Anaerobic oxygen rubber composition

A composition, anaerobic adhesive technology, applied in the direction of adhesives, adhesive types, ester copolymer adhesives, etc., can solve the problems of strong, toxicity, etc., achieve the effect of low odor, low volatility, and improve the working environment

Inactive Publication Date: 2008-12-24
GUANGDONG HENGDA NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such as U.S. US4287330, US43801613 and Chinese patent CN1057787C, CN1248281A, CN1328103A, the oxidizing agents such as cumene hydroperoxide and tert-butyl hydroperoxide adopted by the anaerobic adhesive disclosed in CN1248281A and CN1328103A just have strong pungent smell and corrosiveness, and U.S. Patent US3188229, US4007323 and Chinese patent CN1226589A, CN1232068A disclosed anaerobic adhesive used reducing agent used amines such as triethylamine, tributylamine, N, N-dimethyl p-toluidine, these materials not only have Strong amine odor, but also has some toxicity

Method used

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Experimental program
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Effect test

Embodiment 1

[0032] According to the number of parts by mass, 51 parts of triethylene glycol dimethacrylate and 45.67 parts of epoxy methacrylate were added to the reactor, and then 0.1 part of hydroquinone as a polymerization inhibitor, 0.1 part of chelating agent ethylenediaminetetraacetic acid di 0.15 parts of sodium, stir and heat to 60-70°C, and react for 2-3 hours. Cool to 50-55°C, add 0.45 parts of benzohydrazide, 1.1 parts of o-sulfonyl benzimide, 1.5 parts of dicumyl peroxide and 0.02 parts of 1,2,3,4-tetrahydroquinoline in sequence , and stir until completely dissolved. Finally, add 0.01 part of oil soluble red and stir evenly. After passing the inspection, it can be packaged as a finished product.

Embodiment 2

[0034] According to the number of parts by mass, 50 parts of triethylene glycol dimethacrylate and 43.9 parts of epoxy methacrylate were added to the reactor, and then 0.08 parts of polymerization inhibitor p-benzoquinone and chelating agent disodium edetate were added. 0.2 parts, stirred and heated to 60-70°C, and reacted for 2-3 hours. Cool to 50-55°C, add 0.55 parts of N-acetylphenylhydrazine, 1.55 parts of o-sulfonyl benzimide, 1.7 parts of dicumyl peroxide and 0.02 parts of 1,2,3,4-tetrahydroquinoline portion, and stir until completely dissolved. Finally, add 2 parts of fumed silica and stir evenly. After passing the inspection, it can be packaged as a finished product.

Embodiment 3

[0036] According to the number of parts by mass, 46 parts of triethylene glycol dimethacrylate and 44.54 parts of epoxy methacrylate were added to the reactor, and then 0.08 parts of hydroquinone as a polymerization inhibitor, 0.08 parts of chelating agent ethylenediaminetetraacetic acid di 0.12 parts of sodium, stir and heat to 60-70°C, and react for 2-3 hours. Cool to 50-55°C, add 0.55 parts of benzohydrazide, 1.8 parts of o-sulfonyl benzimide, 1.85 parts of 1,4-bis-tert-butylperoxycumene and 6-methyl-1 , 0.05 parts of 2,3,4-tetrahydroquinoline, stirred until completely dissolved. Finally, add 0.01 part of oil soluble blue and 5 parts of castor oil, and stir evenly. After passing the inspection, it can be packaged as a finished product.

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Abstract

The invention relates to an adhesive compound with an anaerobic curing nature. An anaerobic adhesive compound comprises the following compositions according to the following mass percentage: 70 to 98 percent of a monomer or oligomer containing vinyl, 0.01 to 0.05 percent of a chelating agent, 0.5 to 5 percent of an organic peroxide initiator, 0.1 to 1 percent of organic hydrazide, 0.3 to 5 percent of saccharin, 0.01 to 0.5 percent of an inhibitor, and 0.001 to 0.5 percent of 1, 2, 3, 4-tetrahydroquinoline or derivatives thereof. The monomer used in the invention consists of acylic ester or methacrylic acid ester containing one to a plurality of base groups of -OH, -OCH3, -OCH2CH2-. The anaerobic adhesive compound which is characterized in low volatility, low odor and low toxicity can be widely applied to the locking and sealing of threads or the retention of cylindrical parts.

Description

technical field [0001] The present invention relates to adhesive compositions having anaerobic curing properties. Background technique [0002] The research on anaerobic adhesives began in the 1940s. The first practical variety was reported in the United States in 1953. After that, the technology became more and more perfect. In the mid-1960s, the American Loctite Company commercialized the product. Although companies from various countries have competed with it in the past ten years, Loctite is still the largest producer of anaerobic adhesives in the world, accounting for more than 80% of the total sales. Other manufacturers include companies such as Three Bond and 3M. The development of anaerobic adhesives in my country began in the early 1970s, and the first practical variety was developed in 1972 (XQ-1 Dalian), which promoted the attention and application of anaerobic adhesives by the Ministry of Machinery Industry. In the following ten years, Jinan (BN), Shanghai (Anc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/06C09J9/00C09K3/10
Inventor 刘运洪
Owner GUANGDONG HENGDA NEW MATERIALS TECH
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