Thermoplastic polymer composition and molded article

a technology of thermoplastic polymer and composition, applied in the direction of film/foil adhesives, synthetic resin layered products, water-setting substance layered products, etc., can solve the problems of reduced productivity, increased production costs, and difficult melting adhesion, and achieve high production efficiency, excellent flexibility, and moldability. good

Inactive Publication Date: 2014-11-27
KURARAY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0021]A thermoplastic polymer composition of the present invention can be adhered to a ceramic, a metal or a synthetic resin without performing a primer treatment or the like and has excellent flexibility, mechanical properties, moldability, storage stability and heat resistance. Of course, the thermoplastic polymer composition can be adhered to a ceramic, a metal or a synthetic resin, that has been subjected to a primer treatment.
[0022]A molded article in which a thermoplastic polymer composition of the present invention is adhered to a ceramic, a metal or a synthetic resin has practically sufficient adhesiveness even through placed in an environment of 60° C. or higher, and can be used in a wide range of uses. Furthermore, a molded article in which a thermoplastic polymer composition of the present invention is adhered thereto a ceramic, a metal or a synthetic resin in higher adhesive strength can be produced, and the molded article thus obtained can be used in uses requiring higher adhesive strength.
[0023]Furthermore, a molded article of the present invention can maintain good adhesiveness without bleeding of a softener or the like even through the molded article is stored over a long period of time.

Problems solved by technology

However, the styrenic thermoplastic elastomer is a material having low polarity, and its adhesive force to a ceramic, a metal or the like is not sufficient, and the styrenic thermoplastic elastomer has a problem that melting adhesion is difficult as it is.
However, the methods disclosed in Patent Documents 1 to 6 have the problems that not only steps are complicated, but productivity is decreased and production costs are increased.

Method used

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  • Thermoplastic polymer composition and molded article
  • Thermoplastic polymer composition and molded article
  • Thermoplastic polymer composition and molded article

Examples

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examples

[0136]The present invention is described below in further detail by examples and the like, but it should be understood that the invention is not construed as being limited to those.

[0137]Each component used in the following examples and comparative examples is as follows.

[Thermoplastic Elastomer (A1)]

[0138]64 L of cyclohexane as a solvent and 0.20 L of sec-butyllithium (10 mass % cyclohexane solution) as an initiator were charged in a pressure vessel substituted with nitrogen and dried, and 0.3 L (corresponding to 15 times in a stoichiometric ratio to lithium atoms in the initiator) of tetrahydrofuran as an organic Lewis base was charged therein. After increasing the temperature to 50° C., 2.3 L of styrene was added and polymerization was conducted for 3 hours. Subsequently, 23 L of isoprene was added and polymerization was conducted for 4 hours. 2.3 L of styrene was further added and polymerization was conducted for 3 hours. The reaction liquid obtained was poured in 80 L of methan...

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Abstract

The present invention is a thermoplastic polymer composition which contains 10-120 parts by mass of a polar group-containing polypropylene resin (B) per 100 parts by mass of a thermoplastic elastomer (A) that is a block copolymer having a polymer block containing an aromatic vinyl compound unit and a polymer block composed of a conjugated diene unit having 40% by mole or more of 1,2-bonds and 3,4-bonds in total, or a hydrogenated product of the block copolymer (provided that a thermoplastic polymer composition containing 1 part by mass or more of a polyvinyl acetal resin is excluded). This thermoplastic polymer composition is able to be bonded with a ceramic, a metal or a synthetic resin without requiring a primer treatment, and has excellent flexibility, mechanical characteristics, moldability, heat resistance and storage stability.

Description

TECHNICAL FIELD[0001]The present invention relates to a thermoplastic polymer composition that can be adhered to a ceramic, a metal or a synthetic resin without performing a primer treatment or the like and has excellent flexibility, mechanical properties, moldability, heat resistance and storage stability, and a molded article thereof, and also relates to a method for producing the molded article, particularly a molded article in which the thermoplastic polymer composition is adhered to a ceramic, a metal or a synthetic resin, by insert molding.BACKGROUND ART[0002]Ceramics, metals and synthetic resins, having excellent durability, heat resistance and mechanical strength are widely used in various uses such as household appliances, electronic parts, machine parts and automobile parts. Those members are sometimes used by adhering to or combining with an elastomer member having excellent flexibility for the purpose of fixing to other structural member or for the purpose of shock absor...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B32B27/06B32B15/085B32B27/30B32B18/00C08L53/02B32B27/32B29C70/68B32B27/08
CPCB32B27/06B32B2274/00B32B15/085B32B27/08B32B18/00C08L53/025B29C70/683B32B27/32B32B27/302B29K2023/12B29K2096/04B29K2105/0085B29K2995/0088B29K2105/0088B29K2105/0005B29K2705/02B32B2270/00B29C70/68B29C45/0001B29C45/14778B32B9/005B32B9/045B32B27/18B32B2307/306B32B2457/00C04B35/63408C04B35/6344C04B37/008C04B2237/34C04B2237/343C04B2237/346C04B2237/348C04B2237/36C04B2237/365C04B2237/368C08L23/10C08L51/06C09J153/025Y10T428/31667Y10T428/31696Y10T428/31931C08L23/26C08L53/02C08L101/00B29K2023/14B29L2031/3481
Inventor MINAMIDE, ASAKOMASUDA, MIKIOSUZUKI, MASAHIRO
Owner KURARAY CO LTD
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