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Process for extracting potassium chloride from native sylvite ore

A technology of potassium halite and potassium chloride, which is applied in the field of extracting industrial and agricultural potassium chloride products that meet national standards, can solve the problems of inconvenient use of primary particles, poor product quality, and high energy consumption for grinding, and achieve large Large-scale industrial production, low production cost, and the effect of coarse grinding particle size

Inactive Publication Date: 2011-04-13
CHANGSHA DESIGN & RES INST OF CHEM IND MIN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, in the process of producing potassium chloride by flotation, there is a common problem of fine grinding particle size, which makes the grinding energy consumption high, and the product is inconvenient to use because the primary particles are relatively fine and easy to agglomerate and agglomerate. Flotation is an important development direction of the flotation process for the production of potassium chloride from potassium halite
[0005] However, the existing potassium halite coarse-grained flotation technology for producing potassium chloride has poor product quality and low potassium recovery rate, and there are no reports for production practice.

Method used

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  • Process for extracting potassium chloride from native sylvite ore
  • Process for extracting potassium chloride from native sylvite ore

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (1) Grind potassium halite (containing 42.92% KCl) to below -8 mesh (-2.35mm); Add collector octadecyl fatty amine 150 g / ton, auxiliary collector unsaturated aliphatic hydrocarbon (C 16 ) 1000 g / ton, add inhibitor carboxymethyl cellulose 100 g / ton at the same time, flotation time 3 minutes; Octyl fatty amine 100 g / t, auxiliary collector unsaturated aliphatic hydrocarbon (C 16 ) 500 g / t for slurry flotation, the flotation time is 2 minutes; for the selection without adding chemicals, the flotation time for the two selections is 2 minutes, the KCl content of the flotation concentrate is 95.84%, and the recovery rate is 91.82%. (4) Concentrate washing, according to flotation concentrate: flotation mother liquor: water (mass ratio) is 8:10:1, add washing medium to wash and filter, test results: Potassium chloride concentrate can be obtained, KCl content 97.84 %,K + The recovery rate is 97.14%.

Embodiment 2

[0020] (1) Grind potash halite (containing 40.75% KCl) to below -8 mesh (-2.35mm); Add collector cetyl fatty amine 150 g / ton, auxiliary collector unsaturated aliphatic hydrocarbon (C 14 ) 900 g / ton, and add inhibitor carboxyethyl cellulose 100 g / ton at the same time, and the flotation time is 3 minutes; Hexaalkyl fatty amine 100 g / t, auxiliary collector unsaturated aliphatic hydrocarbon (C 14 ) at 400 g / t for slurry flotation, the flotation time is 2 minutes; for selection without adding chemicals, the two selection flotation times are both 2 minutes, the KCl content of the flotation concentrate is 95.24%, and the recovery rate is 91.28%. (4) Concentrate washing, according to flotation concentrate: flotation mother liquor: water (mass ratio) is 8:10:1, add washing medium to wash and filter, test results: Potassium chloride concentrate can be obtained, KCl content 97.45 %,K + The recovery rate is 97.40%.

Embodiment 3

[0022] (1) Grind potash rock salt ore (containing 38.85% KCl) to below -8 mesh (-2.35mm); Add collector tetradecyl fatty amine 250 g / ton, auxiliary collector unsaturated aliphatic hydrocarbon (C 10 ) 1100 g / ton, add inhibitor hydroxymethyl cellulose 100 g / ton at the same time, flotation time 3 minutes; Dialkyl aliphatic amine 250 g / t, auxiliary collector unsaturated aliphatic hydrocarbon (C 8 ) 600 g / t for pulping flotation, the flotation time is 2 minutes; the selection does not add chemicals, the two selection flotation times are 2 minutes, the KCl content of the flotation concentrate is 96.10%, and the recovery rate is 90.98%. (4) Concentrate washing, according to flotation concentrate: flotation mother liquor: water (mass ratio) is 8:10:1, add washing medium to wash and filter, test results: Potassium chloride concentrate can be obtained, KCl content 97.95 %,K + The recovery rate is 97.23%.

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Abstract

The invention discloses a process for extracting potassium chloride from native sylvite ore, which comprises the following steps of: (1) crushing the ore: coarsely crushing the sylvite ore; (2) performing floatation: performing floatation in saturated motor solution at normal temperature and normal pressure, and adding an inhibitor modified cellulose, a collector alkyl fatty amine and an auxiliary collector unsaturated aliphatic hydrocarbon, wherein the floatation process comprises twice rougher floatation and twice concentration, and middlings in the concentration are sequentially returned for re-concentration; (3) dewatering and size mixing: dewatering products in a tank after primary rougher floatation and before secondary rougher floatation until the pulp concentration is 50 to 70 percent, and performing size mixing; and (4) washing concentrate: mixing washing water and a proper amount of floatation saturated mother solution, performing size mixing, washing and filtering on the floatation concentrate. The process ensures that the flow is reasonable, the selected granularity is high, the granularity of tailings is high, the ore is easy to dewater and convenient to refill, the energy consumption is low and the operation is simple, and is suitable for extracting a potassium chloride product used for agriculture and industry, which meets the national standard, from the native sylvite ore.

Description

technical field [0001] The invention relates to a process for extracting potassium chloride from potash halite ore, in particular to a process for extracting industrial and agricultural chlorinated chloride from primary potash halite ore through traditional positive flotation (coarse grain) Process for Potassium Products. Background technique [0002] Primary potassium halite is the main potassium-containing ore for the production of potassium chloride, and its main impurity is sodium chloride. The processing methods of this kind of ore at home and abroad mainly include dissolution crystallization method and flotation method. [0003] The dissolution crystallization method is to use the characteristics of different solubility of potassium chloride and sodium chloride in the solution at different temperatures to obtain potassium chloride by high-temperature dissolution and low-temperature crystallization separation. Well, the product has no chemical pollution. The disadvant...

Claims

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Application Information

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IPC IPC(8): B03D1/00B03D1/08B03B1/00
Inventor 季荣甘顺鹏黄银广汤建良郑贤福孙成高
Owner CHANGSHA DESIGN & RES INST OF CHEM IND MIN
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