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Precision injection molding polyamide composite and preparation method thereof

A composite material, injection molding technology, applied in the field of precision injection molding, can solve the problems of poor toughness, increased shrinkage, easy water break, etc., to achieve the effect of improving the bending elastic modulus, improving the thermal deformation temperature, and accelerating the crystallization rate

Inactive Publication Date: 2010-05-12
东莞市中洲石化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, general-purpose polyamide plastics, such as: nylon 6 (PA6) and nylon 66 (PA66), etc., during processing, due to the high crystallinity of polyamide plastics, the crystallization speed is slow, the cooling time is long, the shrinkage rate changes greatly, and the demoulding Defects such as difficulties
If the polyamide plastic reinforced with glass fiber is cooled for a long time during the molding process, it will completely crystallize, and the crystallization will make the plastic brittle (decrease in impact resistance), poor toughness and poor ductility, and it will easily break the water outlet.
At the same time, due to the high crystallinity of crystalline polymers, the volume change after cooling is large, so the shrinkage increases, resulting in difficulty in demoulding, and it is impossible to inject a batch of small precision plastic castings at one time.

Method used

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  • Precision injection molding polyamide composite and preparation method thereof
  • Precision injection molding polyamide composite and preparation method thereof
  • Precision injection molding polyamide composite and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Example 1 A precision injection molding grade polyamide composite material, containing components and the weight percentage of each component is: PA6 or PA66 49.4%; E-type glass fiber 50%; nucleating agent 0.2%; flow agent 0.2%; The oxygen agent is 0.2%, wherein the nucleating agent is calcium salt of carboxylate with long carbon chain as the main component; the flow agent is an optimized mixture of copolymer and montanic acid derivative; the antioxidant is inorganic phosphate.

[0038] The preparation method of the above-mentioned precision injection molding grade polyamide composite material is as follows:

[0039] (1) Take PA6 or PA66, put it into a high-speed mixer and mix well;

[0040] (2) Get nucleating agent, flow agent and antioxidant and step (1) gained nylon material and put into general mixer and stir;

[0041] (3) Put the mixture obtained in step (2) into the screw machine, add E-type glass fiber at the same time, mix it, and melt it at a temperature of 25...

Embodiment 2

[0043] Example 2 A precision injection molding grade polyamide composite material, containing components and the weight percentage of each component is: PA6 or PA66 54.4%; E-type glass fiber 45%; nucleating agent Licomont CaV102 0.2%; flow agent BRUGGOLEN P12 0.2%; antioxidant BRUGGOLEN H10 0.2%.

[0044] Its preparation method is with embodiment 1

Embodiment 3

[0045] Example 3 A precision injection molding polyamide composite material, containing components and the weight percentage of each component: PA6 or PA66 52%; E-type glass fiber 47.4%; nucleating agent CaV102 0.2%; flow agent BRUGGOLENP12 0.2%; Antioxidant BRUGGOLEN H10 0.2%.

[0046] Its preparation method is with embodiment 1

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Abstract

The invention provides a precision injection molding polyamide composite, which comprises the following components in percentage by weight: PA6 or PA66 40-60, E-type glass fiber 40-55, nucleating agent 0.1-0.3, flowable agent 0.1-0.3 and antioxidant 0.1-0.3, wherein the nucleating agent is calcium carboxylate of which the main ingredients are long carbon chains; the flowable agent is an optimized mixture of copolymers and montanic acid derivatives; and the antioxidant is an inorganic phosphate. The polyamide composite provided by the invention has the advantages that: a batch of small precision plastic injection-molded parts can be molded by the pin-hole injection at one time; degating is avoided and demolding is easy; meanwhile, the physical properties such as thermal deformation temperature, rigidity and transparency are improved and the dynamic performance such as elasticity bending modulus and impact strength is also improved.

Description

technical field [0001] The invention relates to the technical field of precision injection molding, in particular to a precision injection-grade polyamide composite material and a preparation method thereof, which is specially used for preparing small-scale precision injection castings in the fields of electronics and communications. Background technique [0002] Most of the plastic electronic components are injection molded. In recent years, with the rapid development of electronics, communications and other industries, people's requirements for high precision and high performance of small precision plastic castings are increasing day by day. The traditional plastic molding process has been difficult to meet the current high requirements. According to the requirements of the standard, precision injection molding technology must be used. [0003] Precision injection molding requires that the product not only has high dimensional accuracy, low warpage deformation, excellent t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08L101/00C08K7/14C08K5/098
Inventor 刘德平刘幸平周桂明朱德洲刘崇武刘崇文李锋杨席兵
Owner 东莞市中洲石化有限公司
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