged into a cup (40) represented in FIG. 1, sealed with a foiling paper (20) and compressed. The cup (40) charged with the primer powder (30) was coupled with a...

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Abstract

The present invention relates to a non-toxic primer powder composition for small caliber ammunition characterized by comprising potassium nitrate coated with shellac as an oxidizer, and particularly characterized by comprising 25-40 wt % of an initiating explosive, 10-30 wt % of nitrate ester as a fuel, 32-40 wt % of a shellac-coated potassium nitrate (KNO3) as an oxidizer, 5-10 wt % of tetracene as a first sensitizer, 3-9 wt % of a borosilicate powder as a second sensitizer and 0.1-0.2 wt % of a chemical binder.

Description

TECHNICAL FIELD [0001] The present invention relates to a non-toxic primer powder composition for small caliber ammunition characterized by comprising potassium nitrate coated with shellac as an oxidizer, and particularly characterized by comprising an initiating explosive, nitrate ester as a fuel, a shellac-coated potassium nitrate (KNO3) as an oxidizer, tetracene as a first sensitizer, a borosilicate powder as a second sensitizer and a chemical binder. BACKGROUND ART [0002] A primer powder composition is generally comprised of an initiating explosive, a fuel, an oxidizer, a sensitizer and a chemical binder. Reviewing each function of said components, the initiating explosive initiates detonation of the primer powder by impact caused by a stroke of a hammer; the fuel generates flame by which a propellant can be combusted, in which the combustion is initiated by the detonation of the initiating explosive; the oxidizer provides oxygen required for combustion of the fuel, i.e.2 serves...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C06B35/00C06B45/32C06C7/00
CPCC06B45/32C06C7/00A63F13/24G06F3/021G06F3/0312G06F3/0676H04R1/028
Inventor JUNG, SUNG MOLEESON, JONG WOOPAK, CHANG HO
Owner POONGSAN CO LTD
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