Laminated body used to produce printed wiring board, and method of producing printed wiring board using the same
A technology of printed circuit boards and laminates, applied in the fields of printed circuit, printed circuit, printed circuit manufacturing, etc., to achieve the effect of excellent viscosity and excellent high-frequency characteristics
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Embodiment 1 to 5
[0256] (forms an adhesive layer on the surface of the carrier)
[0257] A polyethylene terephthalate film having a thickness of 16 μm that was not subjected to surface treatment or pretreatment was prepared and used as a support for forming an adhesive layer.
[0258] Using stick #6, polymer precursor composition 1 having the following composition was coated on the support surface and dried at 100° C. for 1 minute, thereby forming a polymer precursor layer [(B) layer], wherein the polymer Precursor composition 1 includes a polymer containing acrylic group as a polymerizable compound and a carboxyl group as a reactive group (polymer containing a polymerizable group on a side chain: P-1, obtained using the synthesis example described below ) inclusive. The thickness of the polymer precursor layer is set at 0.2 to 1.5 μm.
[0259] (polymer precursor composition liniment 1)
[0260] -Hydrophilic polymer (P-1) having a polymerizable group on the side chain 3.1 g
[0261] - Wate...
specific Embodiment 1
[0266] 300 g of this reaction solution was put into a beaker, and then cooled to 5° C. with an ice bath. While stirring the reaction solution, 41.2 ml of an aqueous sodium hydroxide (4N) solution was added dropwise over about 1 hour. During the dropwise addition, the temperature of the reaction solution was 5 to 11°C. After the dropwise addition, the reaction solution was stirred at room temperature for 10 minutes, and the solid matter was removed by suction filtration to obtain a brown solution. The solution was reprecipitated with 3 liters of ethyl acetate, and the precipitated solid was filtered. The solid was resuspended overnight with 3 liters of acetone. The solid was obtained by filtration, and then dried under vacuum for 10 hours to obtain light brown powder P-1. 1 g of polymer was dissolved in a mixture solvent of 2 g of water and 1 g of acetonitrile. The pH of the solution was 5.56 and its viscosity was 5.74 cps. Viscosity was measured using a viscometer (trade ...
specific Embodiment 2
[0272] (Specific embodiment 2: form active species generation layer 2)
[0273] 5g of liquid bisphenol A epoxy resin (epoxy equivalent 176, trade name: EPIKOTE 825, produced by JapanEpoxy Resins Co., Ltd.), 2g of MEK varnish (trade name: PHENOLITE LA -7052, produced by Dainippon Ink And Chemicals, Inc., non-volatile components 62%, phenolic hydroxyl equivalent of non-volatile components 120), 10.7g phenoxy resin MEK varnish (trade name: YP-50EK35, produced by Tohto Kasei Co., Ltd. production, non-volatile content 35%), 2.3 g of 1-[4-(2-hydroxyethoxy)phenyl]-2-hydroxy-2-methylpropane- 1-Kone, 5.3 g of MEK, and 0.053 g of 2-ethyl-4-methylimidazole were mixed and stirred so as to dissolve completely, resulting in a varnish-like epoxy resin composition. This epoxy resin varnish was coated on the polymer precursor layer [(B) layer] with a coater so that the epoxy resin varnish had a thickness of 90 μm after drying. Then, the epoxy resin varnish is dried at a temperature of 80 to ...
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