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Precursor compositions for the deposition of electrically conductive features

a technology of precursor compositions and features, applied in the direction of conductive pattern formation, liquid/solution decomposition chemical coating, conductors, etc., can solve the problems of poor reliability and performance, low reliability, and low performance of existing thick film conductor compositions, and achieve the effect of reducing the number of layers

Inactive Publication Date: 2006-03-02
CABOT CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention is about a method for depositing conductive features onto a surface using precursor compositions that can be thick-film deposited. These compositions have a low decomposition temperature, making them suitable for use on a variety of substrates, including organic substrates. The compositions can include various combinations of molecular metal precursors, solvents, micron-sized particles, nanoparticles, vehicles, reducing agents, and other additives. The precursor compositions can be deposited onto a substrate and reacted to form highly conductive features with good electrical and mechanical properties. The conductive features formed according to the present invention have good electrical properties, such as a resistivity not greater than 20 times the resistivity of the bulk conductor. The method also uses low processing temperatures and short heating times.

Problems solved by technology

Existing thick film conductor compositions cannot provide this combination of features.
These pastes provide processing temperatures close to 100° C., but offer poor reliability and performance.
Thin film techniques offer high reliability and high performance, but have a high cost and provide limited materials and geometries.
Paste compositions including conductor particles that must be sintered require firing temperatures of 600° C. or higher, limiting their application to glass or ceramic substrates.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 3

[0249] A mixture of 1.7 grams terpineol and 1.7 grams silver trifluoroacetate was formed, corresponding to 0.69 moles of precursor to one mole of precursor. The mixture was subjected to TGA analysis, which showed that the mixture converted to substantially pure silver at 175° C. This mixture has a conversion temperature of 175° C. The molar ratio of salt to terpineol is 0.69 moles of salt to one mole of terpineol. This example illustrates a correct ratio of inducing agent to precursor.

example 5 (

Preferred Additive)

[0251] A mixture was formulated containing 44 grams Ag-trifluoroacetate, 22 grams H2O, 33 grams DEGBE and 1 part by weight lactic acid. The calculated silver content was 21.5 wt. % and thermogravimetric analysis showed the mass loss reached 79 wt. % at 215° C. The addition of DEGBE advantageously reduced the decomposition temperature by 125° C. compared to the formulation as described in Example 4. The lactic acid functions as a crystallization inhibitor.

example 8

[0254] A mixture was formulated containing 51 grams Ag-trifluoroacetate, 16 grams DMAc and 32 grams alpha terpineol. The calculated silver content was 25 wt. %. Thermogravimetric analysis showed a mass loss of 77 wt. % at 205° C. This decomposition temperature is decreased by 70° C. compared to the formulation described in Example 7, which does not employ terpineol as an additive.

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PUM

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Abstract

A precursor composition for the deposition and formation of an electrical feature such as a conductive feature. The precursor composition advantageously has a viscosity of at least about 1000 centipoise and can be deposited by screen printing. The precursor composition also has a low conversion temperature, enabling the deposition and conversion to an electrical feature on low temperature substrates. A particularly preferred precursor composition includes silver and / or copper metal for the formation of highly conductive features.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application claims the benefit of U.S. Provisional Application No. 60 / 327,621 filed Oct. 5, 2001 and U.S. Provisional Patent Application No. 60 / 338,797 filed Nov. 22, 2001. The disclosure of each of these applications is incorporated herein by reference in its entirety.BACKGROUND OF THE INVENTION [0002] 1. Field of the Invention [0003] The present invention relates to precursor compositions that are useful for the deposition of conductive electronic features. The precursor compositions can advantageously have a low conversion temperature to enable low-temperature treatment of the precursors to form conductive features on a variety of substrates. The precursor compositions have a relatively high viscosity and can be deposited onto a substrate using methods such as thick-film deposition or syringe dispensing. [0004] 2. Description of Related Art [0005] The electronics, display and energy industries rely on the formation of coatings a...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01B1/22C09D11/00H01B1/02H01C17/065H01L21/288H01L21/314H01L21/316H05K1/09H05K3/10
CPCC09D11/30H01B1/026H01C17/06506H01C17/06533C23C18/08H01L21/288H01L21/31691H05K1/097H05K3/105H01C17/06573
Inventor KODAS, TOIVO T.HAMPDEN-SMITH, MARK J.VANHEUSDEN, KARELDENHAM, HUGHSTUMP, AARON D.SCHULT, ALLEN B.ATANASSOVA, PAOLINAKUNZE, KLAUS
Owner CABOT CORP
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