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A kind of preparation method of Gan-based LED chip

An LED chip, p-gan technology, applied in electrical components, circuits, semiconductor devices, etc., can solve problems such as poor P-type ohmic contact, increase series resistance, reduce device reliability, etc., to achieve good P-type ohmic contact, The effect of long device operating life and low forward operating voltage

Active Publication Date: 2011-12-28
XIAMEN TOP SUCCEED ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, so far, GaN-based LED devices still have many technical problems that have not been fully resolved. Among them, the most important problems restricting their development are the difficulty in achieving a high effective doping concentration of P-GaN and the preparation of a good P-type GaN ohmic contact. Difficult to wait
Generally, P-GaN doping of GaN-based LED epitaxial wafers is generally doped with Mg during MOCVD growth, and then activated by high-temperature annealing; or ion implantation high-temperature annealing, co-doping technology, etc.; but these technologies can do The P-type effective doping concentration of the GaN material is generally only 10 17 cm -3 magnitude
The P-type effective doping concentration of GaN materials is not high. The main reasons are as follows: when GaN is grown by MOCVD, the acceptor Mg easily forms an electrically neutral Mg-H complex with H, so that Mg cannot effectively It replaces Ga sites; secondly, N vacancies are easy to be generated when GaN is grown, and N vacancies are the donor source, so the GaN material is n-type without doping; in addition, the energy level of Mg in GaN materials is relatively deep, and generally the shallowest energy level also has about 170mev, difficult to ionize at room temperature
P-type effective doping concentration is not high, it is difficult to prepare a good P-type ohmic contact
For GaN-based LED devices, poor P-type ohmic contact increases the series resistance of the device
The higher P-type series resistance not only reduces the heat generation and carrier injection efficiency of the LED device, but also causes the device to generate heat during operation, reducing the luminous efficiency of the device and reducing the reliability of the device, thereby shortening the life of the device.

Method used

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  • A kind of preparation method of Gan-based LED chip
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  • A kind of preparation method of Gan-based LED chip

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Deposit a layer of Zn film with a thickness of 200nm on the surface of the cleaned conventional LED epitaxial wafer P-GaN by sputtering, and use an excimer laser with a wavelength of 248nm to irradiate the Zn / P-GaN surface of the sample in an atmospheric environment. The pulse frequency is 20Hz, the single pulse energy is 300mJ, and the irradiation time is 2.5s. The remaining Zn was etched away with dilute hydrochloric acid, rinsed and dried with deionized water. Perform ICP etching on the processed sample to expose the n-type GaN layer, photolithography and sputtering the Ti(60nm) / Al(2nm) metal layer, and form an n-type electrode after peeling off, annealing in a nitrogen atmosphere at 700°C for 2min; The sample was subjected to photolithography again and a Ni / Au metal layer was sputtered on the surface, and a p-type electrode was formed after peeling off, and annealed in a nitrogen atmosphere at 550°C for 2 minutes.

Embodiment 2

[0028] Deposit a layer of Zn film with a thickness of 300nm on the surface of the cleaned conventional LED epitaxial wafer P-GaN by sputtering, use a KrF excimer laser to irradiate the Zn / P-GaN surface of the sample in an atmospheric environment, and the pulse of the laser The frequency is 25Hz, the single pulse energy is 350mJ, and the irradiation time is 2s. The remaining Zn was etched away with dilute hydrochloric acid, rinsed and dried with deionized water. Perform ICP etching on the processed sample to expose the n-type GaN layer, photolithography and sputtering the Ti(60nm) / Al(2nm) metal layer, peel off to form an n-type electrode, and anneal in a nitrogen atmosphere at 600°C for 4 minutes; The sample was subjected to photolithography again and a Ni / Au metal layer was sputtered on the surface, and a p-type electrode was formed after peeling off, and annealed in a nitrogen atmosphere at 500°C for 3 minutes.

Embodiment 3

[0030]Deposit a layer of 100nm thick Zn film on the surface of the cleaned conventional LED epitaxial wafer P-GaN by sputtering, and use a KrF excimer laser to irradiate the Zn / P-GaN surface of the sample in an atmospheric environment. The frequency is 30Hz, the single pulse energy is 250mJ, and the irradiation time is 3s. The remaining Zn was etched away with dilute hydrochloric acid, rinsed and dried with deionized water. Perform ICP etching on the processed sample to expose the n-type GaN layer, photolithography and sputtering the Ti(60nm) / Al(2nm) metal layer, and form an n-type electrode after peeling off, annealing in a nitrogen atmosphere at 650°C for 5min; The sample was subjected to photolithography again and a Ni / Au metal layer was sputtered on the surface, and a p-type electrode was formed after peeling off, and annealed in a nitrogen atmosphere at 600°C for 2 minutes.

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Abstract

A method for preparing a GaN-based LED chip relates to an LED chip. The invention provides a method for preparing a GaN-based LED chip which not only has obvious effect, is easy to operate, is compatible with conventional device technology, but also has low series resistance and good P-type ohmic contact. Deposit a layer of metal Zn film on the surface of LED epitaxial wafer P-GaN by sputtering or evaporation; irradiate the Zn / P-GaN surface of the sample with a laser; etch away the remaining Zn on the surface of the sample, clean and dry; The processed sample is etched by ICP to expose the n-type GaN layer, photolithography and sputtering Ti / Al metal layer, after peeling off to form an n-type electrode, annealing; the sample is photolithography again and Ni / Au metal is sputtered on the surface Layer, after peeling off to form a p-type electrode, annealed.

Description

technical field [0001] The invention relates to an LED chip, in particular to a method for preparing a GaN-based LED chip by laser-induced doping Zn. Background technique [0002] GaN-based light-emitting diodes (LEDs) have been widely used in digital and image display fields due to their advantages in high efficiency, energy saving, and environmental protection. In recent years, due to breakthroughs in the research of GaN-based materials, high-efficiency white and blue LEDs have been developed, which can not only be used in the field of large-screen color display, but also have the potential to replace existing incandescent lamps, fluorescent lamps and other lighting projects. into people's lives. However, so far, GaN-based LED devices still have many technical problems that have not been fully resolved. Among them, the most important problems restricting their development are the difficulty in achieving a high effective doping concentration of P-GaN and the preparation of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L33/00
Inventor 陈朝薛正群黄生荣田洪涛
Owner XIAMEN TOP SUCCEED ELECTRONICS TECH