TiO2 nanotube with molecular imprinting functionalization

Abstract

The invention discloses a TiO2 nanotube with molecular imprinting functionalization and relates to a TiO2 nanotube with inorganic semiconductor film modification of organic pollutant imprinting; wherein, the imprinting matrix material is an inorganic semiconductor; and the imprinting molecule is an organic pollutant. The molecular imprinting polymer synthesized by molecular imprinting technology which adopts inorganic nano material as imprinting matrix has high mechanical strength and the identification point is not easy to be damaged. As an absorptive carrier, the TiO2 nanotube greatly reduces nonspecific absorption and reduces embedding phenomenon, thus having very optimistic development prospect in the aspects of photocatalysis, mimic enzymes, sensors and biometric identification, etc.

Description

technical field [0001] The invention relates to a novel structure of imprinted functionalized TiO 2 nanotube material. Background technique [0002] Due to the weak chemical reaction functionality and hydrophobicity of most organic pollutant molecules, the hydrophilic TiO 2 The surface adsorption is very low, which is also the use of TiO 2 Eliminate one of the bottlenecks of hydrophobic organic pollutants, thus enhancing the organic pollutants in TiO 2 The adsorption research on the surface of photocatalytic materials is very important for the efficient reduction of organic pollutants. Molecular imprinting technology, an artificial biological template technology that simulates antibody-antigen specific recognition and binding, has aroused everyone's interest. In this technique, template molecules (imprinted molecules) form stable molecules with one or more functional monomers through covalent bonds or non-covalent interactions such as hydrogen bonds, van der Waals forces...

AI Technical Summary

Problems solved by technology

However, the organic polymer imprinted matrix is ​​modified TiO 2 There are some problems when used in photocatalysis: imprinted polymer covered in TiO 2 Surface-affected TiO 2 Light absorption and charge transport; the imprinted polymer will degrade during the photocatalytic process; the organic polymer imprinted matrix has poor mechanical and thermal stability, resulting in unstable shape memory

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