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Method for producing water-proof salmon leather

A production method, salmon technology, applied in special leather manufacturing, small raw hide/big raw hide/leather/fur treatment, small raw hide/large raw hide/leather skin/fur chemical treatment, etc., can solve fish skin pattern without special finishing , Salmon leather has not been waterproofed, poor practicality and durability, etc.

Inactive Publication Date: 2008-08-13
李宏强
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 1998, Shi Xuelin and others studied the structural characteristics of salmon skin, and introduced the processing technology of salmon leather ("Research on the development of salmon leather", "China Leather" 1998 No. 04), according to this technology. The salmon leather produced has no special waterproof treatment, which cannot meet the waterproof and washable properties of leather products, so the practicability and durability are not good
In 2005, people such as Zhang Jingbin also proposed a kind of technique that utilizes salmon skin to make full-bodied leather ("Study on the process of making full-bodied leather with salmon skin", "China Leather" 2005 No. 21), although in this process It is mentioned that after retanning, fatliquoring is used to endow salmon leather with a certain degree of water resistance. However, since the fiber layer of the leather itself has not been waterproofed, the waterproof effect is not long-lasting, and the purpose of making the leather truly waterproof cannot be achieved.
However, in the existing salmon leather preparation process, the fish skin pattern has not been specially arranged, and the aesthetic effect cannot be achieved; even in some processes, the fish skin is usually pressed by a scalding machine for many times, and the natural texture on the fish leather The fish scale pattern is crushed to death, coupled with the coating, it is impossible to achieve the natural beauty of the fish scale pattern, and the characteristics of opening and closing freely, but the grade of the fish leather is lowered.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0082] Embodiment 1, preparation waterproof tanning agent

[0083] Multi-chain alkyl acrylate (purchased from Shenyang Reagent Industry Corporation), unsaturated anhydride ester (purchased from Shanghai Jiachen Chemical Co., Ltd.) and N-methylol benzamide (commercially purchased) were mixed according to the ratio of 10:6:8. The weight ratio is fully mixed, and then add polyalkylene acrylate, unsaturated anhydride ester and N-methylol benzamide about 8 times the total weight of hot water at a temperature of 80-100°C for emulsification, stir and mix several times, and Add formic acid dropwise under stirring state to reduce the pH value until the pH value is reduced to about 1.5 and stop (the amount of formic acid added dropwise is about 1% of the total mass of the waterproof tanning agent), and cooling at room temperature can obtain the waterproof tanning agent of the present invention .

Embodiment 2

[0084] Embodiment 2, the production technology of waterproof salmon leather (one)

[0085] The scaled salmon skin raw materials are grouped in batches according to size and thickness, weighed, and put into the drum (in this embodiment, the rotating speed of the drum is about 25 revolutions per minute), and the order is operated according to the following procedures:

[0086] Cleaning: Add about 300% water of fish skin weight, about 3% degreasing agent EDS (purchased from Derun Company (Germany)), about 2% soda ash into the drum, turn for about 30 minutes, and drain;

[0087] Soaking in water: Add about 300% water, soak for about 24 hours, and rotate for about 10 minutes every 2 hours, drain;

[0088] Descaling: Add about 200% of water, about 0.4% of BSU (purchased from Heim (Italy)), about 0.5% of THL enzyme (purchased from BASF (Germany)), 0.7% brightener JFO (purchased Rotate from Heim Company (Italy)) for about 1 hour, drain;

[0089] Decolorization: Add about 200% of wat...

Embodiment 3

[0108] Embodiment 3, the production technology of waterproof salmon leather (two)

[0109] Take the raw material of salmon skin with scales, and follow the steps below:

[0110] Batch formation: the scaled salmon skin raw materials are formed into batches according to size and thickness, and weighed;

[0111] Cleaning: Put the batches of fish skins into the drum, add about 200% water, about 5% degreasing agent EDS (purchased from Derun Company (Germany)), 2% soda ash, and turn for about 30 minutes. drainage;

[0112] Soaking in water: add about 300% water to the drum, soak for about 24 hours, and turn it for 10 minutes for 2 hours to drain;

[0113] Descaling: add about 200% water to the drum, about 1% BSU (purchased from Heim (Italy)), 0.5% THL enzyme (purchased from BASF (Germany)), 2% whitening agent JFO (purchased from Heim Company (Italy)), rotate for about 1 hour, drain;

[0114] Decolorization: add about 100% water, add about 3% decolorizer DO (purchased from Heim C...

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PUM

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Abstract

The invention provides a production method for a waterproof salmon leather, which performs waterproof treatment to the leather during the tanning process with a specific waterproof tanning agent, the waterproof tanning agent is got by mainly mixing acrylic acid multi-chain alkyl ester, unsaturated anhydride ester and N-hydroxymethyl benzamide in weight proportion of 8-12: 5-7:6-10, emulsifying with water, and then dipping formic acid to adjust the pH value to about 1.4-1.6. After the leather is tanned by the waterproof tanning agent, water-repellent group forms between fibers, the waterproof ability of the leather and the final leather product has improved, and the contractibility of the leather and the structure stability of the fiber can also be increased. The production method of the invention also has special treatment to the surface pattern of the leather, which makes the leather both beautiful and waterproof.

Description

technical field [0001] The invention relates to a production process of waterproof fish leather, in particular to a production method for producing waterproof salmon leather by tanning and finishing processes on salmon skin. Background technique [0002] Salmon (or salmon, rainbow trout, Salmon) is abundant in my country, and it is usually processed into refined meat products for export in large quantities to earn foreign exchange. The leftover fish skin that is eliminated during the processing process is too strong due to the fishy smell. People don't like to eat it and are abandoned, so they can't earn foreign exchange. If these fish skins can be utilized and turned into wealth, it will have very practical significance. [0003] Because salmon skin has a unique natural and beautiful appearance and natural patterns, if it is processed into leather, it is used to make leather products such as clothing, belts, ties, bags, wallets, or other decorations. It not only has use val...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C14C13/00
Inventor 李宏强
Owner 李宏强
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