Modified environment-friendly polyolefin material and preparation method thereof

A polyolefin and polyolefin resin technology, applied in the field of modified environmentally friendly polyolefin materials and their manufacturing, can solve the problems of unsatisfactory degradability, bending tensile modulus, notched impact strength, UV resistance, heat resistance, and heat resistance. The mechanical properties and degradability of impact are not very good, and it has not been promoted and applied, so as to achieve the effect of excellent coloring performance, superior performance and increased impact strength

Inactive Publication Date: 2009-09-16
鹏马环保塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Existing products made of polypropylene resin or polyethylene resin are all injection molded with pure polypropylene resin or polyethylene resin. , The mechanical properties and degradability of resisting cold and heat shock are not very good, especially as people pay more and more attention to environmental protection, the requirements for the degradation performance of plastic products are getting higher and higher. Therefore, the traditional polypropylene resin or products made of polyethylene resin are increasingly subject to market and government restrictions
Although some degradable polypropylene resin or polyethylene resin products have appeared at present, they have not been widely promoted and applied due to their unsatisfactory degradability and other properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Wood powder 40Kg

[0027] Polypropylene resin 43.5Kg

[0028] Maleic anhydride grafted polypropylene 3Kg

[0029] Nano calcium carbonate 10Kg

[0030] Oxidized polypropylene wax 3Kg

[0031] Antioxidant AO_2 0.5Kg

[0032] Prepare polypropylene resin particles, wood flour, nano calcium carbonate, oxidized polypropylene wax, antioxidant AO_2, maleic anhydride grafted polypropylene (coupling agent) according to the above weight; Mixing; after mixing, use a twin-screw machine to extrude at a temperature of 150°C to form granules; then dry the granules completely at 110°C, and pack them into bags for later use. In the above proportioning, the same effect can be achieved by replacing the wood flour with the same weight of grain flour, bamboo flour, sugarcane stalk fiber powder or corn stalk fiber powder and mixtures thereof.

Embodiment 2

[0034] Grain Flour 48Kg

[0035] Polypropylene resin 34.5Kg

[0036] Maleic anhydride grafted polypropylene 5Kg

[0037] Nano calcium carbonate 8Kg

[0038] Oxidized polypropylene wax 4Kg

[0039] Antioxidant AO_2 0.5Kg

[0040] Prepare polypropylene resin particles, grain flour, nano calcium carbonate, oxidized polypropylene wax, antioxidant AO_2, maleic anhydride grafted polypropylene (coupling agent) according to the above weight; Mixing; after mixing, extrude into granules with a twin-screw machine at a temperature of 160°C; then dry the granules completely at 120°C, and pack them into bags for later use. In the above proportioning, the same effect can be achieved by replacing the wood flour with the same weight of wood flour, bamboo flour, sugarcane stalk fiber powder or corn stalk fiber powder and mixtures thereof.

Embodiment 3

[0042] Bamboo Powder 56Kg

[0043] Polyethylene resin 26.7Kg

[0044] Maleic anhydride grafted polypropylene 6Kg

[0045] Nano calcium carbonate 6Kg

[0046] Oxidized polypropylene wax 5Kg

[0047] Antioxidant AO_2 0.3Kg

[0048] Prepare polyethylene resin particles, bamboo powder, nano-calcium carbonate, oxidized polypropylene wax, antioxidant AO_2, maleic anhydride grafted polypropylene (coupling agent) according to the above weight; Mixing; after mixing, extrude into granules with a twin-screw machine at a temperature of 175°C; then dry the granules completely at 130°C, and pack them into bags for later use. In the above-mentioned proportioning, the same effect can be achieved by replacing the wood flour with the same weight of wood flour, grain flour, sugarcane stalk fiber powder or corn stalk fiber powder and mixtures thereof for the bamboo powder.

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PUM

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Abstract

The invention discloses a modified environment-friendly polyolefin material which comprises components with the following weight percentages: 40 percent to 70 percent of vegetable fiber, 20 percent to 50 percent of polyolefin resin, 3 percent to 8 percent of coupling agent, 3 percent to 10 percent of nano calcium carbonate, 3 percent to 5 percent of polypropylene oxide wax and 0.3 percent to 0.5 percent of antioxidant. The preparation method comprises the following steps of: preparing materials, mixing the materials at high speed, granulating and drying for later use. The polyolefin material can not only be biochemically degraded in nature, but also can be chemically degraded by chemical fertilizers, is in accord with the general orientation of environmental protection, fully meets the requirements of European ROHS, reaches the toy safety standard of EN71 / ASTM 963, contains no heavy metal, toxic elements or chemical substances damaging the ozone layer, and has the advantages of ultraviolet (UV) radiation resistance, mechanical performance against thermal and cold shocks and excellent pigmenting property.

Description

technical field [0001] The invention relates to a modified environment-friendly polyolefin material and a manufacturing method thereof. Background technique [0002] Existing products made of polypropylene resin or polyethylene resin are all injection molded with pure polypropylene resin or polyethylene resin. , The mechanical properties and degradability of resisting cold and heat shock are not very good, especially as people pay more and more attention to environmental protection, the requirements for the degradation performance of plastic products are getting higher and higher. Therefore, the traditional polypropylene resin or polyethylene resin products are increasingly subject to market and government restrictions. Although there are some degradable polypropylene resin or polyethylene resin products at present, they have not been widely promoted and applied because their degradability and other performances are not very satisfactory. Contents of the invention [000...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L97/02C08K3/26B29B9/12B29C47/92B29C48/92
CPCB29B7/002B29B7/46B29B7/92B29B9/06B29B9/14B29C48/0022B29C48/04B29C48/40B29C48/92B29C2948/92704B29C2948/92895
Inventor 罗世平
Owner 鹏马环保塑料有限公司
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