MnOx/ZrO2-TiO2 low temperature selective catalytic reduction NOx catalyst possessing anti SO2 performance and its preparation technology
A catalyst and selective technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, chemical instruments and methods, etc., can solve problems such as catalyst poisoning, reduce operating temperature, and reduce deposition , the effect of high catalytic efficiency
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Embodiment 1
[0021] Using the sol-gel method, n-butyl titanate, ethanol, water, Mn(NO 3 ) 2 , ZrOCl 2 , acetic acid as raw material, the volume ratio of each component is as follows, n-butyl titanate: ethanol: water: acetic acid = 1: 1.5: 0.5: 0.5, Mn(NO 3 ) 2 The amount added is Mn:Ti=0.4, ZrOCl 2 The addition amount is: Zr:Ti=1, mixed, after the sol is transformed into a gel, dried, ground, and roasted at 200-600°C to obtain the catalyst.
[0022] Application treatment NO: NH 3 = 1, O 2 Concentration = 3%, GHSV (gas space velocity per hour) = 30000h -1 The flue gas denitrification of the SCR method, when the reaction temperature is 120 ° C, the catalytic efficiency is about 90%, adding 150ppm of S0 2 After that, the catalytic efficiency was 75%.
Embodiment 2
[0024] Using the sol-gel method, tetraethoxytitanium, ethanol, water, Mn(NO 3 ) 2 , ZrCl 4 , Nitric acid is raw material, and the volume ratio of each component is as follows, tetraethoxytitanium: ethanol: water: nitric acid=1: 1.65: 0.05: 0.07, Mn: Ti=0.4, ZrCl 4 The addition amount is: Zr:Ti=1, mixed, after the sol is transformed into a gel, dried, ground, and roasted at 200-600°C to obtain the catalyst.
[0025] Application treatment NO:NH 3 = 1, O 2 Concentration = 3%, GHSV (gas space velocity per hour) = 30000h -1 The SCR flue gas denitrification method, when the reaction temperature is 150 ° C, the catalytic efficiency is about 90%, adding 150ppm of SO 2 After that, the catalytic efficiency was 72%.
Embodiment 3
[0027] Using the sol-gel method, n-propyl titanate, propanol, water, Mn(NO 3 ) 2 , Zr(NO 3 ) 4 , nitric acid as raw material, n-propyl titanate:propanol:water:volume ratio of nitric acid=1:1.85:0.06:0.02, Mn(NO 3 ) 2 The amount added is: Mn:Ti=0.4, Zr(NO 3 ) 4 The added amount is: Zr:Ti=0.5, mixed, after the sol is transformed into a gel, dried, ground, and roasted at 200-600°C to obtain the catalyst.
[0028] Application treatment NO:NH 3 = 1, O 2 Concentration = 3%, GHSV (gas space velocity per hour) = 30000h -1 The SCR flue gas denitrification method, when the reaction temperature is 120 ° C, the catalytic efficiency is about 80%, adding 150ppm of SO 2 After that, the catalytic efficiency was 65%.
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