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Micro-pulse sample injection device and method for measuring content of micro-cobalt in nickel matrix solution

A sampling device and cobalt content technology, applied in the field of chemical analysis, to achieve the effect of improving labor intensity of employees, good application value, and reducing labor intensity of employees

Active Publication Date: 2012-01-25
JINCHUAN GROUP LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is currently no micro pulse sampling device for measuring trace cobalt content in nickel matrix solution

Method used

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  • Micro-pulse sample injection device and method for measuring content of micro-cobalt in nickel matrix solution
  • Micro-pulse sample injection device and method for measuring content of micro-cobalt in nickel matrix solution
  • Micro-pulse sample injection device and method for measuring content of micro-cobalt in nickel matrix solution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Pipette 2.00mL cobalt standard storage solution (standard storage solution containing 1.00mg cobalt in 1.00mL solution) into a 200mL volumetric flask, dilute to the mark with water, shake well to obtain the first cobalt standard solution, 1mL of the first cobalt standard The solution contains 10.00μg cobalt; pipette 25.00mL of the first cobalt standard storage solution into a 1000mL volumetric flask, dilute to the mark with water, shake well to obtain the second cobalt standard solution, 1mL of the second cobalt standard solution contains 25.00μg Cobalt; take five 50mL volumetric flasks, add 30.00mL nickel matrix solution to be measured respectively in each volumetric flask, then, add 0.00mL the second cobalt standard solution that makes in the first volumetric flask, in the second Add 2.00mL of the second cobalt standard solution prepared in the first volumetric flask, add 5.00mL of the second cobalt standard solution in the third volumetric flask, add 10.00mL of the se...

Embodiment 2

[0067] Pipette 2.00mL cobalt standard storage solution (standard storage solution containing 1.00mg cobalt in 1.00mL solution) into a 200mL volumetric flask, dilute to the mark with water, shake well to obtain the first cobalt standard solution, 1mL of the first cobalt standard The solution contains 10.00μg cobalt; pipette 25.00mL of the first cobalt standard storage solution into a 1000mL volumetric flask, dilute to the mark with water, shake well to obtain the second cobalt standard solution, 1mL of the second cobalt standard solution contains 25.00μg Cobalt; take five 50mL volumetric flasks, add 30.00mL nickel matrix solution to be measured respectively in each volumetric flask, then, add 0.00mL the second cobalt standard solution that makes in the first volumetric flask, in the second Add 2.00mL of the second cobalt standard solution prepared in the first volumetric flask, add 5.00mL of the second cobalt standard solution in the third volumetric flask, add 10.00mL of the se...

Embodiment 3

[0071] Pipette 2.00mL cobalt standard storage solution (standard storage solution containing 1.00mg cobalt in 1.00mL solution) into a 200mL volumetric flask, dilute to the mark with water, shake well to obtain the first cobalt standard solution, 1mL of the first cobalt standard The solution contains 10.00μg cobalt; pipette 25.00mL of the first cobalt standard storage solution into a 1000mL volumetric flask, dilute to the mark with water, shake well to obtain the second cobalt standard solution, 1mL of the second cobalt standard solution contains 25.00μg Cobalt; take five 50mL volumetric flasks, add 30.00mL nickel matrix solution to be measured respectively in each volumetric flask, then, add 0.00mL the second cobalt standard solution that makes in the first volumetric flask, in the second Add 2.00mL of the second cobalt standard solution prepared in the first volumetric flask, add 5.00mL of the second cobalt standard solution in the third volumetric flask, add 10.00mL of the se...

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Abstract

The invention discloses a micro-pulse sample injection device and method for measuring content of micro-cobalt in a nickel matrix solution. The device comprises a sampling injector, a fog chamber and a sprayer provided with an air channel, wherein a nozzle is arranged at one end of the air channel; a sample injection pipe is arranged in the air channel; the sample injection pipe is communicated with a micro-pulse sample injector; and an auxiliary gas inlet, a gas inlet, a combustor and an effluent outlet are arranged on the sprayer. The method comprises the following steps: preparing a standard cobalt storage solution into a second standard cobalt solution; adding the same volume of to-be-measured nickel matrix solutions into five volumetric flasks, and then adding different volumes of second standard cobalt solutions, dropwise adding hydrogen peroxide and sodium dodecyl sulfate, and carrying out constant volume, and acquiring five standard solutions; injecting the standard solutions into the micro-pulse sampling device for combustion, treating absorbed signals by adopting a peak height method, drawing standard addition method calibration curves for the standard solutions, and measuring the concentration of the to-be-measured nickel matrix solution; and calculating the contents of the micro-cobalt in the nickel matrix solution. The method is simple and quick and can be used for greatly improving the measurement efficiency and accuracy.

Description

[0001] technical field [0002] The invention belongs to the technical field of chemical analysis, and relates to a device for measuring the content of trace elements in a nickel matrix solution, in particular to a micro pulse sampling device for measuring the content of trace cobalt in the nickel matrix solution. The invention also relates to a method for measuring trace elements in nickel matrix solution by using the micro pulse sampling device. Background technique [0003] A stable and reliable organic reagent extraction titration-visual colorimetric method is usually used to analyze and determine the content of cobalt in the nickel matrix solution. However, this method has the disadvantages of cumbersome operation, long process, high labor intensity for the operator, and pollution of the working environment by organic reagents. Pulse injection is an atomic absorption micro-sampling technique, which injects the test solution into the flame atomizer in a pulsed way inste...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/72
Inventor 王纪华王琳刘晓丽
Owner JINCHUAN GROUP LIMITED