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Laser-marked and halogen-free flame-retardant polyamide composite material

A flame retardant polyamide and laser marking technology, which is applied in the field of halogen-free flame retardant polyamide composite materials and can be laser marked, can solve the problem of lack of clear laser marking ability, flame retardant performance that does not meet the requirements of use, and long-term durability. Can not meet and other problems, to achieve the effect of convenient laser marking, clear marking and high processing efficiency

Active Publication Date: 2013-10-30
BENSONG ENG PLASTICS HANGZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its shortcomings: First, although the polyamide itself has self-extinguishing properties, the flame retardant performance cannot meet the requirements for use; second, the halogen-containing flame retardant is added to the polyamide, and the halogen-containing flame retardant released when the halogen-containing flame retardant burns Compounds not only cause harm to people, but also directly pollute the environment; third, they do not have the ability to clearly laser mark, so the current common practice is to use silk screen printing, ink spraying, etc. to mark thermoplastic products to reflect relevant information, such as manufacturer , production date, shelf life, anti-counterfeiting marks, etc., but the screen printing method will inevitably cause mechanical damage to the product surface and even produce chemical effects. Although the surface printing technology such as ink spraying is clear, it has high impact on raw materials such as composite materials and inks. requirements, and its long-term durability cannot meet the requirements of users

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Embodiment 1: a laser-markable, halogen-free flame retardant polyamide composite material, comprising:

[0032] A) The amount of at least one polyamide resin is 25-80 parts, the preferred solution is about 45-75 parts or the sum of the amount of one or more polyamide resins, and the polyamide resin refers to nylon 6, nylon 66, or nylon 6 and nylon 66 blend; the melting temperature range of the polyamide resin is about 200~280℃, the more preferred melting temperature range is controlled at 220~270℃, and the relative viscosity range of the polyamide resin is preferably 2.15~280℃ 2.75.

[0033] B) At least one or several inorganic filler materials and the one or several inorganic filler materials and refers to one of glass fiber, talc, wollastonite, or a blend of two or three thereof.

[0034]C) At least one or more halogen-free flame retardants with flame retardant properties, and the one or more halogen-free flame retardants with flame retardant properties refer to phos...

Embodiment 1-1

[0037] Example 1-1: 50% by weight of nylon 66 (Pingdingshan Shenma: EPR27), 30% by weight of MPP (Melapur 200), 0.5% by weight of laser marking auxiliary (self-made), 0.25% by weight of N,N '-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine (provided by Zhongqing Chemical Industry Co., Ltd.), 0.25% by weight of tris[2.4-di-tert-butylphenyl] ] Phosphite (provided by Rianlong) and 0.3% by weight of pentaerythritol stearate were stirred in a high-speed mixer for 5 minutes, after mixing uniformly, put into a twin-screw extruder for extrusion and granulation, and add 20% by weight to the side feeder % short glass fiber (international composite alkali-free short glass fiber), the length-diameter ratio of the twin-screw extruder is 40:1, the screw speed is 265rpm / min, and the temperature of each zone of the screw is 260°C in the first zone and 260°C in the second zone. The second zone is 260°C, the third zone is 260°C, the fourth zone is 260°C, the fifth zone ...

Embodiment 1-2

[0038] Example 1-2: 35% by weight of nylon 66 (Pingdingshan Shenma: EPR27), 10% by weight of nylon 6 (1013B), 30% by weight of MPP (Melapur 200), 0.5% by weight of laser marking auxiliary ( Homemade), 0.25 wt% of N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine, 0.25 wt% of tris[2.4-di-tert. Butylphenyl] phosphite and 0.5% by weight of pentaerythritol stearate were stirred in a high-speed mixer for 5 minutes. After mixing uniformly, they were put into a twin-screw extruder for extrusion and granulation, and 25% by weight of Short glass fiber (international composite alkali-free short glass fiber), the length-diameter ratio of the twin-screw extruder is 40:1, the screw speed is 265rpm / min, and the temperature of each zone of the screw is 260°C in the first zone and 260°C in the second zone. 260°C, the third zone 260°C, the fourth zone 260°C, the fifth zone 255°C, the sixth zone 255°C, the seventh zone 255°C, the eighth zone 255°C, the ninth zone 255...

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Abstract

The invention relates to a laser-marked and halogen-free flame-retardant polyamide composite material with excellent flame-retardant property and laser marking effect. The polyamide composite material is characterized by comprising the following substances: at least one or more of polyamide resins, at least one or more of inorganic packing materials, at least one or more of halogen-free flame retardants which can provide the excellent flame-retardant property for the composite material, at least one or more of aids which can provide excellent laser marking for the composite material, and other unessential aids such as lubricants, antioxidants, pigments and the like. The composite material has the comprehensive performance of excellent temperature resistance, flame retardance, and dimensional stability, easiness of processing and molding and the like, and also has clear and attractive laser marking effect at the same time. The composite material is widely applied in the fields of household products, electronic appliances, laser handles and the like and has huge market prospect.

Description

technical field [0001] The invention relates to a laser-markable, halogen-free flame-retardant polyamide composite material with excellent flame-retardant properties and excellent laser-markable effect, belonging to the field of general engineering plastic polyamide composite material manufacturing. Background technique [0002] Polyamide resin is a thermoplastic general engineering plastic with excellent comprehensive properties. It has excellent temperature resistance. The thermal decomposition temperature is usually greater than 350 ° C. It can be used continuously under the conditions of 80 to 120 ° C. It has good tensile strength Strength, is the preferred material for mechanical parts, and also has excellent impact toughness, corrosion resistance to acids, alkalis, most inorganic salt solutions, halogenated alkanes, hydrocarbons, esters, ketones, etc. Excellent wear resistance, self-lubricating It can be widely used in functional components in the fields of electrical ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08L77/02C08L77/06C08K13/04C08K7/14C08K3/34C08K3/22
Inventor 丁广军曾湘云周永松陈光辉
Owner BENSONG ENG PLASTICS HANGZHOU
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