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Packaging structural element of dye-sensitized cell and packaging method thereof

The invention relates to a dye-sensitized battery and packaging method technology, which is applied to the packaging structure and packaging field of dye-sensitized batteries, and can solve the problems of poor lamination process stability and uniformity of sarin film, difficulty in ensuring packaging uniformity with glass paste, Problems such as poor stability of sarin film packaging process

Active Publication Date: 2010-07-21
ENN SCI & TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Disadvantages of the encapsulation process of the patent CN101515509A: the stability of the sarin film encapsulation process is poor, and it is very easy to cause encapsulation failure in the case of contact with the electrolyte, resulting in electrolyte leakage and battery failure
In addition, sarin film is expensive (such as Surlyn1702 heat-sealing film is about 1,000 yuan / square meter), and the cutting and laying process of surlyn film is not suitable for automatic production. In addition, the lamination process of surlyn film has relatively low stability and uniformity. Poor, not conducive to industrial production
[0007] Disadvantages of the packaging process of the patent CN101354970A: it is difficult to ensure the tightness of each contact point during the sintering of the glass paste, because it is difficult to maintain a uniform thickness of the glass paste after screen printing, and it is easy to apply pressure on the glass during the sintering process. cause glass to deform
In addition, there are also a small number of holes after the glass paste is sintered, which easily leads to leakage and volatilization of the electrolyte
[0008] It can be seen that the prior art is generally a single-layer encapsulation structure on the conductive electrode. Some use Surlyn1702 heat-sealing film alone, some use glass paste alone, and some use special adhesive alone, but the prior art exists certain shortcomings
For example, Surlyn1702 heat-sealing film has disadvantages such as poor stability and solvent resistance, difficulty in automation, and high cost; glass paste has disadvantages such as difficulty in ensuring the uniformity of packaging, and some upper and lower packaging points cannot be in good contact, which leads to electrolyte leakage
The disadvantage of easy short circuit when using adhesive alone is that the adhesive is easily deformed under high temperature and pressure, so that the adhesive layer becomes thinner, resulting in a contact point between the photoanode and the conductive electrode on the counter electrode, resulting in short circuit

Method used

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  • Packaging structural element of dye-sensitized cell and packaging method thereof
  • Packaging structural element of dye-sensitized cell and packaging method thereof
  • Packaging structural element of dye-sensitized cell and packaging method thereof

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preparation example Construction

[0046] The preparation method of the packaging structure of the dye-sensitized battery of the present invention is described below. The packaging structure of the present invention is a packaging structure of two or more layers combined, which at least includes a layer covering the conductive electrode (5) A hard insulating layer (6) on the surface and an adhesive bonding layer (7) covering the surface of the hard insulating layer (6). The packaging structure in which the hard insulating layer (6) and the adhesive adhesive layer (7) covering the hard insulating layer (6) are combined is a kind of packaging structure that can effectively prevent battery Short-circuited packaging structure, because the adhesive is deformed under high temperature and pressure, the adhesive bonding layer is thinned, but the introduction of a hard insulating layer can effectively prevent the contact point between the photoanode and the conductive electrode on the counter electrode, thereby Prevent ...

Embodiment 1

[0082] The conductive electrode 5 is a silver electrode, and the hard insulating layer 6 is TiO 2 slurry, and when the hard insulating layer 6 is not sintered, the adhesive layer 7 is an adhesive layer formed by a common solvent-resistant thermal adhesive, such as JELCON AD-HM6 ink. The specific implementation method is:

[0083] 1. In such as figure 1 On the photoanode assembly of the above-mentioned photoanode, the silver electrode 5 is covered with a layer of titanium dioxide slurry with a thickness of 9 microns by using a screen printing process, and dried at 125° C. for 8 minutes to obtain a hard insulating layer 6, that is, the following can be obtained: figure 2 The photoanode assembly shown. The mesh number of the wire mesh is 100 mesh.

[0084] 2. Next, use the screen printing process to print a layer of AD-HM6 ink adhesive layer with a thickness of 8 microns on the hard insulating layer 6, and cure it at 60°C for 2 minutes to obtain the adhesive adhesive layer 7,...

Embodiment 2

[0089] The conductive electrode 5 is (ACHESON) ED 581SS conductive carbon paste, and the hard insulating layer 6 is TiO 2 slurry, and when the hard insulating layer 6 is not sintered, the adhesive layer 7 is an adhesive layer formed by a common solvent-resistant thermal adhesive, such as JELCON AD-HM6 ink. The specific implementation method is:

[0090] 1. After adsorbing dyes such as Figure 5 On the photoanode assembly shown, use a screen printing process to print a layer of (ACHESON) ED 581SS conductive carbon paste with a thickness of 6 microns on the position of the conductive electrode, and cure it at 135°C for 60 minutes, and then you can get the following: figure 1 The photoanode assembly shown. Wherein the conductive electrode is ED 581SS conductive carbon paste. The number of wire mesh used is 200 mesh.

[0091] 2. Next, use the screen printing process to cover the conductive electrode with a layer of titanium dioxide slurry with a thickness of 9 microns as a har...

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Abstract

The invention discloses a packaging structural element of dye-sensitized cell and a packaging method for preparing the packaging structural element of dye-sensitized cell; the dye-sensitized cell comprises a photocathode component, a counter electrode component and an electrolyte (8) packaged together; the packaging structural element is characterized in that the packaging structural element combined with two or more layers is covered on the surface of the conductive electrode (5) in the photocathode component and / or the counter electrode component, wherein the packaging structural element combined with two or more layers at least comprises a rigid insulation layer (6) covered on the surface of the conductive electrode (5) and a binder bonding layer (7) covered on the surface of the rigid insulation layer (6). In the packaging structural element combined with two or more layers, the defects of material in the prior art are avoided, thereby solving the technical problem of short circuit due to the easily deforming of the bonding layer at high temperature and pressure which makes the bonding layer become thinner, and the conductive electrodes of the photocathode and the counter electrode have contact points.

Description

technical field [0001] The invention relates to a packaging structure and packaging method of a dye-sensitized battery, in particular to a packaging structure with a hard insulating layer covering the surface of a conductive electrode and an adhesive coating covering the surface of the hard insulating layer. This two-layer or multi-layer dye-sensitized battery packaging structure of the binder adhesive layer, and a preparation method related to such a dye-sensitized battery packaging structure. Background technique [0002] Energy shortage and environmental pollution are two major problems facing mankind at present. Traditional energy sources such as coal, oil and wood can only last for fifty to one hundred years at the current rate of consumption. In addition, the resulting environmental pollution is also threatening the earth on which human beings depend for survival. In the future that can be predicted by human beings, solar energy, as an inexhaustible clean energy sour...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/20H01G9/04H01M14/00H01L51/42H01L51/44H01L51/48
CPCH01G9/2059Y02E10/542H01G9/2077H01G9/2031
Inventor 丁天朋李晓洁赵云峰周祥勇赵伟
Owner ENN SCI & TECH DEV
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