Catalyst for norbornene, maleic anhydride and acrylic ester ternary polymerization and preparation method of catalyst and ternary polymerization method

A technology of acrylate ternary and norbornene, which is applied in the field of polymer synthesis, can solve the problems of low copolymer yield, long reaction time, and few researches, and achieve high copolymer yield, cheap catalyst, and catalytic high efficiency effect

Inactive Publication Date: 2010-04-07
NINGBO UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These synthetic methods currently used have disadvantages such as long reaction time, low yield of copolymers, small molecular weight of copolymers, and low degree of alternation of copolymers, and domestic researches on the ternary copolymerization of norbornene, acrylate, and tetrafluoroethylene have been carried out a lot. few

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Example 1: Dissolve 0.01 mol of neodymium naphthenate in 20 ml of toluene, add 0.30 mol of 1-bromo-1-phenylethane to the above solution, keep the temperature in a water bath at 50°C for 30 minutes, and obtain rare earth after cooling. Complex catalyst.

Embodiment 2

[0018] Example 2: Dissolve 0.01 mol of neodymium naphthenate in 20 ml of cyclohexane, add 0.30 mol of 1-chloro-1-phenylethane to the above solution, and keep the temperature in a water bath at 50°C for 30 minutes. The rare earth complex catalyst is obtained.

Embodiment 3

[0019] Example 3: Dissolve 0.01 mol of neodymium naphthenate in 20 ml of benzene, add 0.20 mol of benzyl bromide to the above solution, and keep the temperature in a water bath at 50° C. for 30 minutes. After cooling, the rare earth complex catalyst is obtained.

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PUM

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Abstract

The invention relates to a catalyst for norbornene, maleic anhydride and acrylic ester ternary polymerization and a preparation method of the catalyst and a ternary polymerization method; the catalyst is prepared by rare-earth complex and halogenated hydrocarbon and can generate catalytic activity in a nitrogen protection system at normal pressure and at the temperature of 0-150 DEG C for catalyzing norbornene, maleic anhydride and acrylic ester ternary polymerization, and the products are soaked by methanol for easy washing and separation; the invention has the characteristics of high copolymer yield, low reaction temperature, cheap and easy-obtaining catalyst and high catalyst efficiency.

Description

Technical field [0001] The present invention relates to the field of polymer synthesis, and specifically refers to a catalyst for the ternary copolymerization of norbornene, maleic anhydride and acrylate, a method for preparing the catalyst, and the use of the catalyst to carry out norbornene, maleic anhydride and acrylic acid The method of ester copolymerization. Background technique [0002] Polynorbornene is a special polymer with excellent mechanical properties, heat resistance, solubility and transparency in organic solvents, and can be used for 193nm UV lithography. The main disadvantages of this material are brittleness, poor viscosity and low molecular weight. After inserting maleic anhydride into the polynorbornene main chain, the adhesion and solubility of the polymer can be improved, and the polymerization of acrylate can increase the toughness of the copolymer photolithography material. This terpolymer can be used as a photoresist material for 193nm photocopying tec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/10C08F222/06C08F232/08C08F4/12
Inventor 房江华杨建平胡敏杰高浩其陈斌王江波
Owner NINGBO UNIVERSITY OF TECHNOLOGY
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