Nonuniform cemented carbide for hot extruding hot die and method for preparing same

A technology of cemented carbide and hot pier, which is applied in the field of cemented carbide and its preparation technology, can solve the problems of weak oxidation resistance, poor impact toughness, and high temperature resistance, so as to improve fracture strength and toughness, reduce porosity, Effect of increasing hardness and wear resistance

Inactive Publication Date: 2008-10-15
ZHUZHOU JINGGONG CEMENTED CARBIDE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is mainly aimed at cemented carbide used in the manufacture of snow shoveling flakes. Due to its low cobalt content of only 11-12%, the particle size of the main tungsten carbide powder is fine (9.01-13 μm), although it can meet the working state requirements of snow shoveling flakes. It also meets the strength requirements for making hot heading hot punching dies, but its impact toughness is poor, and its composition is pure tungsten carbide-cobalt, which is not resistant to high temperature and has weak oxidation resistance, so it is not suitable for making cemented carbide hot heading dies. further improvement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A cemented carbide for hot stamping die products, the composition and weight percentage of the alloy are: 15% of cobalt powder, 5% of nickel powder, 60% of 25um tungsten carbide powder, and 20% of 1.0um tungsten carbide powder.

[0020] The preparation method of the above-mentioned cemented carbide for hot pier and hot stamping die products is to take each raw material in proportion, mix the powder evenly, and form a mixture. In the type wet mill, alcohol is used as the medium for wet milling, the ball-material ratio is 4:1, the liquid-solid ratio is 450ml / kg, the ball mill speed is 36r / min, the milling time is 24 hours, and the milled slurry is dried 1. After pressing and molding, dewaxing and vacuum sintering are carried out in an integrated furnace. The sintering temperature is 1470° C. and the holding time is 60 minutes to obtain the product. The properties of the obtained product are: hardness 85.5HRA, bending strength 2700MPa.

Embodiment 2

[0022] A cemented carbide for hot stamping die products, the composition and weight percentage of the alloy are: 12% of cobalt powder, 3% of nickel powder, 70% of 25um tungsten carbide powder, and 15% of 1.0um tungsten carbide powder.

[0023] The preparation method of cemented carbide for the above-mentioned hot pier hot stamping die products is to take each raw material in proportion, mix the powder evenly, and form a mixture. The weight of the mixture is 300Kg. In the wet mill, use alcohol as the medium for wet grinding, the ball-to-material ratio is 4:1, the liquid-solid ratio is 450ml / kg, the ball mill speed is 36r / min, and the grinding time is 24 hours. The ground slurry is dried, After pressing and molding, dewaxing and vacuum sintering are carried out in an integrated furnace. The sintering temperature is 1470°C and the holding time is 60 minutes. The performance of the product is: hardness 88.0HRA, bending strength 2850MPa.

Embodiment 3

[0025] A cemented carbide for hot stamping die products, the composition and weight percentage of the alloy are: 18% of cobalt powder, 5% of nickel powder, 65% of 25um tungsten carbide powder, and 12% of 1.0um tungsten carbide powder.

[0026] The preparation method of the above-mentioned cemented carbide for hot pier and hot stamping die products is to take each raw material in proportion, mix the powder evenly, and form a mixture. The weight of the mixture is 300Kg. In the wet mill, use alcohol as the medium for wet grinding, the ball-to-material ratio is 4:1, the liquid-solid ratio is 450ml / kg, the ball mill speed is 36r / min, and the grinding time is 24 hours. The ground slurry is dried, After pressing and molding, dewaxing and vacuum sintering are carried out in an integrated furnace. The sintering temperature is 1470°C and the holding time is 60 minutes. The performance of the product is: hardness 84.5HRA, bending strength 2750MPa.

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Abstract

The invention discloses a material for a hot heading die and a preparation process thereof. The compositions by weight percentage of the material are: 12 to 20 percent of cobalt, 3 to 10 percent of nickel, 50 to 70 percent of tungsten carbide with 20 to 25mu m, 10 to 30 percent of tungsten carbide with 1.0 to 1.5mu m. The preparation method for the material comprises the following steps: a step of mixing, during which the raw materials are taken in proportion and mixed evenly to obtain a mixture; a step of wet-grinding of the mixture, which is carried out inside a ball mill by using alcohol or acetone as the medium with a rotating speed of 36r / min and a grinding time of between 20 and 30 hours under the condition that the mixture is in accordance with the ratio of balls and the materials of 3-5 to 1, and the liquid-to-solid ratio of the mixture is 450-520ml / kg; a step of drying and press forming, and sintering in a vacuum furnace, thus the product is obtained. The invention uses the uneven structure theory of the hard alloy material, under the condition of certain content of cobalt in alloy, the fracture intensity and toughness of the alloy can be improved by reasonably collocating the proportion of coarse tungsten carbide powder and fine tungsten carbide powder, and inevitably the hardness and wear resistance can be improved thereafter. The different proportion between cobalt and nickel can obtain alloys with different impacting toughness and wear resistance. Furthermore, nickel powder is favorable to improve high-temperature oxidation resistance of the alloy.

Description

technical field [0001] The invention relates to a hard alloy and a preparation process thereof, in particular to a material for a high-strength and wear-resistant hot pier hot stamping die and a preparation process thereof. Background technique [0002] Because of its high strength and high hardness, cemented carbide is known as the tooth of industry and is a widely used tool material. However, the common technical problem of current cemented carbide products is how to organically combine the advantages of high strength and high hardness. When the alloy has high strength, it often has low hardness and poor wear resistance. When it has high hardness, it often has low strength. Poor toughness. How to realize the simultaneous realization of high strength and high hardness as much as possible to meet the special requirements of various construction machinery, rock drilling tools, and wear-resistant parts has always been the goal and direction of cemented carbide research. At p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C29/08C22C1/00
Inventor 陈明
Owner ZHUZHOU JINGGONG CEMENTED CARBIDE
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