Method for producing low-carbon olefins by using petroleum hydrocarbon

A technology of low-carbon olefins and petroleum hydrocarbons, which is applied in the petroleum industry, hydrocarbon cracking to produce hydrocarbons, and catalytic cracking. It can solve the problems of energy demand and low heat transfer efficiency, and achieve the goals of improving heat transfer effects, protecting the environment, and reducing costs. Effect

Inactive Publication Date: 2010-10-27
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The steam thermal cracking process currently used in industry and the naphtha fixed-bed catalytic cracking process under research face the problems of huge energy demand and low heat transfer efficiency of providing ultra-high temperature through external indirect heating.

Method used

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  • Method for producing low-carbon olefins by using petroleum hydrocarbon
  • Method for producing low-carbon olefins by using petroleum hydrocarbon
  • Method for producing low-carbon olefins by using petroleum hydrocarbon

Examples

Experimental program
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Effect test

Embodiment 1

[0052] The above-mentioned light naphtha (C 5 ~C 10 ) After being preheated to about 100℃ by a heat exchanger, it is mixed with water, hydrogen and oxygen and then enters the hydrogen combustion direct heating zone. The hydrogen combustion heating zone consists of a low-temperature hydrogen combustion reactor and two high-temperature hydrogen combustion reactors. The reaction conditions in the combustion heating zone are: weight hourly space velocity 4h -1 , The reaction pressure is 0.15MPa, and the weight ratio of water vapor to oil is 0.5. Low temperature hydrogen combustion reactor is equipped with hydrogen combustion Pt / Al 2 O 3 Catalyst (produced by Beijing Research Institute of Chemical Industry, brand BHO-L), the temperature of the stream leaving the low-temperature hydrogen combustion reactor is 150°C, and then enters the Pt / Al containing hydrogen combustion catalyst 2 O 3 The high-temperature hydrogen combustion reactor (produced by Beijing Research Institute of Chemical...

Embodiment 2

[0054] Except that the temperature of the stream leaving the hydrogen combustion reactor was changed to 650°C, low-carbon olefins were produced using the same method and conditions as in Example 1.

Embodiment 3

[0056] Except that the temperature of the stream leaving the hydrogen combustion reactor was changed to 600°C, low-carbon olefins were produced using the same method and conditions as in Example 1.

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Abstract

The invention discloses a method for producing low-carbon olefins by using petroleum hydrocarbon. The method comprises the following steps of: making a preheated petroleum hydrocarbon raw material contact a hydrogen combustion catalyst in a hydrogen combustion heating area to directly obtain heat, which is required by the dehydrogenization of the petroleum hydrocarbon, of a hydrogen combustion reaction; allowing the petroleum hydrocarbon to contact a dehydrogenization catalyst in a dehydrogenization area to obtain petroleum hydrocarbon material flow which contains unsaturated olefin compounds, wherein the conversion rate of a dehydrogenization reaction is at least 20 percent; and allowing the obtained petroleum hydrocarbon material flow which contains the unsaturated olefin compounds to contact an olefin cracking catalyst in an olefin cracking reaction area to obtain a petroleum hydrocarbon material flow which contains C2 to C9 olefins and separating the petroleum hydrocarbon material flow which contains C2 to C9 olefins to obtain low-carbon products. When the technical process of the invention is used for producing the low-carbon olefins, the heat transfer effect and the heat transfer efficiency are improved, the energy is saved, the environment is protected, the energy consumption in a separation process is reduced and the low-carbon olefin selectivity of the petroleum olefin raw materials is obviously improved.

Description

Technical field [0001] The present invention relates to a method for producing olefins from petroleum saturated hydrocarbons. More specifically, the present invention relates to a 4 -C 35 Saturated hydrocarbons are used as raw materials to produce low-carbon olefins, especially ethylene, propylene and butene. Background technique [0002] As we all know, the production of low-carbon olefins by cracking petroleum hydrocarbons is a high temperature and strong endothermic process. At present, the most common method for producing low-carbon olefins such as ethylene, propylene and butadiene from petroleum saturated hydrocarbons is steam cracking. About 99% of ethylene and more than 50% of propylene in the world are produced by this method. Since the production of steam cracking methods is currently operated under very harsh conditions, for example, the final temperature of the radiant section of the cracking furnace reaches or exceeds 1125°C, and the residence time of the material in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C4/06C07C11/04C07C11/06C07C11/08C10G11/20
Inventor 郝雪松张勇王国清张兆斌陈硕白杰
Owner CHINA PETROLEUM & CHEM CORP
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