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Coating compositions for producing transparent super-hydrophobic surfaces

a technology of super-hydrophobic coatings and coating compositions, which is applied in the direction of coatings, thin material processing, transportation and packaging, etc., can solve the problems of leaving a water spot when the water dries, high cost of use, etc., and achieves/or abrasion, good resistance to uv light, and some resistance to abrasion

Inactive Publication Date: 2008-09-11
ASHLAND LICENSING & INTPROP LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0009]The coating solves the problem of poor resistance to UV light and / or abrasion found in previous coatings of similar nature. The transparent, near transparent, or semi-transparent coatings can be produced using the current invention whereas previous coatings of comparable hydrophobicity have all been white or opaque. The coating can be applied by a single and easy spraying method and the super hydrophobic property can be achieved by drying the film at room temperature for 5 to 10 minutes. A preferred coating has good resistance to UV light and some resistance to abrasion.
[0011]The invention described herein provides a long lasting super hydrophobic coating that has the benefit of self cleaning of various surfaces and will reduce icing caused by water drops. However it should be noted that snow will cover horizontal surfaces but can be more easily removed from the surfaces protected with the coating formed from the composition of the present invention. Furthermore, the coatings of the instant invention are inexpensive compared to paint and can be sprayed regularly if necessary to keep the surface clean without any further steps.
[0017]Another object of the present invention is to provide coatings that are practical in use, that do not degrade rapidly in sunlight, that can be readily applied, and have enough resistance to abrasion to survive for a practical length of time, at least between vehicle washes, and preferably for weeks or months depending upon environmental conditions to which the coating is exposed.
[0019]Another object of the present invention is to use “lotus” coatings for a different purpose, to reduce drag.
[0022]Selection of the nanoparticle enables the formulation of a composition without any binder which will produce a practical lotus effect that is not easily destroyed by fog, UV light, or abrasion, e.g. by flowing water.

Problems solved by technology

Moreover, it recommends to use purified rinse water which is expensive to use.
However, the hydrophobicity of the surfaces is not sufficient enough to bead the water completely from the surface thereby leaving the water spot when the water dries.

Method used

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  • Coating compositions for producing transparent super-hydrophobic surfaces
  • Coating compositions for producing transparent super-hydrophobic surfaces
  • Coating compositions for producing transparent super-hydrophobic surfaces

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0048]Synthesis of Silsesquioxanes A1: In a typical experiment, 3 g of 28% ammonium hydroxide was dissolved in 30 g of ethanol and transferred into a 2 necked 100 ml round bottomed flask. The whole mixture was heated to 75° C. for 30 minutes under stirring. After 30 minutes, a known amount of fluorinated triethoxysilane, methyl triethoxysilane and tetraethylorthosilicate (TEOS) in the ratio of May 5 / 50 / 45 respectively were added. Continued the reaction for another 12 hrs at 75° C. and cooled the reaction.

example 2

[0049]A2 In another experiment, the experimental procedure follows the same as in example 1 except that the composition of the monomers (fluorinated triethoxysilane, methyl triethoxysilane and Tetraethylorthosilicate (TEOS)) were changed to 0 / 50 / 50.

example 3

[0050]A3, In another experiment, the experimental procedure follows the same as in example 1 except that the composition of the monomers (fluorinated triethoxysilane, methyl triethoxysilane and Tetraethylorthosilicate (TEOS)) were changed to Feb. 10 / 40 / 50.

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Abstract

A coating composition and process for generating transparent, near-transparent, and semi-transparent super-hydrophobic coatings on surfaces having a contact angle of greater than 165 degrees. The composition comprises hydrophobic nanoparticles of silsesquioxanes containing adhesion promoter groups and low surface energy groups.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application claims priority from U.S. Provisional Application Ser. No. 60 / 841,720 filed on Aug. 31, 2006 and U.S. Provisional Application Ser. No. 60 / 931,545 filed on May 24, 2007 and U.S. application Ser. No. 11 / 699,883 filed on Jan. 30, 2007 which claims priority from U.S. Provisional Application Ser. No. 60 / 763,294 filed on Jan. 30, 2006 all of which are incorporated by reference herein in their entirety. Reference to documents made in the specification is intended to result in such patents or literature cited are expressly incorporated herein by reference, including any patents or other literature references cited within such documents as if fully set forth in this specification.TECHNICAL FIELD[0002]The technical field of this invention is producing super hydrophobic coatings on surfaces.BACKGROUND OF THE INVENTION[0003]The invention relates to protection of various surfaces from contaminants and from oxidation of surfaces in air...

Claims

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Application Information

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IPC IPC(8): C08L83/04C09D7/62
CPCC08K3/36C08K9/04C09D5/1618Y10T428/2995C09D7/1266C09D183/04C09D7/1225C09D7/62C09D7/67Y10T428/31663
Inventor KANAGASABAPATHY, SUBBAREDDYBAUMGART, RICHARD J.SU, WEN-CHENLOCKWOOD, FRANCES E.
Owner ASHLAND LICENSING & INTPROP LLC
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