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Flame-retardant fiber sheet and formed article thereof

A fiber sheet, flame retardant technology, which is applied in the field of flame retardant fiber sheet and its molded products, can solve the problems of high price and inability to obtain flame retardancy, and achieve the effect of high water resistance and durable flame retardancy

Inactive Publication Date: 2007-12-26
NAGOYA OIL CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the above-mentioned phosphoric acid flame retardants are water-soluble, and if they come into contact with moisture, they will be dissolved from the fiber sheet, and it is impossible to obtain durable flame retardancy.
In order to impart water resistance to phosphoric acid-based flame retardants, a flame retardant is provided in which a synthetic resin film is coated on the surface of the flame retardant powder, but the price becomes very high due to the coating treatment

Method used

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  • Flame-retardant fiber sheet and formed article thereof
  • Flame-retardant fiber sheet and formed article thereof
  • Flame-retardant fiber sheet and formed article thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0115] By mixing 80% by mass of polyester fiber (denier: 12.5dtex, fiber length: 55mm) and 20% by mass of low-melting polyester fiber (softening point: 110°C, finer: 15dtex, fiber length: 50mm) The web of fibers is needle-punched to make a weight per unit area of ​​120g / m 2 fiber sheet. Next, after coating the phenol-formaldehyde initial condensate (aqueous solution of 45% by mass of solid content) as a synthetic resin binder with a coating roller so as to reach a coating amount of 30% by mass with respect to the fiber sheet, thereafter Sprinkle ammonium polyphosphate (particle size: 50-75 μm) with an average degree of polymerization of n=10, 30, and 40 on the back surface of the fiber sheet so as to reach 20% by mass, and dry it at a temperature of 130-140° C. 3 minutes. A flame-retardant fiber sheet is produced by precuring the fiber sheet while fixing the ammonium polyphosphate attached to the back of the fiber sheet. The resulting flame-retardant fiber sheet was then he...

Embodiment 2

[0119] Raised cotton is obtained by carding the regenerated fiber scraps composed of polyester or cotton into cotton form through a carding machine. Next, 50 parts by mass of novolac resin powder (particle diameter: 20 to 30 μm, melting point: 78 to 85° C.) and 50 A mixture of ammonium polyphosphate (particle size: 50-75 μm) with an average degree of polymerization of n=10, 30, and 40 in parts by mass, and then carded and mixed with the fluffed cotton to form long staples, then hot air at 150°C Pre-cured both sides of the plush to obtain a thickness of 15mm and a weight per unit area of ​​800g / m 2 flame retardant fiber sheet. Finally, the obtained flame-retardant fiber sheet was hot-press molded at a temperature of 200° C. for 60 seconds to obtain a molded product with a thickness of 5 mm.

Embodiment 3

[0123] Raised cotton is obtained by carding the regenerated fiber scraps composed of polyester or cotton into cotton form through a carding machine. Next, 50 parts by mass of novolak resin powder (particle diameter: 20 to 30 μm, melting point: 78 to 85° C.) and 5 Parts by mass of expanded graphite (particle size: 70-80 μm, expansion start temperature: 300°C, expansion rate: 300ml / g), and 45 parts by mass of ammonium polyphosphate (particles) with an average degree of polymerization of n=10, 30, 40 Diameter: 50-75μm), and then carded and mixed with the fluffed cotton to form a long pile, and the two sides of the long pile were pre-cured with hot air at 150°C to obtain a thickness of 15mm and a weight per unit area of ​​600g / m 2 flame retardant fiber sheet. Finally, the obtained flame-retardant fiber sheet was hot-press molded at a temperature of 200° C. for 60 seconds to obtain a molded product with a thickness of 5 mm.

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Abstract

The object of the present invention is to provide a fiber sheet or a molded fiber sheet having excellent flame retardancy A flame retardant fiber sheet containing a polyammonium phosphate with average degree of polymerization in the range of between 10 and 40 is provided in the present invention. The polyammonium phosphate is insoluble or sparingly soluble in water so that said polyammonium phosphate gives the fiber sheet excellent flame retardancy with water resistance and durability, and is also inexpensive. The molded fiber sheet is highly flame retardant and harmless, so that the molded fiber sheet is useful for automobile and building interiors.

Description

technical field [0001] The present invention relates to a flame-retardant fiber sheet used for automobiles or building interior materials, and its molding. Background technique [0002] In the past, as such a fiber sheet, a needle-punched non-woven fabric or a needle-punched felt obtained by intertwining a fiber web sheet by a needle punching method, and a resin-free non-woven fabric obtained by bonding a fiber web sheet by a synthetic resin, have been provided. Woven cloth or resin felt, fiber braid, etc. Such fiber sheets are required to have flame retardancy in addition to soundproofing and heat insulating properties. Conventionally, in order to impart flame retardancy to the fiber sheet, a less toxic phosphoric acid flame retardant is contained in the fiber sheet (for example, refer to Patent Documents 1, 2, and 3). [0003] Patent document: JP-A-2002-348766 [0004] Patent document: Japanese Patent Application Laid-Open No. 10-226952 [0005] Patent document: Japane...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M11/72D04H1/54D06M11/73D06M15/41
Inventor 小川正则平野司芳渡边刚
Owner NAGOYA OIL CHEM CO LTD