Asphalt modifier and asphalt composition comprising same

a technology of asphalt modifier and modifier, which is applied in the field of asphalt modifier, can solve the problems of plastic deformation, cracking, and high cost of dissolving block copolymer at high temperature, and achieve the effects of improving the physical properties of asphalt composition, excellent compatibility with asphalt, and improving workability

Inactive Publication Date: 2020-04-23
LG CHEM LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0024]The asphalt modifier according to the present invention has excellent compatibility with asphalt as a certain multifunctional group is introduced into a vinyl aromatic hydrocarbon-conjugated diene block copolymer. Thus, when the asphalt modifier is used in an asphalt composition, workability can be remarkably improved, and various physical properties of asphalt, such as low-temperature and high-temperature properties, storage stability, and the like, can be effectively improved.
[0025]Hereinafter, the present invention will be described in further detail.
[0026]The terms and / or words used in this specification and the appended claims are not to be interpreted as limited to commonly used meanings or meanings in dictionaries and should be interpreted with meanings and concepts which are consistent with the technological scope of the present invention based on the principle that the present inventors have appropriately defined concepts of terms to describe the present invention in the best way.
[0027]To improve physical properties of an asphalt composition, a vinyl aromatic hydrocarbon-conjugated diene block copolymer is used as an asphalt modifier.
[0028]The asphalt composition is mainly composed of four components. Among these, a component having the worst compatibility with a vinyl aromatic hydrocarbon-conjugated diene block copolymer used as the asphalt modifier is asphaltene. Asphaltene is a highly concentrated aromatic hydrocarbon compound including polar functional groups having a number of heteroatoms in a chemical aspect. However, because the vinyl aromatic hydrocarbon-conjugated diene block copolymer used as the asphalt modifier contains no polar functional groups, the asphalt modifier has poor compatibility with the asphalt composition, resulting in degraded processability and workability. Also, the asphalt modifier is not sufficiently mixed with the asphalt composition, resulting in degraded quality, such as degraded elasticity, of asphalt.
[0029]To solve the above problems, a method of adjusting a molecular weight of a block copolymer or a method of adding a hydrophilic monomer, oil, and the like has been used in the prior art. However, such a method has a drawback in that the molecular weight of the block copolymer may decrease due to cleavage of chains thereof, and thus the physical properties of the asphalt composition may be rather degraded.

Problems solved by technology

However, the asphalt has drawbacks in that plastic deformation occurs during use when the asphalt is exposed to a high temperature for a prolonged period of time and cracking occurs at a low temperature due to external impacts.
When the vinyl aromatic hydrocarbon-conjugated diene block copolymer is used as the asphalt modifier, much time and cost are required to dissolve the block copolymer at a high temperature.
Because the asphaltene as an aggregate of aromatic hydrocarbons, includes a large amount of polar functional groups at the ends thereof, the asphaltene has very low compatibility with block copolymers having no polar functional groups.
Thus, a processing time or a manufacturing time of the asphalt may not only be remarkably extended, but a decline in quality of the asphalt, for example, a decrease in elasticity of modified asphalt, may also be caused.
Such patents have somewhat improved compatibility with the asphalt composition, but do not exhibit a sufficient improvement effect.
Also, the patents have no ultimate solution because there is a high variation in quality of asphalt according to crude oil and asphalt compositions obtained accordingly also have different modification effects.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 2

ON OF ASPHALT MODIFIER AND ASPHALT COMPOSITION

[0084]A styrene-butadiene block copolymer pellet having a weight average molecular weight of approximately 110 kg / mol and a styrene block content of 31% by weight was prepared in the same manner as in Example 1, except that 2.378 g of 1,6-hexanediol diglycidyl ether was used as the coupling agent of Example 1 instead of the 1,4-butanediol diglycidyl ether.

[0085]Next, an asphalt composition was prepared in the same manner as in Example 1.

example 3

ON OF ASPHALT MODIFIER AND ASPHALT COMPOSITION

[0086]A styrene-butadiene block copolymer pellet having a weight average molecular weight of approximately 110 kg / mol and a styrene block content of 31% by weight was prepared in the same manner as in Example 1, except that 1.799 g of ethylene glycol diglycidyl ether was used as the coupling agent of Example 1 instead of the 1,4-butanediol diglycidyl ether.

[0087]Next, an asphalt composition was prepared in the same manner as in Example 1.

experimental example 1

PROPERTIES OF ASPHALT COMPOSITIONS

[0090]The physical properties of the modified asphalt composition including each of the asphalt modifiers prepared in Examples and Comparative Example were measured, as follows. The results are listed in the following Table 1.

(1) Softening Point

[0091]The softening point is a measure of high-temperature properties of the modified asphalt measured according to the American Society for Testing and Materials (ASTM) D36. Here, the softening point was measured by heating water or glycerin at a rate of 5° C. / minute so that a specimen began to soften by the heating, followed by measuring a temperature when a ball having a diameter of 9.525 mm and a weight of 3.5 g, which had been disposed on the specimen, moved down by approximately 1 inch.

(2) Phase Separation Temperature

[0092]50 g of the modified asphalt composition was weighed in an aluminum tube, and kept at 180° C. for 72 hours in an oven. Thereafter, the asphalt composition was divided into three equal...

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Abstract

The present invention relates to an asphalt modifier and an asphalt composition including the same, and more particularly, to an asphalt modifier capable of effectively improving low-temperature properties, high-temperature properties, storage stability, and the like of an asphalt composition due to excellent compatibility with the asphalt composition when a vinyl aromatic hydrocarbon-conjugated diene block copolymer containing a certain multifunctional group is used as the asphalt modifier, and an asphalt composition including the same.

Description

TECHNICAL FIELD[0001]This application claims the benefit of Korean Patent Application No. 10-2016-0137678, filed on Oct. 21, 2016, with the Korean Intellectual Property Office, the disclosure of which is herein incorporated by reference in its entirety.[0002]The present invention relates to an asphalt modifier having excellent compatibility with asphalt and an asphalt composition including the same.BACKGROUND ART[0003]Asphalt is a residue which is obtained after most of volatile oils in components of crude oil are evaporated, and has a physical property of being maintained in a liquid or semi-solid state having a high viscosity at a high temperature but being firmly hardened at a temperature less than or equal to room temperature.[0004]Because the asphalt has good plasticity, high water repellency, electrical insulating properties and adhesiveness, and chemically stable characteristics, the asphalt has been widely used for construction materials such as paving materials or waterproo...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C08L95/00C08F297/04C08K5/06C08L53/02
CPCC08K5/06C08L2555/84C08F297/044C08L53/025C08L95/00C08L2312/00C08F297/04C08L53/02
Inventor KIM, TAEJUNGLEE, CHUNHWALEE, HYE RIM
Owner LG CHEM LTD
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