Thermoplastic elastomer capable of coating and bonding with glass fibre filling reinforced nylon

A thermoplastic elastomer, nylon technology, applied in the field of thermoplastic elastomer and its preparation, can solve the problems of poor physical properties, reduced bonding effect, small application range, etc., achieves good mechanical properties and use properties, simple preparation method, and process short process effect

Active Publication Date: 2012-05-02
ZHEJIANG SHIP ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the thermoplastic elastomer material is firmly bonded to common nylon, since the tackifier in the elastomer has adopted at least one of nylon polymers and polar resins, if the tackifier adopts nylon polymers, However, there are no other ingredients in the material itself that increase the compatibility of nylon polymers and matrix resins in the formula

Method used

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  • Thermoplastic elastomer capable of coating and bonding with glass fibre filling reinforced nylon
  • Thermoplastic elastomer capable of coating and bonding with glass fibre filling reinforced nylon
  • Thermoplastic elastomer capable of coating and bonding with glass fibre filling reinforced nylon

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Elastomer A1 was prepared as follows:

[0039] 1. Take raw materials according to the weight percentage distribution ratio of Example 1 in Table 1;

[0040] 2. Put the matrix resin into the mixer, inject the softening plasticizer into the mixer through the spray device, spray and mix while spraying;

[0041] 3. After the softening plasticizer is completely absorbed by the matrix resin, add adhesion promoters, compatibilizers, mineral fillers, stabilizers, and lubricants and mix well;

[0042] 4. Put the mixed materials above into a twin-screw extruder to extrude and granulate. The temperature of the twin-screw extruder is set at 250°C, the feeding frequency is 20 Hz, and the speed of the main machine is 300 rpm.

[0043] Thermoplastic elastomer and high glass fiber filled nylon (25% glass fiber content) including bonding: uniformly spray a surface treatment agent on the predetermined bonding surface of nylon, and then complete the secondary injection molding process wi...

Embodiment 2-6

[0058] Elastomers A2-A6 and samples B2-B6 were prepared according to the method of Example 1 and the raw materials of Examples 2-6 in Table 1 and their percentages.

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PUM

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Abstract

The invention provides a thermoplastic elastomer capable of coating and bonding with a glass fibre filling reinforced nylon, comprising the following raw materials in percentages by weight: 20-40% of matrix resin, 5-45% of softened plasticizer, 15-30% of adhesion promoter, 0-30% of mineral filler, 15-35% of compatilizer, 0-1% of lubricant and 0-2% of stabilizer, wherein the adhesion promoter includes a first adhesion promoter and a second adhesion promoter; the first adhesion promoter is at least one of a polyamide thermosol and a nylon polymer; and the second adhesion promoter is a mixture of a thermoplastic polyurethane elastomer and a polyether block amide copolymer; meanwhile, the invention further provides a method for preparing the elastomer. The elastomer is far higher than contrast products in tensile strength at break, tensile elongation at break and peel strength. The elastomer of the invention has good mechanical property.

Description

technical field [0001] The invention belongs to the field of macromolecular materials, and relates to a thermoplastic elastomer which can be coated and bonded with glass fiber-filled and reinforced nylon and a preparation method thereof. Background technique [0002] Thermoplastic elastomer is a new type of material that combines the excellent properties of thermoplastics and rubber. It can be molded alone, or it can be firmly coated on PP by secondary injection molding or extruder co-extrusion without any binder. , PE, PS, ABS, PC and other plastic materials, so as to make the inner hard polymer skeleton, and the outer layer is a soft elastomer product. Therefore, it is widely used in the handles of households, toys, and various tools to achieve elastic, rigid, and non-slip handles, as well as the functions of heat insulation, shock absorption, damping, and insulation, which can relieve user fatigue. Due to the different raw material formulations and proportions of thermop...

Claims

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Application Information

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IPC IPC(8): C08L53/02C08L77/00C08L75/04C08L71/00C08L51/00C08L51/06B29B9/06B29C47/92B29C48/92
CPCB29B7/46B29B7/72B29B7/7461B29B7/90B29B9/06B29B9/12B29B9/14B29C48/04B29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 刘华胡建友余玲张煜杰张文阳
Owner ZHEJIANG SHIP ELECTRONICS TECH
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