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Novel gas diffusion layer used for fuel cell, preparation and application

A gas diffusion layer and fuel cell technology, which is applied in the parts of fuel cells, fuel cells, electrical components, etc., can solve problems such as shortages, improve mass transfer and electrical conductivity, high-efficiency drainage and gas-conducting functions, and realize drainage. and the effect of air conduction

Inactive Publication Date: 2011-06-22
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be seen from the existing literature that the conventional gas diffusion layer preparation method is to simply mix and coat the above-mentioned two components of carbon powder and water-repellent agent on the diffusion layer support such as carbon paper. However, there is still a lack of systematic theoretical analysis on how the three components that constitute the gas diffusion layer should be distributed in space, and how to realize the three functions of water drainage, electrical conduction, and gas transmission.

Method used

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  • Novel gas diffusion layer used for fuel cell, preparation and application
  • Novel gas diffusion layer used for fuel cell, preparation and application
  • Novel gas diffusion layer used for fuel cell, preparation and application

Examples

Experimental program
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Effect test

Embodiment 1

[0031] Using ammonium carbonate as a pore-forming agent, the gas diffusion layer was prepared in five layers by one-sided leveling process, and the electrode was prepared by CCS method.

[0032] 1. Preparation of Diffusion Layer

[0033] (1) Ingredients and first application

[0034] (a) According to the carbon paper area, press 0.8mg carbon powder / cm 2 For carbon paper, weigh XC-72 carbon powder and place it in a beaker, add absolute ethanol at the rate of 70ml ethanol / g carbon powder, ultrasonically oscillate, and stir for one minute.

[0035] (b) According to carbon powder weight: PTFE dry weight = 1: 1.5, weigh 30% (wt.) water-repellent PTFE emulsion. Add dropwise into the feed liquid, ultrasonically oscillate, and stir for 2 minutes until the feed liquid becomes ink-like.

[0036] (c) According to carbon powder weight: pore-forming agent dry weight = 1:1.9, weigh the ammonium carbonate pore-forming agent sieved through 400 mesh and add it to the above-mentioned feed li...

Embodiment 2

[0054] Using ammonium oxalate as a pore-forming agent, the gas diffusion layer was prepared in five layers by one-sided leveling process, and the electrode was prepared by CCM method.

[0055] The preparation of the diffusion layer is the same as that in Example 1. Ammonium oxalate is used instead of ammonium carbonate as a pore-forming agent when preparing the leveling material of the gas diffusion layer. The preparation of the catalytic layer adopts the CCS method, and catalysts are prepared on both sides of the proton exchange membrane according to the known methods in the literature. To form an electrode, two prepared gas diffusion layers are sandwiched between the two sides of the CCS method electrode to assemble an MEA. This MEA is numbered B# and placed in a fuel cell evaluation device for testing.

Embodiment 3

[0057] Using ammonium chloride as pore-forming agent, the gas diffusion layer was prepared in five layers by one-side leveling process, and the electrode was prepared by CCS method.

[0058] The preparation method of the diffusion layer and the catalytic layer is the same as in Example 1, except that the pore-forming agent is changed to ammonium chloride.

[0059] The prepared two CCS method electrodes are sandwiched between the two sides of the proton exchange membrane to assemble the MEA. This MEA is numbered C# and placed in the fuel cell evaluation device for testing.

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Abstract

The invention discloses a gas diffusion layer used for a fuel cell and a preparation method thereof. In a microscopic structure, the double-pore distribution of the diffusion layer is formed by nano-scale hydrophilic micropores and micron-sized hydrophobic macropores; and the structure contributes to that the gas diffusion layer has high-efficiency draining and air guiding functions at the same time. In macrocosmic, the porosity and the aperture of the diffusion layer are in anisotropic distribution on the whole of the diffusion layer; the diffusion layer is in asymmetric conical pore distribution in the direction vertical to the plane of the gas diffusion layer; the porosity and the aperture are decreased gradually from outside to inside; the inside is the side on which an attached catalyst layer is connected with the proton exchange membrane on the diffusion layer when in application; the porosity and the aperture of the diffusion layer are in uniform distribution in the direction parallel to the plane of the gas diffusion layer; and the distribution contributes to improving the mass transfer and the electrical conduction efficiency of the diffusion layer. The invention discloses a preparation technology for preparing micro-porous layers in layers by using pore-forming materials with different types and different grain diameters so as to realize the fuel cell gas diffusion layer of which the porosity and the aperture can be controlled accurately.

Description

technical field [0001] The invention proposes a novel gas diffusion layer for fuel cells and a preparation method. Microscopically, the diffusion layer structure consists of nm-level hydrophilic pores and um-level hydrophobic macropores to form a dual-pore distribution in the diffusion layer. This structure is conducive to realizing the efficient drainage and gas conduction functions of the gas diffusion layer. Macroscopically, the porosity and pore size of the gas diffusion layer present an anisotropic distribution on the whole, and this distribution can improve the mass transfer and conductivity efficiency of the diffusion layer. In the direction perpendicular to the proton exchange membrane, the diffusion layer has an asymmetric cone-shaped pore distribution and in a direction parallel to the proton exchange membrane, it has a uniform porous distribution. The invention discloses a preparation technology of a gas diffusion layer that uses different types and particle sizes ...

Claims

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Application Information

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IPC IPC(8): H01M8/02H01M4/88H01M4/98H01M8/0245
CPCY02E60/50
Inventor 董明全张华民邱艳玲马海鹏钟和香刘波
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI