Additive for silicon nitride sintered bodies

A sintered body and additive technology, applied in the field of heating element additives, can solve the problems of high sintering temperature, increase the cost of sintering equipment, limit the mass production of sintered body, etc., and achieve the effect of improving refractoriness and mechanical properties

Inactive Publication Date: 2013-04-17
CHANGSHA SYNO THERM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The sintering temperature is high, and the heat-resistant specifications of the sintering furnace and its auxiliary devices need to be improved, which will greatly increase the cost of the sintering equipment. In addition, the high sintering temperature makes it difficult to use a continuous manufacturing process to prepare silicon nitride sintered bodies, which limits the sintered body. mass production
At present, there is no silicon nitride sintered body additive that can realize rapid sintering of silicon nitride sintered body under normal pressure or slightly positive pressure and under sintering conditions below 1500 °C

Method used

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  • Additive for silicon nitride sintered bodies
  • Additive for silicon nitride sintered bodies

Examples

Experimental program
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Effect test

Embodiment 1-10

[0033] The preparation method of embodiment 1-10:

[0034] (1) Raw material configuration: According to the ingredients in Table 1, add absolute ethanol and silicon nitride balls, ball mill for 1 hour, and dry under the protection of nitrogen.

[0035] (2) Green body preparation: Process the mold according to the shape requirements of the heating element (150mm×30mm×5mm), and prepare the green body by using dry powder compression molding.

[0036] (3) Microwave sintering process: the green body enters the microwave sintering furnace continuously, and is continuously sintered under the protection of flowing nitrogen. The sintering temperature of the furnace body is shown in Table 1, and the atmosphere in the furnace is 102,325-102500Pa flowing nitrogen. The green body is sintered in this temperature range and released after cooling.

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Abstract

The invention discloses an additive for silicon nitride sintered bodies, which is prepared from the following components by weight percent: 29.5-65.2 percent of sintering aid and 34.8-70.5 percent of activating composite oxide, wherein the activating composite oxide is a compound formed by combining lithium oxide (Li2O), yttrium oxide (Y2O3), silicon dioxide (SiO2) and aluminium-containing compound. After the additive is added into a silicon nitride sintered body, the inter-granular phase components of a silicon nitride heating element is changed, the refractoriness of the silicon nitride sintered body sintered at normal pressure is enhanced, the mechanical property of the heating element at high temperature is improved and a heating element of the silicon nitride sintered body with the use temperature of 1,200-1,400 DEG C is obtained, the thermoconductivity is 21-32 W*m <-1>*K<-1>, the linear expansibility is 3.1*10<-6>-3.8*10<-6> / DEG C(40-800DEG C) and the density is over 98 percent. The invention realizes the normal-pressure low-temperature rapid-firing sintering of the silicon nitride heating element.

Description

technical field [0001] The invention relates to a heating element additive for a silicon nitride sintered body. Background technique [0002] Silicon nitride is an atomic crystal compound composed of nitrogen and silicon through strong covalent bonds. The heat of formation is 733.6kJ / mol. Compared with the combination of two nitrogen atoms to form nitrogen (N 2 ) is much lower than the 941.69kJ / mol released, so even if the sintering temperature is reached under the condition of no sintering aid, α-silicon nitride will decompose to generate nitrogen and free silicon without sintering. In the prior art, the decomposition of silicon nitride is suppressed by applying pressure or adding sintering aids to realize sintering. Commonly added sintering aids are oxides of rare earth elements, such as yttrium oxide and lanthanum oxide, which can effectively prevent the decomposition of Si3N4 during sintering. [0003] CN1229829A discloses a silicon nitride heating element and its manu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/63C04B35/584
Inventor 彭虎刘建平
Owner CHANGSHA SYNO THERM
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