Broad-spectrum high-efficiency antibacterial masterbatch based on nano-cluster technology and preparation method thereof
An antibacterial masterbatch and nano-cluster technology, applied in the field of plastic masterbatch, can solve the problems of difficult dispersion, poor chemical stability, high temperature resistance, etc., and achieve the effects of uniform dispersion, good stability and excellent antibacterial properties.
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Embodiment 1
[0023] Embodiment 1: 10g of nanometer silver powder is dissolved in the mixed solution of 500ml n-hexane and xylene, the mass ratio of n-hexane and xylene is 1: 1, then add MFI and be 100g in the polypropylene chip of 25, reflux in wide mouth The device was heated to reflux at 130°C until dissolved, then the temperature was raised to 150°C to distill off the solvent, and after cooling, the solid was taken out and ground into powder. Afterwards, the powder and polypropylene powder are added to the twin-screw at a mass ratio of 1:100, blended, extruded, and pelletized at 190°C to obtain brightly colored polypropylene masterbatches.
Embodiment 2
[0024] Embodiment 2: Nano-silver powder 10g is dissolved in the mixed solution of 500ml toluene and xylene, the mass ratio of toluene and xylene is 2: 1, then add MFI and be 100g in the polypropylene chip of 20, in wide-mouth reflux device Heat to reflux at 130°C until dissolved, then raise the temperature to 150°C to distill off the solvent, take out the solid after cooling and grind it into powder. Afterwards, the powder and PET powder were added to the twin-screw at a mass ratio of 1:50, blended, extruded, and pelletized at 280°C to obtain bright-colored modified PET masterbatches.
Embodiment 3
[0025] Embodiment 3: the n-heptane solution of nano-silver, wherein containing the mixed solution of nano-silver 10g and 500ml n-hexane and sherwood oil, the mass ratio of n-hexane and sherwood oil is 1: 1, then adding MFI is 25 poly Take 200g of propylene slices, heat and reflux at 130°C in a wide-mouth reflux device until dissolved, then raise the temperature to 150°C to distill off the solvent, take out the solid after cooling, and grind it into powder. Afterwards, the powder and polyethylene powder are added to the twin-screw at a mass ratio of 1:100, blended, extruded, and pelletized at 185°C to obtain polyethylene masterbatches with bright colors.
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