Large power redox flow cell device electric pile structure
A technology for flow batteries and stacks, which is applied in fuel cell components, fuel cells, and regenerative fuel cells, etc., can solve the problems of large-scale application of stacks, difficult processing and assembly, poor flow performance, etc. Discharge loss, improving assembly efficiency and effectiveness, improving sealing performance
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[0016] According to the structure design of this patent, an all-vanadium redox flow battery stack was built, and the charging and discharging experiments were carried out. Using V4+ / V5+ and V3+ / V2+ vanadium ions as the anode and cathode active materials of the redox flow battery respectively, the half-cell electrochemical reaction in the stack is as follows.
[0017] Positive reaction
[0018]
[0019] Negative reaction
[0020] E. 0 =-0.26V
[0021] The all-vanadium redox flow battery stack is composed of four single cells in series, the effective electrode area is 200×270mm, and the positive and negative electrolytes are 800ml of 1.0mol / L V4++2mol / L H2SO4 and 1.0mol / L V3 respectively ++2mol / L H2SO4 aqueous solution, charge and discharge experiments were carried out at an electrolyte circulation flow rate of 50L / h, and the stack performance of the redox flow battery was measured at room temperature. Figure 4 is the curve of charging and discharging current and volta...
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