Method for preparing organic compound single-crystal nano structure

An organic compound, single crystal nanotechnology, applied in chemical instruments and methods, single crystal growth, single crystal growth, etc., to achieve the effects of low sublimation temperature, good reproducibility, and convenient operation

Inactive Publication Date: 2008-07-02
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, how to construct organic compounds into more complex micro-nano structures (nanotubes, nanotowers, etc.) and their arrays has not been reported yet.

Method used

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  • Method for preparing organic compound single-crystal nano structure
  • Method for preparing organic compound single-crystal nano structure
  • Method for preparing organic compound single-crystal nano structure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: Preparation of chlorocopper phthalocyanine single crystal nanostructure

[0026] Weigh an appropriate amount of chlorocopper phthalocyanine powder, put it into the quartz boat 3, put the quartz boat 3 on the bottom of the quartz tube 2; then put the quartz tube 2 into the central position of the horizontal tubular heating furnace 1, and put the quartz The open end of the tube 2 is connected to a vacuum system 5 . In the initial stage, first use the vacuum system to pump the pressure in the quartz tube 2 to 1 Pa, then use the horizontal tube heating furnace 1 to quickly heat the quartz boat 3 to 500-520 ° C, and keep it for 10 minutes to make the chlorine in the quartz boat 3 Sublimation of substituted copper phthalocyanine powder into chlorinated copper phthalocyanine vapor, and controlled sample growth substrate 4 (Si / SiO 2 The temperature of the sheet) is between 350-380 °C, and the vacuum pump is used to continuously work to cause the pressure difference ...

Embodiment 2

[0027] Example 2: Preparation of fluorinated copper phthalocyanine single crystal nanostructure

[0028] Weigh an appropriate amount of fluorinated copper phthalocyanine powder, put it into the quartz boat 3, put the quartz boat 3 on the bottom of the quartz tube 2; then put the quartz tube 2 into the central position of the horizontal tubular heating furnace 1, and put the quartz The open end of the tube 2 is connected to a vacuum system 5 . In the initial stage, first use the vacuum system to pump the pressure in the quartz tube 2 to 1 Pa, then use the horizontal tube heating furnace 1 to rapidly heat the quartz boat 3 to 450-470 ° C, and keep it for 5 minutes to make the fluorine in the quartz boat 3 Copper phthalocyanine powder is sublimated into fluorinated copper phthalocyanine vapor, and the temperature of the sample growth substrate 4 (silicon wafer) is controlled between 280-330°C, and vacuum pumps are used to continuously work to form fluorinated copper phthalocyanin...

Embodiment 3

[0030] Embodiment 3: Preparation of copper phthalocyanine single crystal nanostructure

[0031] Weigh an appropriate amount of copper phthalocyanine powder, put it into the quartz boat 3, put the quartz boat 3 on the bottom of the quartz tube 2; then put the quartz tube 2 into the central position of the horizontal tubular heating furnace 1, and place the quartz tube 2 The open end of is connected with vacuum system 5. At the initial stage, first use the vacuum system to pump the pressure in the quartz tube 2 to 1 Pa, then use the horizontal tube heating furnace 1 to rapidly heat the quartz boat 3 to 400-420 ° C, and keep it for 10 minutes to make the copper in the quartz boat 3 The phthalocyanine powder is sublimated into copper phthalocyanine vapor, and the temperature of the sample growth substrate 4 is controlled between 250-280°C, and the continuous operation of the vacuum pump is used to cause the pressure difference of the copper phthalocyanine vapor in different temper...

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Abstract

The invention discloses a method for preparing single crystal nanostructure of an organic compound, which comprises the following steps of: (1) disposing a substrate and a quartz boat loaded with an organic compound powder into a quartz tube, connecting the quartz tube with a vacuum system and vacuuming the quartz tube to a pressure 10<-2> to -5 Pa; and (2) heating the quartz boat to the sublimation temperature of the organic compound and heating the substrate to a temperature lower than the sublimation temperature of the organic compound by 130 to 180 DEG C, keeping the vacuum degree in the quartz tube and growing the crystal nanostructure of the organic compound on the substrate. The invention is simple and easy and can obviate the use of a template and a catalyst. The obtained nanostructure has good crystallization, no defect, high purity and better test reproducibility.

Description

technical field [0001] The invention relates to a method for preparing an organic compound single crystal nanostructure. Background technique [0002] Due to their unique properties, nanomaterials not only have huge potential application prospects in electronics, optics, mechanics and other devices, but also have great potential for basic research in the fields of chemistry, physics, electronics, optics, materials science and biological sciences. Profound significance. In recent years, with the development of nanotechnology, the preparation of inorganic and semiconductor nanomaterials has been greatly developed. However, due to the high-temperature instability of organic molecules, the construction of organic compound nanostructures and nanostructure arrays is still a current research topic. difficulty. Recently, it has been reported that copper phthalocyanine and fluorophthalocyanine copper nanobelts and nanowires were prepared by physical vapor deposition of carrier gas,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B29/54C30B23/00
Inventor 王春儒闫东伟刘伟
Owner INST OF CHEM CHINESE ACAD OF SCI
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