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Hydrogen generator

Inactive Publication Date: 2009-12-31
LYNNTECH POWER SYST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0040]The catalyst may be selected from one or more transition metals. Preferred catalysts include ruthenium, ruthenium chloride, or combinations thereof. Preferred solvents include, for example, tetrahydrofuran, ethylene glycol ethers, anhydrous ammonia, substituted amines, pyridine or combinations ther

Problems solved by technology

Both Rusta-Sallehy and Amendola disclosed systems that used sodium borohydride solutions to generate hydrogen but both have several significant limitations.
The solutions required a substantial excess of vater that decreased the mass yield of hydrogen.
The processes also required pumps, which add to the weight and complexity of the systems.
In addition, the aqueous solution is not completely stable.
Even under basic conditions, the borohydride gradually hydrolyzes, thereby limiting the shelf-life of the chemical hydride solution.
However, this water-starved condition was achieved by injecting water throughout the mass of hydride in a slow, controlled manner using a complex mechanical control system, thereby substantially reducing the wt % yield of hydrogen from the generator system.
The system and methods disclosed by Tsang do not address or solve the problems of making a light weight hydrogen generator because the two required pumps and the hydroxide necessary for storing the borohydride solution add significant weight to the disclosed hydrogen generator.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

Hydride Pellet Production

[0127]The hydride is frequently prepared as pellets. For each compound to be tested in this form, pellets were produced both neat and with predetermined amounts of catalyst blended with the hydride. For catalyzed pellets, the catalyst was blended with the hydride by grinding the components together. Pellets were standardized with a diameter of 13 mm and a height of ˜1 cm. The exact height of a pellet varied, as variations in additives and pressing conditions altered the final density. The pellets were produced using a standard pellet die (Graseby Specac) with a 12 ton press (Carver).

[0128]The effect on the density of lithium hydride pellets caused by varying the pressure exerted by the press is shown in Table 3. The accuracy of the pressures shown is about ±500 psi.

TABLE 3Pressure (psi)Density (g / mL)Fraction of Theoretical5,0000.53068.0%10,0000.55170.7%15,0000.57774.0%20,0000.60978.1%25,0000.64983.3%30,0000.65984.5%

[0129]All of the pellets showed good integr...

example 2

Evaluation of Hydrogen Evolution from Hydride Pellets

[0130]An apparatus for evaluating both neat and hydride-catalyst compositions for use in passively controlled generators is shown in FIG. 7. The hydride is shown as a pellet 26, which is a preferred form for the hydride because it is easily handled. A measured amount of water was injected into the flask 82 at the start of the experiment. Typically two to five grams of hydride were used in each reaction. The amount of water added was determined by the amount of hydride, the amount of water required to stoichiometrically hydrolyze it, and the stoichiometry being tested. As hydrogen was generated, the gas stream exited the flask 82, passed through a drying tube 85, and exited through a mass flow monitor 83 and vent 84. The drying tube 85 removed most, if not all, of the water in the gas stream. It is important that the dew point of the gas passing through the mass flow 83 is significantly below ambient to avoid condensate in the inst...

example 3

Hydride Pellets with Wicking Agents

[0133]LiH pellets were separately formed with four different wicking agents that included two sources of cellulose fibers, (paper and cotton), modified polyester having a surface treatment to enhance water transport along the surface without absorption into the fiber, and polyacrylamide, the active component of disposable diapers. In each case, the wicking material was included with the LiH in the die for pressing.

[0134]The pellets were hydrolyzed as described in Example 2. The fiber-containing pellets hydrolyzed quantitatively, unlike the results of Example 2. However, the reaction was quite rapid, lasting no more than a few minutes in any of the cases. The rate of hydrogen generation peaked in excess of 1.5 L per minute and then decreased to about 100 mL per minute within 5 minutes. The entire reaction was over in about 45 minutes.

[0135]In the presence of a ground paper wick or a polyacrylamide wick mixed into the hydrogen-containing composition ...

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Abstract

An apparatus and method apply water to a hydrogen-containing composition, such as a hydride, in the presence of a catalyst that promotes hydrolysis to generate hydrogen in a controlled manner. The amount of catalyst used can be carefully tailored so that the reaction rate is limited by the amount of catalyst present (passive control) or it can be sufficiently large so that the reaction is controlled by the rate of water addition (active control).

Description

[0001]This application claims the benefit of U.S. Provisional Application No. 60 / 470,319, filed May 14, 2003.[0002]This invention was made with Government support under DAAH01-00-C-R178 awarded by the U.S. Army Aviation and Missile Command. The Government has certain rights in this invention.BACKGROUND OF THE INVENTION[0003]1. Field of the Invention[0004]The present invention relates generally to the generation of hydrogen gas, such as for use in a fuel cell.[0005]2. Background of the Related Art[0006]A fuel cell is an energy conversion device that efficiently converts the stored chemical energy of a fuel into electrical energy. A proton exchange membrane (PEM) fuel cell is a particular type of fuel cell that generates electricity through two electrochemical reactions that occur at the proton exchange membrane / catalyst interfaces at relatively low temperatures (typically<80° C.). A necessary step in the operation of such fuel cells is the electrochemical oxidation of a fuel, typi...

Claims

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Application Information

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IPC IPC(8): B01J8/00C01B6/00B01J4/00B01J4/02C01B3/06
CPCB01J4/001Y02E60/362C01B3/065B01J4/02Y02E60/36
Inventor SALINAS, CARLOSCISAR, ALANCLARKE, ERICMURPHY, OLIVER J.FIEBIG, BRAD
Owner LYNNTECH POWER SYST
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