Method for preparing metal phosphide hydrogenation refining catalyst by using hydrogen plasma reduction mehtod
A metal phosphide and plasma technology, applied in the direction of physical/chemical process catalysts, chemical instruments and methods, chemical/physical processes, etc., can solve problems such as consumption, large hydrogen, and unsatisfactory activity, and achieve wide application prospects and economical The effect of high-efficiency deep desulfurization and denitrification, high catalytic reactivity
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[0009] Specific embodiments of the present invention will be described in detail below.
[0010] Preparation of catalyst precursor
[0011] Taking the preparation of silica-supported molybdenum-sulfur-phosphorus catalyst precursor by co-impregnation method as an example, MoO 3 The loading amount is 40% (mass). Take by weighing 3.65 grams of ammonium molybdate ((NH 4 ) 6 Mo 7 o 24 .4H 2 O) and 2.729 grams of diammonium phosphate ((NH4) 2 HPO 4 ), add 10 ml of deionized water, and dissolve to make an impregnation solution. Weigh 3 grams of porous silica, add impregnation solution, and impregnate at room temperature for 12 hours. The slurry was dried at 120° C. for 12 hours, and then fired at 500° C. in air for 5 hours to obtain an oxide precursor.
[0012] Catalyst preparation
[0013] The oxide precursor is made into 0.3-0.5 mm particles by tableting, and 0.8 g is weighed and loaded into a non-equilibrium plasma reactor with an inner diameter of 8 mm. The distance b...
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