Lithium ion battery diaphragm and production thereof
A technology for battery diaphragms and diaphragms, which is applied to battery pack parts, circuits, electrical components, etc. It can solve problems such as difficult hole shape and precise adjustment of porosity, and achieve uniform strength, high puncture resistance, and high production efficiency.
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Embodiment 1
[0019] (1) Add 0.01% by weight of poly-1-butene as a pore modifier and 0.01% by weight of N-methylolacrylamide as a porosity regulator into polypropylene resin, and melt at a temperature of 100 to 260°C Extrusion granulation into pellets;
[0020] (2) Melt and extrude the above-mentioned pellets at 100-260° C., and cool the extruded flat film with a cooling roll. The cooling temperature is -20-150° C. and the cooling time is 0.1-10 minutes. When other conditions are constant, the higher the elastic modulus of the original flat film, the more conducive to the formation of micropores, and the cooling temperature and time can affect the elastic modulus;
[0021] (3) The above-mentioned extruded flat film is subjected to a continuous process of first longitudinal stretching and then transverse stretching, the stretching temperature is -20-220° C., and finally heat-set at 0-200° C. for 0.1-30 minutes.
Embodiment 2
[0023] (1) Add 0.1% by weight of poly-1-butene as a pore modifier and 0.1% by weight of N-methylolacrylamide as a porosity regulator into polypropylene resin, and melt at a temperature of 100 to 260°C Extrusion granulation into pellets;
[0024] (2) Melt and extrude the above pellets at 100-260°C, and cool the extruded flat film with a cooling roll, the cooling temperature is -20-150°C, and the cooling time is 0.1-10 minutes;
[0025] (3) The above-mentioned extruded flat film is subjected to a continuous process of first longitudinal stretching and then transverse stretching, the stretching temperature is -20-220° C., and finally heat-set at 0-200° C. for 0.1-30 minutes.
[0026] Head Example 3:
[0027] (1) Add 1% by weight of poly-1-butene as a pore modifier and 1% by weight of N-methylolacrylamide as a porosity regulator into polypropylene resin, and melt at a temperature of 100 to 260°C Extrusion granulation into pellets;
[0028] (2) Melt and extrude the above pellets...
Embodiment 4
[0031] (1) Add 0.5% by weight of polyvinylidene fluoride as a pore modifier and 0.2% by weight of magnesium oxide as a porosity regulator into polypropylene resin, melt and extrude at a temperature of 100 to 260°C to form granules material;
[0032] (2) Melt and extrude the above pellets at 100-260°C, and cool the extruded flat film with a cooling roll, the cooling temperature is -20-150°C, and the cooling time is 0.1-10 minutes;
[0033] (3) The above-mentioned extruded flat film is subjected to a continuous process of first longitudinal stretching and then transverse stretching, the stretching temperature is -20-220° C., and finally heat-set at 0-200° C. for 0.1-30 minutes.
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Abstract
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