Nickel-based tar reforming catalyst based on mesoporous zirconia carrier and preparation method thereof
A mesoporous zirconia and tar conversion technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem of low catalyst activity and inappropriate pore structure. , easy carbon deposition and other problems, to achieve the effect of superior catalytic activity, good tar catalytic conversion performance, and prevention of deactivation of carbon deposition
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[0020] Example 1
[0021] (1) Preparation of mesoporous zirconium-based molecular sieve carrier: Measure 4.55 g of zirconium sulfate (ZrSO 4 ·4H 2 O) and 1.5g of CTAB (hexadecyltrimethylammonium bromide) were dissolved in 60mL of deionized water, and stirred for 2h, then transferred to a stainless steel reactor lined with PTFE, and aged at 100℃ After 2 days, the white precipitate was obtained by filtration, dried in a common blast drying oven at 105°C for 5 hours, and then the dried powder was refluxed in a 0.5mol / L phosphoric acid solution for 8 hours; after filtration, the filter residue was placed in a common blast Drying in a drying oven at 105°C for 12h, and then roasting in a muffle furnace at 500°C (programmed temperature rise rate is 2°C / min, holding time is 3h) to obtain 1.6g of mesoporous ZrO 2 Carrier
[0022] (2) Load of active component NiO: According to the equal volume impregnation method, measure 0.07g of nickel nitrate (Ni(NO 3 ) 2 ·6H 2 O) Dissolve in 8g deionized...
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[0024] Example 2
[0025] (1) Preparation of mesoporous zirconium-based molecular sieve carrier: 1.6 g of mesoporous ZrO was prepared according to the method of step (1) in Example 1. 2 Carrier
[0026] (2) Load of active component NiO: According to the equal volume impregnation method, measure 0.21g of nickel nitrate (Ni(NO 3 ) 2 ·6H 2 O) Dissolve in 8g deionized water, add 1.6g mesoporous ZrO 2 The carrier was added to the above nickel nitrate solution, ultrasonically treated for 2 hours and left for 3 hours; then the above materials were placed in a common blast drying oven at 100°C for 4 hours, and in a muffle furnace at 550°C for 3 hours (programmed heating rate is 3°C / min , The holding time is 3h), the mesoporous NiO / ZrO is obtained 2 Composite catalyst, in which the content of NiO is 3.3%.
[0027] The performance of the above-mentioned catalyst was evaluated in the biomass pyrolysis gasification unit. When the catalytic reaction temperature is 500-1000℃, the tar conversion ef...
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[0028] Example 3
[0029] (1) Preparation of mesoporous zirconium-based molecular sieve carrier: Measure 4.55 g of zirconium sulfate (ZrSO 4 ·4H 2 O) and 1.5 g of CTAB (hexadecyl trimethyl ammonium bromide) were dissolved in 60 mL of deionized water and stirred for 3 hours, then transferred to a stainless steel reactor lined with polytetrafluoroethylene and aged at 90°C After 2 days, the white precipitate was obtained by filtration, and it was dried in an ordinary blast drying oven at 110°C for 3 hours, and then the dried powder was refluxed in a 1.0 mol / L phosphoric acid solution for 6 hours; after filtration, the residue was placed in ordinary blast Drying in a drying oven at 105°C for 12h, and then roasting in a muffle furnace at 500°C (programmed temperature rise rate is 2°C / min, holding time is 3h) to obtain 1.6g of mesoporous ZrO 2 Carrier
[0030] (2) Load of active component NiO: According to the equal volume impregnation method, measure 0.45g of nickel acetate (Ni(CH 3 COO...
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