Application of high toughness, low viscosity nano-molecular resin for reinforcing pothole patching materials in asphalt and concrete base pavement

Abstract

Described herein are methods of improving the durability of concrete by the infusion of the concrete with a low-viscosity oligomeric solution, and subsequent curing of the oligomeric solution to form a high toughness polymer. Also described herein are compositions containing concrete and high toughness polymers, and formed articles made from concrete and high toughness polymers. The methods and compositions are useful for improving the durability of concrete roads and structures, as well as the durability of repairs to concrete roads.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation-in-part of International Application No. PCT / US2012 / 035602 filed Apr. 27, 2012, which claims priority to U.S. application Ser. No. 13 / 096,750 filed Apr. 28, 2011, the disclosure of which is incorporated herein by reference in its entirety. This application also is a continuation-in-part of U.S. application Ser. No. 13 / 096,750 filed Apr. 28, 2011, which claims the benefit of U.S. Provisional Application No. 61 / 329,505 filed Apr. 29, 2010, the disclosure of which is incorporated herein by reference in its entirety.STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT[0002]This invention was made with Government support of Grant No. 70NANB10H019, awarded by the Department of Commerce—NIST. The Government has certain rights in this invention.BACKGROUND OF THE INVENTION[0003]Damage to concrete structures such as roads, runways, bridges, and even buildings is a chronic problem around the world. The n...

AI Technical Summary

Benefits of technology

[0015]In accordance with one embodiment, the present invention is directed to methods of increasing the durability of concrete and concrete structures by incorporating polymers into the structure of the concrete. The infusion into the concrete of a low viscosity, fast curing oligomeric solution comprising a nanomolecular precursor and subsequent polymerization of the monomer into a polymer with high toughness provides increased strength and durability to the concrete as well as providing a barrier to the entry of moisture and chemicals that cause degradation of the surface.

[0016]In accordance with another embodiment, the present invention is directed to methods of increasing the durability of concrete and concrete structures by incorporating thermoset polymers into the structure of the concrete. The infusion into the concrete of a low viscosity, fast curing oligomeric solution comprising a nanomolecular precursor and subsequent polymerization of the monomer into a thermoset polymer with high toughness provides increased strength to the concrete as well as providing a barrier to the entry of moisture and chemicals that cause degradation of the surface. In some embodiments, the thermoset polymer is a polymer formed by ring opening methathesis polymerization. Specific examples include polydicyclopentadiene and polynorbornene.

[0017]In accordance with another embodiment, the present invention is directed to compositions comprising concrete and polymers formed by ring opening metathesis polymerization. The compositions of the embodiments of the present invention form highly durable materials that are resistant to moisture intercalation and have improved resistance to degradation caused by weather or use.

Problems solved by technology

Damage to concrete structures such as roads, runways, bridges, and even buildings is a chronic problem around the world.

The natural erosion processes in combination with pollution and / or heavy use have a severe impact on the life of these structures.

Surface damage in concrete roads can result from a number of causes—frost damage, late finishing, toweling-on of a “topping” layer after the main slab has been compacted and found to be low, or mechanical damage, caused for example by vehicles.

Concrete can have high void content that can allow moisture to enter the surface and when frozen, produce tensile stresses that result in scaling and cracking of the surface.

The application of a de-icing agent to a pavement that is already covered in snow or ice will cause the surface to lose heat rapidly.

This melts the ice on the surface, but can cause freezing of any moisture that has become trapped in the material, potentially damaging it.

The occurrence of potholes on asphalt and cement pavements have been long standing issues for all transportation agencies in this country as well as around the world.

In addition, the existence of potholes presents a great safety hazard to vehicles, structures, and pedestrians.

A driver's inherent reaction to veer away from a pothole often presents a danger to nearby vehicles and pedestrians and can cause serious traffic disturbances.

In colder climates, the subsequent freeze-thaw action pushes the pavement upward while traffic stresses the pavement and a breakdown of the road surface causes a material collapse that forms the pothole.

In places such as Florida, temperature and the impact of water on the integrity of the road material and subsurface combine to reduce the integrity of the surface and lead to its compromise.

It is felt that the failure and short life of the pothole repairs are due to the creation of precursor cracks as the result of low toughness, low rutting resistance and low strength of the repairs materials.

Similarly, buildings, bridges and other concrete structures are continually impacted by weathering processes primarily catalyzed by water.

Water can cause spalling and damage to surfaces of bridges and buildings, exposing structural components, such as steel beams and rebar, that may be further damages and cause even more erosion to the concrete.

Further, acid rain can not only cause ugly discoloration to building facades, but also cause significant damage and deterioration to concrete buildings, bridges, and other concrete surfaces, as the acidic solution dissolves the calcium hydrates in the cement.

While it would be safer to make the repair flush with the road surface, absent a firm watertight bond, this is not possible.

This can result in long down-times that can be disruptive and costly.

This can be difficult to estimate, as it can be inexact how much the repair will settle, and in how much time.

It can be appreciated that a repair that ends up too high can cause an unsafe bump for motorists, and a repair that ends up too low can cause pooling of water.

However, this tended to be a labor and capital intensive process.

Despite the benefits of adding polymers to asphalt to improve physical and mechanical performance, the polymers currently in use may not optimize asphalt performance.

Also, the cost of adding polymers to the asphalt at levels sufficiently high to meet desired specifications can be prohibitive.

However, the incorporation of polymers and other components into the asphalt can cause numerous problems that compromise the requisite asphalt properties.

Further, these methods are incompatible for use with cement concrete.

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