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Process and device for integrally producing substitute natural gas by coal gasification and methanation

A technology for replacing natural gas and methanation catalysis, which is applied in the fields of gas fuel, production of combustible gas, granular/powder fuel gasification, etc. The effect of reducing methanation load, wide adaptability, and increasing flexibility

Inactive Publication Date: 2010-12-08
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The synthesis gas is used for methanation to produce substitute natural gas. Since coal gasification and methanation are separated, and methanation needs to be carried out in multiple stages, a large amount of reaction gas needs to be circulated, the equipment investment is large, the power consumption of the compressor is high, and the operating cost is much higher than that of Lugi Gasification technology, so the above-mentioned coal gasification technology is difficult to apply to coal-based natural gas production
[0008] To sum up, the Lurgi coal fixed-bed gasification technology, which is suitable for coal-to-substituting natural gas, is subject to various restrictions due to the difficulty in treating wastewater pollution and the high requirements of the fixed-bed technology itself on coal quality, while the widely popular Texaco water coal Slurry coal gasification technology, Shell pulverized coal gasification technology and similar and improved technologies, because the current methanation technology needs to be carried out in multiple stages and a large amount of circulating reaction gas, so the operating cost is too high and not economical

Method used

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  • Process and device for integrally producing substitute natural gas by coal gasification and methanation
  • Process and device for integrally producing substitute natural gas by coal gasification and methanation
  • Process and device for integrally producing substitute natural gas by coal gasification and methanation

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Embodiment 1

[0038] Embodiment 1 Integrated process and equipment based on coal water slurry gasification process

[0039] This embodiment provides a process and device for coal gasification and methanation integrated production of substitute natural gas based on a coal-water slurry gasification process (such as a Texaco coal-water slurry gasification process), such as figure 1 shown.

[0040] The integrated device provided in this embodiment includes a gasifier, a gas chiller, dust removal equipment, etc., wherein the gasifier used is a coal-water slurry entrained bed gasifier, and its lining is made of alumina, oxidized One or more refractory materials based on silicon, zirconia, etc., with the above-mentioned refractory material as the carrier, carrying nickel whose active component accounts for 5% of the total weight of the refractory material, and adding rare earth lanthanum as an auxiliary agent , the amount of which accounts for 2% of the total weight of the refractory material (ca...

Embodiment 2

[0044] Embodiment 2 Integrated process and equipment based on pulverized coal gasification process

[0045] This embodiment provides a process and device for the integrated production of natural gas by coal gasification and methanation based on a pulverized coal gasification process (such as Shell pulverized coal gasification process), such as figure 2 shown.

[0046] The integrated production device provided in this embodiment includes a gasifier, a gas cooler (located on the upper part of the gasifier), a dust filter (ceramic material, located on the top of the gasifier), a gas heat exchanger (connected with the dust filter) Connection), and subsequent dry dedusting equipment, wet scrubbing equipment, gas circulation equipment (used to transport the treated gas to the gas chiller and gas heat exchanger to cool the high-temperature syngas).

[0047] Among them, the methanation catalytic strengthening treatment of each equipment in the device can include the following three ...

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Abstract

The invention relates to a process and a device for integrally producing substitute natural gas by coal gasification and methanation, which comprises the following steps: manufacturing the raw material coal into pulverized coal or coal water slurry; feeding the raw materials into a gasification furnace for partial oxidation reaction to generate a gas mixture; and enabling the gas mixture to enter a subsequent device for processing to obtain the substitute natural gas, wherein the gasification furnace and / or the subsequent device are subject to methanation catalysis and strengthen process, and the gas mixture generates a methanation reaction in the gasification furnace and / or the subsequent device. The devices comprise the following equipments: the gasification furnace, a dust filter, a gas chiller and / or a coal gas heat exchanger, wherein one or more of the devices are subject to the methanation catalysis and the strengthen process. The process and the device for integrally producing the substitute natural gas through the coal gasification and methanation provided by the invention has high cost efficiency and competitiveness.

Description

technical field [0001] The invention relates to a production process and device for a substitute natural gas, in particular to a process and a device for integrated production of a substitute natural gas by coal gasification and methanation. Background technique [0002] In 2009, China's natural gas accounted for less than 5% of primary energy consumption, while developed countries had reached about 25%. China is a country rich in coal but short of oil and gas. The use of coal gasification and methanation to produce substitute natural gas has great market potential. Many large energy companies have set foot in the field of coal-based natural gas. [0003] Coal-to-natural gas technology traditionally uses coal gasification to generate CO and H 2 of syngas, which is then desulfurized and deCO 2 After that, CO and H 2 The methanation reaction, the CO and H 2 Convert to CH 4 and H 2 O, so as to realize the production of substitute natural gas. Both the Great Plains Corpor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L3/08C10J3/46C10J3/48C10J3/72C10J3/74C10J3/84
Inventor 周红军余长春周广林
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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