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Pelletizing method of ilmenite concentrates and pellet binder

A technology of titanium concentrate and binder, which is applied in the field of titanium metallurgy, can solve the problems of large height difference in material transportation, affecting the quality of titanium slag products, and the method of pelletizing not meeting the requirements of indicators.

Inactive Publication Date: 2010-02-17
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the binder introduces MgO and CaO impurities, which affects the quality of titanium slag products, this binder is not suitable for pretreatment of fine-grained titanium concentrate for titanium slag smelting
Chinese patent CN1854226A discloses a binder for gas ash pelletizing, the binder includes CaO, MgO, SiO 2 and Al 2 o 3 and other components, the use of the binder introduced too much CaO, MgO, SiO 2 and Al 2 o 3 When used in titanium slag smelting, it will increase the consumption of reducing agent and reduce the grade of titanium slag, so it is not suitable for pretreatment of fine-grained titanium concentrate for titanium slag smelting
In this method, the temperature of green pellet roasting is too high, and the production cost of pellets is too high
[0009] In addition, the compressive strength of the pellets produced by the traditional grate machine-rotary kiln pelletizing method does not exceed 500N, and the pulverization rate of the pellets is above 9%. Generally, it is only suitable for the reduction of titanium concentrate and the power of the rotary kiln is 10MW. The following small electric furnace smelting titanium slag
However, during the smelting process of a large-scale titanium slag electric furnace with a power of not less than 20MW, the material transportation height difference is large (about 20m), and the furnace is under negative pressure (about -20Pa) during smelting. If there is too much powder, it will directly enter the dust collector. system, reducing titanium yield
To meet the working conditions of large-scale titanium slag electric furnace smelting, the strength of pellets must not be lower than 1200N, and the pulverization rate of pellets should not exceed 2%. Therefore, the traditional pelletizing method does not meet the index requirements of large-scale electric furnace smelting pellets.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The particle size distribution is shown in Table 1 and TiO 2 Add 600g of liquid binder (composed of polyacrylamide, sodium carboxymethylcellulose and water with a weight ratio of 15:10:100), 100g of starch, 1kg Anthracite, mixed in a wheel mill mixer for 20 minutes; then the mixed material was continuously briquetted on a 430-type high-pressure ore powder briquetting machine, the pressure of the briquetting machine was 20MPa, and the pressure holding time was 1 second to obtain a particle size of 20mm. ~60mm green pellets; send the green pellets to a GZΦ2200×12000 drum dryer with a heat source provided by electric furnace flue gas for drying, the drying temperature is 200°C, and the drying time is 120 minutes to obtain dry pellets. The compressive strength of the pellets is 1750N, and the crushing times of dropping from a height of 3m to a flat concrete floor is 12 times (1.2% powder is produced). The pellets can completely meet the smelting requirements of a large tit...

Embodiment 2

[0039] The particle size distribution is shown in Table 1 and TiO 2 Add 400g of liquid binder (composed of polyacrylamide, sodium carboxymethylcellulose and water with a weight ratio of 20:12:100), 100g of starch, and 1kg of titanium concentrate with a content of 46.44%. Anthracite, mixed in a wheel mill mixer for 20 minutes; then the mixed material was continuously briquetted on a 430-type high-pressure ore powder briquetting machine, the pressure of the briquetting machine was 18MPa, and the pressure holding time was 0.8 seconds to obtain a particle size of 20mm. ~60mm green pellets; send the green pellets to a GZΦ2200×12000 drum dryer with a heat source provided by electric furnace flue gas for drying, the drying temperature is 250°C, and the drying time is 160 minutes to obtain dry pellets. The compressive strength of the pellets is 1650N, and the crushing times of dropping from a height of 3m to a flat cement floor is 10 times (1.0% powder is produced). The pellets can c...

Embodiment 3

[0041] The particle size distribution is shown in Table 1 and TiO 2 Add 350g of liquid binder (composed of polyacrylamide, sodium carboxymethylcellulose and water with a weight ratio of 15:15:100), 75g of starch, and 1kg of titanium concentrate with a content of 46.44%. Anthracite, mixed in a wheel mill mixer for 20 minutes; then the mixed material was continuously briquetted on a 430-type high-pressure ore powder briquetting machine, the pressure of the briquetting machine was 15MPa, and the pressure holding time was 0.5 seconds to obtain a particle size of 20mm. ~60mm green pellets; send the green pellets to a GZΦ2200×12000 drum dryer with a heat source provided by electric furnace flue gas for drying, the drying temperature is 300°C, and the drying time is 180 minutes to obtain dry pellets. The compressive strength of the pellets was 1550N, and the crushing times of dropping from a height of 3m to a flat concrete floor was 6 times (1.6% powder was produced). The pellets ca...

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Abstract

The invention discloses a pelletizing method of ilmenite concentrates and a pellet binder, wherein the method comprises the following steps: uniformly mixing the ilmenite concentrates, the binder anda carbonaceous reducing agent to obtain a mixed material; pressing the mixed material into green pellets; and drying the green pellets to obtain the dry green pellets.

Description

technical field [0001] The invention relates to the field of titanium metallurgy, in particular to a pelletizing method of titanium concentrate and a pellet binder. Background technique [0002] Micro-grained titanium concentrate is prepared by a new flotation process, and its main component is TiO 2 , FeO, CaO, Al 2 o 3 and SiO 2 . The weight of particles with a particle size less than 0.075mm in a kind of fine-grained titanium concentrate used for smelting titanium slag accounts for 72.9% of the total weight. Table 1 shows the fine-grained titanium concentrate and a coarse-grained titanium concentrate. The particle size distribution of the ore. [0003] Table 1 Comparison table of particle size analysis of two different titanium concentrates [0004] Particle size range ≥0.150 [0.109,0.150) [0.075,0.109) [0.045,0.075) [0.038,0.045) <0.038 Coarse ore (%) 63.18 18.17 17.14 1.45 0.06 ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/244C22B34/12
Inventor 韩可喜胡鸿飞魏光亮黄北卫杨强杨仰军秦兴华程晓哲张继东梁从勇李开华赵青娥王斌马勇
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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