Metal salt-converting method for treating high concentration phosphor-containing wastewater
A treatment method and high-concentration technology, applied in the direction of oxidation water/sewage treatment, water/sewage treatment, chemical instruments and methods, etc., can solve the problem that the P content cannot meet the national discharge standards, and achieve the effect of low treatment and operation costs
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Embodiment 1
[0020] On October 20, 2008, the high-concentration P-containing wastewater discharged from the chemical gold line in the workshop entered the collection tank for treatment, and the following process steps were adopted:
[0021] 1. Catalytic oxidation reaction: The PH value in the wastewater is tested to be 1.0~1.5, and the total phosphorus content is about 85~100mg / L. After the wastewater is filled with the oxidation sedimentation tank, the aeration is turned on (the amount of air blasting is 0.12M 3 / S), using temperature control and automatic dosing system to add steam and calcium hydroxide (steam addition 0.2T / M 3 , the amount of calcium hydroxide added is 0.8g / L), the temperature of the wastewater is adjusted to 30°C, and the pH value is adjusted to 2.5; according to the volume of the tank, ferrous sulfate (4.0KG / M 3 ) and hydrogen peroxide (5.5KG / M 3 ), the wastewater is fully mixed and reacted for 1 hour in the oxidation sedimentation tank, the aeration is stopped for 1...
Embodiment 2
[0025] On October 27, 2008, the high-concentration P-containing wastewater discharged from the chemical gold wire in the workshop entered the collection tank for treatment, and the following process steps were adopted:
[0026] 1. Catalytic oxidation reaction: The PH value in the wastewater is tested to be 1.0-1.5, and the total phosphorus content is about 85-100mg / L. After the wastewater is filled with the oxidation sedimentation tank, open the air (air blasting volume is 0.12M 3 / S), using temperature control and automatic dosing system to add steam and calcium hydroxide (steam addition 0.3T / M 3 , the amount of calcium hydroxide added is 1.0g / L), the temperature of the wastewater is adjusted to 35°C, and the pH value is adjusted to 3.3; according to the volume of the tank, ferrous sulfate (4.5KG / M 3 ) and hydrogen peroxide (6.25KG / M 3 ), the wastewater is fully mixed and reacted for 1 hour in the oxidation sedimentation tank, the aeration is stopped for 1.0 hour of precipit...
Embodiment 3
[0030] On November 5, 2008, the high-concentration P-containing wastewater discharged from the chemical gold line in the workshop entered the collection tank for treatment, and the following process steps were adopted:
[0031] 1. Catalytic oxidation reaction: The PH value in the wastewater is tested to be 1.0-1.5, and the total phosphorus content is about 85-100mg / L. After the wastewater is filled with the oxidation sedimentation tank, the aeration is turned on (the amount of air blasting is 0.12M 3 / S), using temperature control and automatic dosing system to add steam and calcium hydroxide (steam addition 0.4T / M 3 , the amount of calcium hydroxide added is 1.2g / L), the temperature of the wastewater is adjusted to 38°C, and the pH value is adjusted to 4.0; according to the volume of the tank, ferrous sulfate (5.0KG / M 3 ) and hydrogen peroxide (7.0KG / M 3 ), the wastewater is fully aerated and mixed for one hour in the oxidation sedimentation tank, then the aeration is stoppe...
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