Composite material of poly lactic acid / natural faric, and production method

A natural fiber and composite material technology, applied in natural fiber reinforced modified polylactic acid composite materials and its production field, can solve the problems of high mechanical equipment requirements, low production efficiency, and difficulty in industrialization, and achieve high production efficiency and good molding processing Sexuality and simple operation

Inactive Publication Date: 2007-07-25
TORAY FIBER RES INST(CHINA) CO LTD
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Abstract

This invention discloses a poly (lactic acid)/natural fiber composite, which is mainly composed of poly (lactic acid) resin and natural fibers. The production method comprises: performing surface treatment on natural fibers with coupling agent, mixing with poly (lactic acid) resin, antioxidant, nucleating agent and lubricant, melt-extruding, and granulating to obtain the product. The method has such advantages as easy operation and high efficiency. The poly(lactic acid)/natural fiber composite has such advantages as high modulus, good heat resistance, good processability, and good biodegradability, and can be used in the fields of automobile industry, architecture and domestic decoration.

Technology Topic

Natural fiberPolylactic acid +3

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  • Composite material of poly lactic acid / natural faric, and production method
  • Composite material of poly lactic acid / natural faric, and production method
  • Composite material of poly lactic acid / natural faric, and production method

Examples

  • Experimental program(12)

Example Embodiment

[0014] Example 1
[0015] Accurately weigh 70 parts of polylactic acid and 0.3 parts of antioxidant tetra{β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid} pentaerythritol and add them to the extruder from the main hopper. At the same time, 30 parts of ramie short fibers are added to the extruder through the side feeder to be extruded and granulated, and the product is obtained after drying. Its mechanical properties are shown in Table 1 in 1 # As shown, for comparison, 0 in Table 1 # The mechanical properties of pure polylactic acid are listed.
[0016] Differential scanning calorimetry (DSC) was used to measure the crystallization performance of the composite material. The first cooling and the second heating curve were taken, and the crystallization peak (crystallization temperature) and half-width of the crystallization peak were used to characterize the crystallization rate. The higher the temperature and the narrower the half-width, the greater the crystallization rate. The area of ​​the crystallization peak (enthalpy of crystallization) and the area of ​​the melting peak (enthalpy of fusion) indicate the relative crystallinity. The greater the enthalpy, the higher the relative crystallinity. Its crystallization performance is shown in Table 2 in 1 * As shown, and 0 in Table 2 * The crystallization properties of pure polylactic acid are listed.
[0017] It can be seen from Table 1: The mechanical properties of the composite material of the present invention, such as flexural strength, flexural modulus and thermal deformation temperature, are much better than those of pure polylactic acid.
[0018] It can be seen from Table 2 that the crystallization performance of the present invention is also significantly better than that of pure polylactic acid.

Example Embodiment

[0019] Example 2
[0020] The cotton staple fiber is surface treated with coupling agent γ-glycidoxypropyltrimethoxysilane. The specific method is as follows: prepare a 1wt% coupling agent aqueous solution, drop a certain amount of concentrated hydrochloric acid to adjust the pH of the solution to pH 3 to 4, The cotton fiber is soaked in the solution, and after soaking for two hours, it is taken out and placed in a blast oven at 80°C for drying.
[0021] Accurately weigh 90 parts of polylactic acid and 0.3 parts of antioxidant tetra{β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid} pentaerythritol and add them from the main hopper to the extruder. At the same time, 10 parts of the treated cotton staple fiber is added to the extruder through the side feeder for extrusion granulation, and the product is dried after drying. The rest is the same as in Example 1, and its mechanical properties are shown in Table 1 in 2 # As shown, the crystallization properties are shown in Table 2 in 2 * Shown.
[0022] It can be seen from Table 1: The mechanical properties of the composite material of the present invention, such as flexural strength, flexural modulus and thermal deformation temperature, are much better than those of pure polylactic acid.
[0023] It can be seen from Table 2 that the crystallization performance of the present invention is also significantly better than that of pure polylactic acid.

Example Embodiment

[0024] Example 3
[0025] Ramie staple fiber is surface treated with coupling agent γ-glycidoxypropyltrimethoxysilane, and the soaking time is 0.5 hours. The specific treatment method is the same as the treatment of cotton fiber in Example 2.
[0026] Accurately weigh 80 parts of polylactic acid and 0.2 parts of antioxidant tetra{β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid} pentaerythritol and add them to the extruder from the main hopper. At the same time, 20 parts of the treated ramie short fiber was added to the extruder through the side feeder for extrusion and granulation, and the product was dried after drying. The rest are the same as in Example 1. The mechanical properties are shown in Table 1 in 3 # As shown, the crystallization properties are shown in Table 2 in 3 * Shown.
[0027] It can be seen from Table 1: The mechanical properties of the composite material of the present invention, such as flexural strength, flexural modulus and thermal deformation temperature, are much better than those of pure polylactic acid.
[0028] It can be seen from Table 2 that the crystallization performance of the present invention is also significantly better than that of pure polylactic acid.

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