Coloring composition for color filter, color filter, and color liquid crystal display element
A technology for coloring compositions and color filters, which can be applied to optical components, instruments, filters, etc., can solve problems such as pigment particleization, and achieve the effect of excellent storage stability
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[0197] Examples are given below to further specifically describe the embodiment of the present invention. However, the present invention is not limited to the following examples.
[0198]
Synthetic example 1
[0200] In a flask equipped with a stirring bar, 1.4 g of methacrylic acid (hereinafter referred to as "MA") and 5.6 g of methoxypolyethylene glycol monomethacrylate (PME-200, manufactured by NOF Corporation) were mixed. (hereinafter referred to as "PME-200"), 5.0 g of n-butyl methacrylate (hereinafter referred to as "nBMA"), 5.0 g of 2-ethylhexyl methacrylate (hereinafter referred to as "EHMA"), 1.7g of benzyl methacrylate (hereinafter referred to as "BzMA"), 7.8g of methyl methacrylate (hereinafter referred to as "MMA"), 303mg of 2,2'-azobisisobutyronitrile (hereinafter referred to as "AIBN") and 781 mg of pyrazole-1-dithiocarboxylate cyano(dimethyl)methyl ester were dissolved in 30 mL of toluene, and nitrogen bubbles were performed for 30 minutes. Thereafter, the reaction solution was stirred slowly to raise the temperature of the reaction solution to 60° C., and the temperature was maintained for 24 hours to perform living radical polymerization.
[0201] Next, 73 mg of AI...
Synthetic example 2
[0203] In a flask equipped with a stirring bar, 1.4 g of MA, 8.4 g of PME-200, 12.9 g of nBMA, 224 mg of AIBN, and 579 mg of pyrazole-1-dithiocarboxylate cyano(dimethyl)formazol The ester was dissolved in 30 mL of toluene and nitrogen bubbles were carried out for 30 minutes. Thereafter, the reaction solution was stirred slowly to raise the temperature of the reaction solution to 57° C., and the temperature was maintained for 34 hours to perform living radical polymerization.
[0204] Next, 277 mg of AIBN and 5.3 g of DAMA were dissolved in 20 mL of toluene, nitrogen substitution was performed for 30 minutes, the resulting solution was added to the above reaction solution, and living radical polymerization was performed at 57° C. for 34 hours. Then, the solvent was replaced with propylene glycol monomethyl ether acetate by concentration under reduced pressure, and the nonvolatile content was adjusted to 40% by mass. Thus, a block copolymer comprising an A block with repeating ...
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