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Pulp for lithium ionic cell electrode and manufacturing method thereof

A lithium-ion battery and slurry technology, applied in battery electrodes, electrode manufacturing, active material electrodes, etc., can solve the problems of reducing the main component content of slurry, delamination, dry material splashing, etc., and achieve improved storage stability , Conducive to uniform distribution, improve the effect of performance

Active Publication Date: 2009-03-25
ZHENGZHOU BAK BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, the above process has the following problems in the actual preparation process: 1) It is easy to cause the dry material to splash when the powder is mixed. On the one hand, it will cause environmental pollution and affect the health of the operator. On the other hand, the actual slurry formula will deviate from the design. 2) In the homogenization step, although the slurry can be temporarily uniformed, because it does not separate the agglomerated material particles in the slurry, it will be stored for a period of time. Finally, the slurry will appear delamination phenomenon, that is, the stability of the slurry is not good; 3) The slurry preparation time is long and the efficiency is not high
The above defects will affect the quality of lithium-ion battery products
[0010] In addition, in the patent documents published by the Chinese Patent Office, there are some methods of changing the distribution ratio of the components of the slurry or adding other additives to achieve better uniformity, such as increasing the proportion of the binder, or adding a certain amount of slurry at the same time. A small amount of dispersant, etc., so that the agglomerated material particles can be well separated when the slurry is mixed, but this method reduces the content of the main components of the slurry, and also increases the production cost of the slurry

Method used

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  • Pulp for lithium ionic cell electrode and manufacturing method thereof
  • Pulp for lithium ionic cell electrode and manufacturing method thereof
  • Pulp for lithium ionic cell electrode and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Weigh 0.3Kg polyvinylidene fluoride (PVDF), weigh the solvent N-methylpyrrolidone (NMP) according to the concentration of 8% PVDF glue and add it to the rubber tube, adjust the speed to 2000 rpm and stir for 45 minutes to make polyvinylidene Vinyl fluoride is completely dissolved to form a colloid. Then take by weighing 0.2Kg acetylene black as the conductive agent and add in the rubber tube, stir at a speed of 3000 rpm for 30 minutes to make the conductive glue, then weigh 10Kg lithium cobaltate and the conductive glue prepared in front and 0.6Kg of solvent N- Add methylpyrrolidone into the mixing tank together, stir at a low speed of 200 rpm and a high speed of 2500 rpm for 30 minutes to form a premixed slurry, and continuously input the prepared premixed slurry into a disperser with a slurry pump for dispersion ( The FM-80-50 model disperser produced by Japan T.K.FILMICS company is used, the rotation speed is 10000 rpm, and the dispersion time is set to 60 seconds), ...

Embodiment 2

[0048] Weigh 0.6Kg polyvinylidene fluoride (PVDF) according to the concentration of 10% PVDF glue, weigh the solvent dimethylformamide (DMF) and add it to the rubber tube, adjust the speed to 3000 rpm and stir for 60 minutes to completely dissolve the PVDF Colloid is obtained. Take 0.4Kg acetylene black as conductive agent and add in the plastic tube, stir at a speed of 4000 rpm for 45 minutes to obtain conductive glue, then weigh 10Kg lithium iron phosphate and the aforementioned conductive glue prepared and 6.6Kg Add the solvent dimethylformamide into the mixing tank together, stir at a low speed of 150 rpm and a high speed of 3000 rpm for 30 minutes to form a premixed slurry, and continuously input the prepared premixed slurry into the disperser with a slurry pump Disperse (the FM-80-50 model disperser produced by Japan T.K.FILMICS company is adopted, the rotation speed is 15000 rpm, and the dispersion time is set as 30 seconds), and the dispersed slurry is continuously outp...

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Abstract

A sizing material for electrodes of a lithium ion battery mainly comprises an active material, a conductive agent, an adhesive and a solvent, and is characterized in that the distribution ratio of the active material, the conductive agent, the adhesive and the solvent is 100 : 0-4 : 1-7 : 35-100. The preparation process thereof comprises the following steps: 1) mixing the adhesive with partial solvent to prepare a glue body with the viscosity of 1 to 10 percent; 2) mixing the conductive agent weighed according to the distribution ratio with the glue body prepared in the step 1) and stirring to form a conductive glue; 3) mixing the active material and the rest solvent weighed according to the distribution ratio with the conductive glue and stirring to form a premixed sizing material; 4) introducing the premixed sizing material into a dispersion machine rotating at a high speed to conduct dispersion; 5) cooling and vacuumizing the dispersed sizing material to form the sizing material for the electrodes of the lithium ion battery. The sizing material has the better use performance, and the preparation method thereof solves the defect in the traditional mixture that the layering of the conductive agent is easily caused by a larger density difference when the conductive agent is mixed with the active material and the like, thereby ensuring the uniform distribution of each ingredient of the sizing material.

Description

【Technical field】 [0001] The invention relates to the field of manufacturing lithium ion batteries, in particular to a slurry for lithium ion battery electrodes and a preparation method for the slurry. 【Background technique】 [0002] Lithium-ion batteries will be the preferred power source for mobile electronic products for a long period of time due to their advantages such as high volume specific energy, long service life, environmental protection, high voltage and high safety. It is formed by sealing a positive electrode group, a negative electrode group, a diaphragm for conducting ions and blocking electrons, and a non-aqueous electrolyte in a casing. The positive and negative electrode groups are respectively made of positive and negative electrode active materials, conductive agents, binders and solvents, etc., which are homogenized into a uniform slurry, uniformly coated and / or filled on the collector, dried and rolled. When the battery is charging, lithium ions are e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/02H01M4/58H01M4/48H01M4/38H01M4/62H01M4/04
CPCY02E60/10
Inventor 方送生
Owner ZHENGZHOU BAK BATTERY CO LTD
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