Cement-based grouting material containing modified naphthalene-series water reducing agent and preparation method thereof

A naphthalene-based water-reducing agent and grouting material technology, which can be used in climate sustainability, sustainable waste treatment, solid waste management, etc., can solve the problems of small slump loss over time, etc. Value, strength and bleeding rate improvement, the effect of increasing the water reduction rate

Inactive Publication Date: 2011-10-12
马清浩
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is difficult for the existing naphthalene-based water reducers to have both high-efficiency water-r

Method used

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  • Cement-based grouting material containing modified naphthalene-series water reducing agent and preparation method thereof
  • Cement-based grouting material containing modified naphthalene-series water reducing agent and preparation method thereof
  • Cement-based grouting material containing modified naphthalene-series water reducing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation Embodiment 1

[0027] Preparation of material A

[0028] Put 1400Kg of naphthalene and 200Kg of anthracene into the melting tank, melt and heat, when the temperature rises to about 90°C, press the molten naphthalene and anthracene into the sulfonation tank, keeping the pressure less than or equal to 0.1MPa. After heating the naphthalene and anthracene pressed into the sulfonation kettle to 130-135°C, add 1600Kg of concentrated sulfuric acid to carry out the sulfonation reaction for 3.5 hours. Then, add 1000Kg of water to carry out the hydrolysis reaction, when the acidity of the reaction system reaches about 28%, add 1000Kg of formaldehyde to carry out the condensation reaction, and the condensation reaction temperature is controlled at 100-110°C. After the condensation reaction was carried out for 3 hours, 1600 Kg of 50% sodium hydroxide aqueous solution was added for neutralization, so that the pH of the reaction system reached 8-10.

[0029] Preparation of material B

[0030]Add 3000kg ...

preparation Embodiment 2

[0033] Preparation of material A

[0034] The remaining steps are the same as in Preparation Example 1, except that 1400Kg of concentrated sulfuric acid is used for sulfonation.

[0035] Preparation of material B

[0036] Add 3000kg of water and about 300Kg of sodium hydroxide into the reaction kettle, stir evenly, add 600Kg of phenol, then continue stirring evenly, add 1000Kg of sulfamic acid, stir for 40 minutes, add 300Kg of formaldehyde dropwise into the reaction system and react for about 1 hour , add 450Kg p-aminobenzenesulfonic acid, then drop 700Kg formaldehyde into the reaction system, continue to react for half an hour, and obtain a liquid product. There is no need to provide external heat during the reaction process, only the heat generated by the reaction is collected and returned to the reactor through the circulation pipeline. After measurement, the molecular weight of the obtained condensation product is about 6200.

[0037] Mix material A and material B in a...

preparation Embodiment 3

[0039] Preparation of material A

[0040] Same as Preparation Example 1.

[0041] Preparation of material B

[0042] Add 3000kg of water and about 300Kg of sodium hydroxide into the reaction kettle, stir evenly, add 600Kg of phenol, then continue to stir evenly, add 1050Kg of sulfamic acid, stir for 40 minutes, add 350Kg of formaldehyde dropwise into the reaction system and react for about 1 hour , add 350Kg p-aminobenzenesulfonic acid, then drop 600Kg formaldehyde into the reaction system, continue to react for half an hour, and obtain a liquid product. There is no need to provide external heat during the reaction process, only the heat generated by the reaction is collected and returned to the reactor through the circulation pipeline. It is measured that the molecular weight of the obtained condensation product is about 6100.

[0043] Mix material A and material B in a ratio of 10:1.

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Abstract

The invention provides a cement-based grouting material containing a modified naphthalene-series water reducing agent and a preparation method thereof. The cement-based grouting material comprises the following components in parts by weight: 350-500 parts of cement clinker, 80-130 parts of pulverized fuel ash, 20-30 parts of expanding agent, 80-120 parts of gypsum, 1-2 parts of pH value regulating agent, 8-15 parts of polyester type carboxylic acid water reducing agent and 300-500 parts of quartz sand, wherein the water reducing agent consists of a material A and a material B; the material A is prepared from naphthalene, anthracene, concentrated sulfuric acid, formaldehyde, water and sodium hydroxide; the material B is prepared from phenyl hydroxide, sodium hydroxide, formaldehyde, sulfamic acid and para-aminobenzene sulfonic acid; and the weight ratio of the material A to the material B is (20:1)-(5:1). The grouting material has high strength and low bleeding rate; and the strength character of the grouting material is hardly influenced by sub-zero weather.

Description

technical field [0001] The invention relates to a building material and a preparation method thereof, in particular to a cement-based grouting material containing a modified naphthalene-based water reducer and a preparation method thereof. Background technique [0002] Due to its high brittleness, concrete structures often crack in engineering applications, and concrete cracks will lead to a decrease in water tightness and leakage of concrete structures, which in turn will affect the service life of the project. Therefore, in the construction and use stages, many projects such as water conservancy, railways, highways, bridges, etc. inevitably need grouting materials to repair and reinforce cracks. The installation of many large instruments also requires the use of high-performance grouting materials to fill the anchor bolts and the machine base or the joint between the steel structure and the foundation. [0003] There are many grouting materials commonly used for repairing...

Claims

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Application Information

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IPC IPC(8): C04B28/14C04B24/22C04B103/30C04B111/70
CPCC04B24/226C04B28/02Y02W30/91C04B14/06C04B18/08C04B22/0093C04B22/143C04B22/008C04B2103/302
Inventor 马清浩
Owner 马清浩
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