Modulation of combustion rates in fuels
a technology of combustion rate and fuel, applied in the field of additive composition, can solve the problems of currently problematically adjusting the desired combustion rate for each such application
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example 2
Production of Mg0.3Mn0.7O Nanoalloy Particles (Cubes+Spheres)
[0086]The following procedure was used to produce an alloy of magnesium and manganese oxide nanoparticles. Oleylamine (4.25 mL, 0.129 mols) and 1.36 mL of oleic acid (0.04 mols) was mixed in a suitable vessel that was stirred and heated in a hot oil bath to 120° C. and held at that temperature for 10 minutes. A mixture of magnesium acetate (0.14 grams) and manganese acetyl acetonate (0.34 grams) powder was added under vigorous stirring to the amine and acid to provide a clear solution. The solution was then microwaved for 15 minutes. After microwaving the solution, synthesized nanoparticles of magnesium / manganese oxide were flocculated with ethanol, centrifuged, and redispersed in toluene. The Mg0.3Mn0.7O nanoparticles made by the foregoing process have an x-ray diffraction pattern that indicates that traces of manganese oxide are included in the Mg0.3Mn0.7O alloy. The nanoparticles have cube-like structures similar to man...
example 3
Preparation of Single Metal Flame Modulation Additive (FMA) Concentrate
[0087]Preparation of a metallic or metallic / metalloid nanoparticle or nanoalloy additive core, can be carried out using any of the published prep methods that are deemed suitable. Particle size control can be achieved by selection of suitable blends of a fatty amine or carboxylic acid. Then the core nanoparticle or nanoalloy can be coated with a flame retardant ligand —R(X)m to give a neat FMA.
Na3PO4.12H2O+-nR(X)m→Na3PO4.12H2O[—R(X)m]n
[0088]Where R(X)m is a diaryl alkyl- or aryl-phosphonate of the type,
With R1 an alkyl group of carbon length 1-32, and n>1
example 4
Preparation of Nanoalloy Particle Flame Modulation Additive Concentrate
[0089]
Mn(NO3)2+Na2H2Sb2O7.7H2O→MnSb2O6
MnSb2O6+-nR(X)m→MnSb2O6.[—R(X)m]n, where;
[0090]R(X)m is a diaryl alkyl- or aryl-phosphonate of the type:
With R1 an alkyl group of carbon length 1-32, m=Br=5, and n>1
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