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Waste paper deinking pulp chlorine-free bleaching method

A technology for deinking pulp and chlorine-free bleaching of waste paper, applied in pulp bleaching, processing waste paper, papermaking, etc., can solve the problems of reduced bleaching effect and low efficiency, and achieve good bleaching effect, reduce consumption, and prevent fouling.

Inactive Publication Date: 2010-07-21
JIANGXI SCI & TECH NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hydrogen peroxide is a commonly used chlorine-free oxidative bleaching agent. The main decomposition products are water and oxygen. Its use can reduce environmental pollution, but compared with bleaching virgin pulp, it is less effective when used in waste paper deinking pulp. Moreover, metal ions will decompose hydrogen peroxide during the bleaching process in alkaline, reducing the bleaching effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A chlorine-free bleaching method for waste paper deinking pulp:

[0016] First prepare liquid A, which is composed of the following raw materials by weight percentage: disodium edetate 6%, sodium polyacrylate 7%, diethylenetriaminepentaacetic acid 6%, hydroxyethylidene diphosphonic acid 8%, diethylenetri Amine pentamethylene phosphonic acid 5%, mix according to the proportion, adjust the pH value to 6.0 to 6.5 with sodium hydroxide, add deionized water to 100%, and set aside;

[0017] The preparation of bleaching liquid, the sodium hydroxide of the 37-42 Baume degree that the amount is 1.5-2.0% of the waste paper deinking dry pulp, the sodium silicate that the amount is 1.5-2.0% of the waste paper deinking dry pulp, the amount Mix 1.5-2.5% hydrogen peroxide for waste paper deinking dry pulp, then add 10-15% hydrogen peroxide A liquid and stir together;

[0018] 3. In the hydrogen peroxide bleaching section of the waste paper deinking pulp, at a temperature of 60-65°C, ...

Embodiment 2

[0020] A chlorine-free bleaching method for waste paper deinking pulp:

[0021] First prepare liquid A, which is composed of the following raw materials by weight percentage: 7% disodium edetate, 7% sodium polyacrylate, 7% diethylenetriaminepentaacetic acid, 9% hydroxyethylidene diphosphonic acid, diethylenetri Amine pentamethylene phosphonic acid 7%, mix according to the proportion, adjust the pH value to 6.0 to 6.5 with sodium hydroxide, add deionized water to make it 100%, and set aside;

[0022] Others are the same as in Example 1.

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PUM

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Abstract

A waste paper deinking pulp chlorine-free bleaching method includes preparing A solution, which contains the components with the following weight percentage: 6 to 8 percent of EDTA, 7 to 10 percent of sodium polyacrylate, 6 to 9 percent of DTPA, 8 to 12 percent of hydroxyethylidene diphosphonic acid, 5 to 8 percent of DTPMPA, and residual deionized water; preparing a bleaching solution, which proportionally mixes sodium hydroxide, sodium silicate, hydrogen peroxide and A solution; directly mixing waste paper deinking pulp and bleaching solution according to 1:1-1.1 weight ratio under certain conditions in the hydrogen peroxide bleaching section; finally bleaching for 60 to 90 minutes. The waste paper deinking pulp chlorine-free bleaching method can prevent the reaction between metal ions and hydrogen peroxide and reduce the catalytic decomposition of hydrogen peroxide and the consumption of sodium silicate so as to prevent sodium silicate from forming dirt and system plant fiber from twisting, reduce flocculation and achieve dispersion effect and better bleaching effect.

Description

technical field [0001] The invention relates to a chlorine-free bleaching method of waste paper deinked pulp. Background technique [0002] Newspapers and office waste paper are important renewable resources, and the recycling of waste paper is an effective way to solve the shortage of resources, energy waste and serious pollution faced by the paper industry. The recycled pulp after waste paper is shredded, because the whiteness of the paper is reduced in the process of shredding and deinking, so the bleaching of waste paper deinked pulp has always been an important issue in the paper industry. Waste paper is a mixture of different fibers, dyes, sizing agents, fillers, etc. Waste paper deinking pulp is more difficult to bleach than virgin pulp. Hydrogen peroxide is a commonly used chlorine-free oxidative bleaching agent. The main decomposition products are water and oxygen. Its use can reduce environmental pollution, but compared with bleaching virgin pulp, it is less effec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21C9/10D21C5/02
CPCY02W30/64
Inventor 肖伟洪张青谢小红曾庆乐曹远亮
Owner JIANGXI SCI & TECH NORMAL UNIV
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