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Resin composition for forming the adhesive layers of a multi-layer flexible printed circuit board

A technology of resin composition and printed circuit board, which is applied in the direction of printed circuit, printed circuit, printed circuit manufacturing, etc., can solve the problems of non-rigid mechanical strength, etc., and achieve the effect of suppressing defects and reducing thickness

Inactive Publication Date: 2011-05-04
MITSUI MINING & SMELTING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the resin layer formed by using this adhesive sheet has the problem of lack of rigidity, low mechanical strength and brittleness.

Method used

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  • Resin composition for forming the adhesive layers of a multi-layer flexible printed circuit board
  • Resin composition for forming the adhesive layers of a multi-layer flexible printed circuit board
  • Resin composition for forming the adhesive layers of a multi-layer flexible printed circuit board

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0087] When describing an Example, the synthesis example of two types of phosphorus-containing epoxy resins used in an Example is demonstrated.

[0088] The synthetic example of phosphorus-containing epoxy resin A: in the four-necked glass separable flask that is equipped with stirrer, thermometer, condensing tube, nitrogen introduction device, the 10-(2 of 5-dihydroxybenzene of packing into 324 parts by weight Base)-10H-9-oxa-10-phosphaphenanthrene-10-oxide (manufactured by HCA-HQ Sanko Co., Ltd.) and 300 parts by weight of ethyl cellosolve were heated and dissolved. 680 parts by weight of YDF-170 (bisphenol F-type epoxy resin, manufactured by Toto Chemical Co., Ltd.) was added, stirred while introducing nitrogen gas, and heated to 120° C. for mixing. 0.3 parts by weight of a triphenylphosphine reagent was added, and reacted at 160° C. for 4 hours. The epoxy equivalent of the obtained epoxy resin was 501 g / eq, and the phosphorus content rate was 3.1 weight%.

[0089] The sy...

Embodiment 2

[0106] In this embodiment 2, the resin composition described in the above table 1 is adopted, and the resin composition is prepared according to the compounding ratio recorded in table 3, to replace the resin composition of embodiment 1, and then dimethylacetamide is used as solvent, the following resin varnishes were formulated. Others are the same as in Example 1.

[0107] table 3

[0108]

[0109] Next, a resin-coated copper foil was manufactured in the same manner as in Example 1, and the evaluation of the multilayer printed wiring board and the evaluation of the flexibility after the resin layer was cured were performed in the same manner as in Example 1. These evaluation results are shown in Table 5 below to enable comparison with Comparative Examples.

Embodiment 3

[0111] In this embodiment 3, the resin composition described in the above table 1 is adopted, and the resin composition is prepared according to the compounding ratio recorded in table 4, to replace the resin composition of embodiment 1, and then dimethylacetamide is used as solvent, the following resin varnishes were formulated. Others are the same as in Example 1.

[0112] Table 4

[0113]

[0114] Next, a resin-coated copper foil was manufactured in the same manner as in Example 1, and the evaluation of the multilayer printed wiring board and the evaluation of the flexibility after the resin layer was cured were performed in the same manner as in Example 1. These evaluation results are shown in Table 7 below to enable comparison with Comparative Examples.

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Abstract

Provided is a resin composition with which the thickness of a multi-layer flexible printed circuit board can be reduced and resin layers having great flexibility can be formed without inconvenience in the lamination process. A resin composition for forming adhesive layers, which includes: component (A) (an epoxy resin comprising one or more bisphenol-based epoxy resins of epoxy equivalent below 200 which are liquid at room temperature), component (B) (a highly heat-resistant epoxy resin), component (C) (a phosphorus-containing fire-retardant epoxy resin), component (D) (a rubber-modified polyamideimide resin which is soluble in solvents of boiling point from 50 DEG C to 200 DEG C) and component (E) (a resin hardening agent comprising one or more biphenyl-type phenolic resins and / or phenolaralkyl-type phenolic resins) is used in the adhesive layer to bond an outer printed circuit board layer to the surface of an inner flexible printed circuit board layer. A resin-coated copper foil or the like on which a resin layer has been formed with this resin composition is used.

Description

technical field [0001] The invention proposed in this application relates to a resin composition for forming an adhesive layer of a multilayer flexible printed circuit board, a resin varnish obtained from the resin composition, a resin-coated copper foil having a resin layer formed of the resin varnish, The manufacturing method of the copper foil with resin and the multilayer flexible printed circuit board. Background technique [0002] In recent years, the demand for higher performance and miniaturization of electronic devices has become prominent, and miniaturization of printed circuit boards used for supplying electronic signals has also been desired. Printed circuit boards can be roughly divided into plate-like rigid substrates and flexible printed circuit boards with flexibility. In this rigid wiring board, since it is easy to form multilayers, it is possible to realize miniaturization of the board size from an early stage. However, in recent years, since flexible pri...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H05K3/46C08G59/20C08L63/00C08L79/08H05K1/03H05K3/38
CPCC09J163/00C08G73/14C08L63/00C08L79/08C08L2203/20C08L2666/20C08L2666/22C09J179/08H05K1/0393H05K3/386H05K3/4635H05K3/4652H05K3/4655H05K2201/012H05K2201/0154H05K2201/0358
Inventor 佐藤哲朗松岛敏文白井武志
Owner MITSUI MINING & SMELTING CO LTD