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Polycarbonate resin and transparent film formed therefrom

a technology of polycarbonate resin and transparent film, which is applied in the direction of polarising elements, instruments, transportation and packaging, etc., can solve the problems of petroleum resource depletion, achieve excellent film formation properties, moderate glass transition temperature, and low photoelastic coefficient

Inactive Publication Date: 2014-09-18
MITSUBISHI CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention is a polycarbonate resin with specific properties that make it suitable for use as an optical film, such as a retardation film. The resin has low photoelasticity and a moderate glass transition temperature. It has excellent film formation properties and high toughness and durability. The film formed from this resin has high orientation properties. The polycarbonate resin contains specific structural units derived from different dihydroxy compounds. The use of certain dihydroxy compounds is preferred. The invention also includes a method for making the polycarbonate resin.

Problems solved by technology

In recent years, however, there is a fear about depletion of petroleum resources, and it is desired to supply a polycarbonate produced from a starting material obtained from biomass resources such as plants.

Method used

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  • Polycarbonate resin and transparent film formed therefrom
  • Polycarbonate resin and transparent film formed therefrom
  • Polycarbonate resin and transparent film formed therefrom

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0115]Into a reaction vessel were introduced 26.2 parts by weight of isosorbide (hereinafter often abbreviated to “ISB”), 100.5 parts by weight of 9,9-bis(4-(2-hydroxyethoxy)phenyl)fluorene (hereinafter often abbreviated to “BHEPF”), 10.7 parts by weight of 1,4-cyclohexanedimethanol (hereinafter often abbreviated to “1,4-CHDM”), 105.1 parts by weight of diphenyl carbonate (hereinafter often abbreviated to “DPC”), and 0.591 parts by weight of cesium carbonate (0.2% by weight aqueous solution) as a catalyst. In a nitrogen atmosphere, the temperature of the heat medium of the reaction vessel was regulated to 150° C. to dissolve the starting materials while stirring the mixture according to need (about 15 minutes) in preparation for a first reaction step.

[0116]Subsequently, the internal pressure of the reaction vessel was reduced from ordinary pressure to 13.3 kPa, and the temperature of the heat medium of the reaction vessel was elevated to 190° C. over 1 hour, during which the phenol ...

example 2

[0120]The same procedure as in Example 1 was conducted, except that use was made of 35.1 parts by weight of ISB, 90.2 parts by weight of BHEPF, 10.6 parts by weight of diethylene glycol (hereinafter often abbreviated to “DEG”), 118.6 parts by weight of DPC, and 0.666 parts by weight of the aqueous cesium carbonate solution as a catalyst. Thus, a polycarbonate resin B was obtained. The polycarbonate resin B obtained had a composition composed of BHEPF / ISB / DEG=37.7 mol % / 44.0 mol % / 18.3 mol %. The properties of the polycarbonate resin B were determined. A transparent film was formed therefrom in the same manner as in Example 1, and the properties thereof were determined. The results thereof are shown in Table 1.

example 3

[0121]The same procedure as in Example 1 was conducted, except that use was made of 27.8 parts by weight of ISB, 82.1 parts by weight of BHEPF, 25.6 parts by weight of 1,4-CHDM, 120.8 parts by weight of DPC, and 0.679 parts by weight of the aqueous cesium carbonate solution as a catalyst. Thus, a polycarbonate resin C was obtained. The polycarbonate resin C obtained had a composition composed of BHEPF / ISB / 1,4-CHDM=33.7 mol % / 34.3 mol % / 32.0 mol %. The properties of the polycarbonate resin C were determined. A transparent film was formed therefrom in the same manner as in Example 1, and the properties thereof were determined. The results thereof are shown in Table 1.

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Abstract

The polycarbonate resin of the invention includes a first structural unit derived from a dihydroxy compound represented by a general formula (1), a second structural unit derived from a dihydroxy compound represented by a general formula (2), and a third structural unit derived from at least one dihydroxy compound selected from the group consisting of a dihydroxy compound represented by a general formula (3), a dihydroxy compound represented by a general formula (4), a dihydroxy compound represented by a general formula (5), and a dihydroxy compound represented by a general formula (6), and in which the first structural unit derived from a dihydroxy compound represented by the general formula (1) accounts for 18% by mole or more of the polycarbonate resin. The above general formulae (1) to (6) are described in the specification of the present application.

Description

TECHNICAL FIELD[0001]The present invention relates to a polycarbonate resin and a transparent film formed therefrom.BACKGROUND ART[0002]Polycarbonate resins are generally produced from starting materials induced from petroleum resources. In recent years, however, there is a fear about depletion of petroleum resources, and it is desired to supply a polycarbonate produced from a starting material obtained from biomass resources such as plants. Furthermore, in view of the fact that the global warming caused by increases in carbon dioxide emission and by accumulation thereof brings about climate changes, etc., there is a need for the development of a polycarbonate resin which is produced using a plant-derived monomer as a starting material and which, even when discarded after use, is carbon-neutral.[0003]For example, a technique has been proposed in which isosorbide is used as a plant-derived monomer to obtain a polycarbonate resin through a transesterification reaction with diphenyl ca...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C08G64/06G02B5/30
CPCG02B5/305C08G64/06C08G64/1608C08J5/18G02B1/04C08J2369/00G02B5/3083Y10T428/31507C08L69/00C08G64/02G02B5/30
Inventor TANAKA, TOMOHIKOYOKOGI, MASASHIMURAKAMI, NAOIIDA, TOSHIYUKI
Owner MITSUBISHI CHEM CORP
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