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Polyester hot melt adhesive used for back glue of carpet and preparation method thereof

A technology of polyester hot-melt adhesive and carpet adhesive, which is applied in the fields of adhesives, textiles, papermaking, and fiber processing, etc. It can solve the problems of few types of hot-melt adhesives, improve toughness and dry-cleaning resistance, low melt viscosity, and improve Effects of Surface Affinity and Operability

Inactive Publication Date: 2010-06-16
KUNSHAN TIANYANG HOT MELT ADHESIVE CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But at present special-purpose carpet back glue hot melt adhesive kind is less, for this reason the present invention proposes a kind of carpet back glue polyester hot melt adhesive and preparation method thereof, to meet market demand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] In a 1.0L polymerization reactor with a distillation device, add dimethyl terephthalate (100.9g), 1,4-butanediol (60g), bisphenol A (66.2g), catalyst tetraethyl titanate Ester (0.012g), heating, when the internal temperature reaches 150°C, the material starts to melt, and then starts to stir; when the temperature rises to about 179°C, methanol begins to distill out, continue to heat up until the internal temperature reaches 195-198°C, wait for the distillation When the methyl alcohol reaches 90% of the theoretical amount, the transesterification reaction ends.

[0021] Add isophthalic acid (43.2g) and adipic acid (7.6g) to the above reactant, and then stir to raise the temperature. When the internal temperature rises to about 190°C, water begins to distill out, and the temperature is gradually raised to 215°C. After the distillate amount reaches 89% of the theoretical value, continue to heat up. When the internal temperature reaches 230°C, to further distill off the oli...

Embodiment 2

[0024] In a 1.0L polymerization reactor with a distillation device, add dimethyl terephthalate (100.9g), 1,4-butanediol (51.8g), bisphenol A (80.2g), catalyst tetratitanate Propyl ester (0.0426g), heating, when the internal temperature reaches 150°C, the material begins to melt, and then starts to stir; when the temperature rises to about 173°C, methanol begins to distill, continue to heat up until the internal temperature reaches 198-202°C, and wait for distillation When the methanol produced reached 88% of the theoretical amount, the transesterification reaction ended.

[0025] Add isophthalic acid (51.8g) and succinic acid (5.5g) to the above reactant, then stir and heat up. When the internal temperature rises to about 198°C, water begins to distill out, gradually warming up to 210°C, water After the distillate amount reaches 88% of the theoretical value, continue to heat up. When the internal temperature reaches 245 ° C, to further distill off the oligomers and excess alco...

Embodiment 3

[0028] In a 1.0L polymerization reactor with a distillation device, add dimethyl terephthalate (100.9g), 1,4-butanediol (51.8g), bisphenol A (63.2g), catalyst tetratitanate Butyl ester (0.044g), heating, when the internal temperature reaches 150°C, the material starts to melt, and then starts to stir; when the temperature rises to about 170°C, the methanol begins to distill, continue to heat up until the internal temperature reaches 190-195°C, and wait for distillation When the methanol produced reached 92% of the theoretical amount, the transesterification reaction ended.

[0029] Add isophthalic acid (56.1g) and adipic acid (14.8g) to the above reactant, then stir and heat up. When the internal temperature rises to about 203°C, water begins to distill out, and continue to heat up to 210°C. After the distillate amount reaches 88% of the theoretical value, continue to heat up. When the internal temperature reaches 218° C., to further distill off the oligomers and excess alcoho...

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Abstract

The invention provides a polyarylester hot melt adhesive used for back glue of a carpet and a preparation method thereof. The preparation method comprises the following steps of: (1) carrying out an ester exchange reaction on dimethyl terephthalate, bisphenol A and 1,4-butanediol under the action of a titanium series catalyst; (2) adding m-phthalic acid, aliphatic dicarboxylic acid and a stabilizing agent into a product in the step (1), then decompressing and carrying out copolycondensation to obtain a copolymer; and (3) adding a mixture of a right amount of LDPE (Low-Density Polyethylene) and butyl rubber into a product in the step (2) and modifying the copolymer to obtain a target product. The obtained polyarylester hot melt adhesive has the advantages of low melting viscosity, large bonding strength, water washing resistance and dry cleaning resistance, can be used as the back glue of carpets of various materials and is especially suitable for bonding chinlon and polypropylene fiber carpets.

Description

technical field [0001] The invention relates to a polyester hot-melt adhesive for carpet back glue and a manufacturing method thereof, in particular to a manufacturing method of a polyester hot-melt adhesive based on organic polymer synthesis. Background technique [0002] Known carpet back glue adopts the form of latex mostly at present, as Chinese patent CN107193 has invented a kind of copolymer latex, can be used as coating composition; The preparation method, the compound can be used as a carpet back glue by adopting dibasic acid Chinese patent CN1078987 to invent a polyvinyl acetal-modified acrylic resin-vinyl acetate resin composite emulsion. U.S. Patent US2009022936 also invented a kind of butyl rubber emulsion as carpet back glue. However, since latex contains a lot of water, it takes a long period from glue application to product molding. If hot-melt adhesive is used instead of latex, this cycle will be greatly shortened. US Patent US2008196813 has invented a meth...

Claims

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Application Information

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IPC IPC(8): C09J167/02C09J123/22C09J123/20D06M15/507
Inventor 李哲龙朱万育韩涛马志艳陶思玉
Owner KUNSHAN TIANYANG HOT MELT ADHESIVE CO LTD