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Method for producing paraxylene

A p-xylene and toluene technology, applied in the field of p-xylene production, can solve the problems of low concentration, high energy consumption, large circulation volume of xylene separation unit and isomerization unit, etc.

Active Publication Date: 2013-03-06
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The technical problem to be solved by the present invention is that in the production of p-xylene in the prior art, there are problems such as the low concentration of p-xylene in the mixed xylene, resulting in large circulation of xylene separation unit and isomerization unit, high energy consumption, etc., providing A new production method of p-xylene

Method used

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  • Method for producing paraxylene
  • Method for producing paraxylene
  • Method for producing paraxylene

Examples

Experimental program
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Effect test

Embodiment 1

[0026] according to figure 2 The process shown is based on the C in typical reformed depentanized oil 6 A~C 10 + The composition of various hydrocarbon substances is used as the basic data to investigate the ability of the present invention to produce p-xylene and benzene and the processing scale of each unit. The composition distribution of aromatics sent out from a typical reformer and the flow rate of each component used in this example are shown in Table 1.

[0027] The dealkylation process unit of C9 and above aromatics adopts a fixed-bed reactor filled with a β-zeolite catalyst containing 0.05% bismuth. The reaction conditions are: reaction temperature 385°C, pressure 3.0MPa, weight space velocity 2.0 hours -1 , a hydrogen / hydrocarbon molar ratio of 3.0. Aromatic raw materials are mixed with hydrogen and then passed through the catalyst bed from top to bottom for C 9 + A dealkylation reaction to produce benzene, toluene and C 8 a.

[0028] The toluene selective...

Embodiment 2

[0044] according to figure 2 The process shown is based on the C in typical reformed depentanized oil 6 A~C 10 + The composition of various hydrocarbon substances is used as the basic data to investigate the ability of the present invention to produce p-xylene and benzene and the processing scale of each unit. The composition distribution of aromatics sent out from a typical reformer and the flow rate of each component used in this example are shown in Table 1.

[0045] The dealkylation process unit of C9 and above aromatics uses a fixed-bed reactor filled with a hydrogen-type mordenite catalyst containing 0.10% bismuth. The reaction conditions are: reaction temperature 320°C, pressure 1.0MPa, weight space velocity 0.8 hours -1 , a hydrogen / hydrocarbon molar ratio of 2.0. Aromatic raw materials are mixed with hydrogen and then passed through the catalyst bed from top to bottom for C 9 + A dealkylation reaction to produce benzene, toluene and C 8 a.

[0046] The tolue...

Embodiment 3

[0056] according to figure 2 The process shown is based on the C in typical reformed depentanized oil 6 A~C 10 + The composition of various hydrocarbon substances is used as the basic data to investigate the ability of the present invention to produce p-xylene and benzene and the processing scale of each unit. The composition distribution of aromatics sent out from a typical reformer and the flow rate of each component used in this example are shown in Table 1.

[0057] The C9 and above aromatics dealkylation process unit adopts a fixed bed reactor, and the reactor is filled with a hydrogen-type MCM-22 zeolite catalyst containing 0.30% bismuth. The reaction conditions are: reaction temperature 460°C, pressure 41.0MPa, weight empty Speed ​​is 3.0 hours -1 , a hydrogen / hydrocarbon molar ratio of 8.0. Aromatic raw materials are mixed with hydrogen and then passed through the catalyst bed from top to bottom for C 9 + A dealkylation reaction to produce benzene, toluene and ...

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Abstract

The invention relates to a method for producing paraxylene, which manly solves the problems of low concentration of paraxylene in mixed xylene during paraxylene production, large circulating load of aromatic hydrocarbon treatment, strict requirements for raw reaction materials, high energy consumption and the like existing in the prior art. The method comprises the following steps of: separating mixed raw materials from a reforming unit; introducing separated C9 and heavier aromatic hydrocarbons into a C9 and heavier aromatic hydrocarbon dealkylation processing unit for a dealkylation reaction to produce a second part of benzene, a second part of methylbenzene and a second part of C8 aromatic hydrocarbon; introducing methylbenzene into a methylbenzene selective disproportionation processing unit for a selective disproportionation reaction of methylbenzene to produce a C8 aromatic hydrocarbon and benzene flow including paraxylene so as to obtain a third part of C8 aromatic hydrocarbon, a third part of methylbenzene and a third part of benzene; after mixing the low-concentration C8 aromatic hydrocarbon, introducing the mixture into a crystallization and separation unit to obtain C8 aromatic hydrocarbon including paraxylene with high concentration; and introducing the C8 aromatic hydrocarbon including paraxylene with high concentration into an absorption and separation unit to obtain the product of paraxylene. With the technical scheme, the invention well solves the problems and can be applied to the industrial production of paraxylene.

Description

technical field [0001] The invention relates to a method for producing p-xylene. Background technique [0002] P-xylene is one of the main basic organic raw materials in the petrochemical industry. It is widely used in many chemical production fields such as chemical fibers, synthetic resins, pesticides, medicines, and plastics. The typical production method of p-xylene is from the thermodynamically balanced xylene containing ethylbenzene, that is, C8 aromatics generated by catalytic reforming of naphtha, through multi-stage cryogenic crystallization separation or molecular sieve simulated moving bed adsorption separation (adsorption separation for short) Technology to separate p-xylene from a mixture of isomers with similar boiling points. For the treatment of ortho- and meta-xylene, C 8 A isomerization (referred to as isomerization) technology to isomerize it into p-xylene. In order to increase the production of p-xylene, the disproportionation of toluene or the disprop...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C15/08C07C4/12C07C5/52C07C7/12C07C7/14C07C7/00
Inventor 钟禄平肖剑杨卫胜郭艳姿张惠明
Owner CHINA PETROLEUM & CHEM CORP
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