The invention relates to a perfluorotributylamine preparation device and a perfluorotributylamine preparation process, and belongs to the field of perfluorotributylamine preparation and fluid working systems, in the process, the
mass ratio of
tributylamine to
hydrogen fluoride is (80-100) kg: (200-230) k, the
hydrogen fluoride is firstly added into an electrolytic bath, and then the
tributylamine is added; air in the electrolytic bath is replaced by
nitrogen before reaction, and the
nitrogen is subjected to primary mixing to prepare an
electrolyte; then low-
voltage current is conducted for an electrolytic replacement reaction, the reaction pressure is controlled to be 0.1-1.5 MPa, and the temperature is controlled to be-10 DEG C to 30 DEG C; the invention provides a perfluorotributylamine preparation method, by controlling the
reflux distribution and single circulation path of circulation liquid, products with large
specific gravity are prevented from being deposited in pipeline equipment, the reaction activity and the fluorination efficiency are improved, the conversion rate is improved, an electrolytic fluorination method is adopted, the reaction is mild and controllable, the process is simple, the efficiency is high, impurities are few, and the impurities are easy to separate, and the scheme further provides a perfluorotributylamine preparation device. The preparation method is adapted to the preparation process, and the crude perfluorotributylamine product with the purity of more than 80% is obtained under the conditions of simple reaction raw materials and simple and convenient reaction device.