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Lithium battery positive pole slurry containing Ketjen superconducting carbon black, as well as preparation method and application thereof

A technology of superconducting carbon black and positive electrode slurry, which is applied in the direction of battery electrodes, circuits, electrical components, etc., can solve the problem that the positive electrode sheet is easy to fall off, and achieve the effects of not easy to fall off, ensuring utilization rate, and good dispersion effect

Inactive Publication Date: 2012-05-16
SHANGHAI HUAMING HI TECH GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, if the traditional stirring method is adopted, that is, the powders such as conductive agent and active material are premixed, and then the binder solution is added to stir, so that the dried positive electrode sheet containing Ketjen superconducting carbon black is easy to fall off, so it is rarely used. Ketjen superconducting carbon black as conductive agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Weighing 15 parts by weight of polyvinylidene fluoride dissolved in 1030 parts by weight of N-methylpyrrolidone, weighing 3 parts by weight of Ketjen superconducting carbon black, and 80 parts by weight of lithium iron phosphate positive electrode active material;

[0038] Mix Ketjen superconducting carbon black and polyvinylidene fluoride solution, stir in a high-speed shear emulsifier at a speed of 3000 rpm for 0.2 hours; then add lithium iron phosphate positive electrode active material, and stir at a speed of 3000 rpm After 0.8 hours, the slurry was poured into a sand mill, the diameter of the grinding beads was 15mm, and the speed of 1500 rpm was ground for 0.5 hours to obtain the lithium-ion battery positive electrode slurry A.

[0039] In order to further illustrate the effect of the present invention, according to the above formula and method, the difference is that acetylene black is used instead of Ketjen superconducting carbon black to prepare comparative slur...

Embodiment 2

[0046] Weighing 10 parts by weight of polyvinylidene fluoride dissolved in 515 parts by weight of N-methylpyrrolidone, weighing 6 parts by weight of Ketjen superconducting carbon black, and 80 parts by weight of lithium iron phosphate positive electrode active material;

[0047] Mix Ketjen superconducting carbon black and polyvinylidene fluoride solution, stir in a high-speed shear emulsifier at a speed of 4000 rpm for 0.5 hours; then add lithium iron phosphate positive electrode active material, and stir at a speed of 4000 rpm After 1 hour, the slurry was poured into a sand mill, the diameter of the grinding beads was 20mm, and the lithium ion battery positive electrode slurry C was obtained by grinding at a speed of 2000 rpm for 0.8 hours.

[0048] In order to further illustrate the effect of the present invention, according to the formula and method of this example, the difference is that acetylene black is used instead of Ketjen superconducting carbon black to prepare compa...

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Abstract

The invention discloses lithium battery positive pole slurry containing Ketjen superconducting carbon black, as well as a preparation method and application thereof. The lithium battery positive pole slurry comprises the following components in parts by weight: 80 parts of lithium iron phosphate positive pole active material, 1-10 parts of Ketjen superconducting carbon black, 5-20 parts of polyvinylidene fluoride, and 500-1100 parts of N-methyl-2-pyrrolidone. The preparation method comprises the following steps of: mixing and dispersing the Ketjen superconducting carbon black and polyvinylidene fluoride bonder bonder, then adding the lithium iron phosphate positive pole active material, mixing and dispersing, pouring the slurry into a sand mill to be milled, and obtaining the lithium battery positive pole slurry containing the Ketjen superconducting carbon black. According to the invention, the problem that a pole piece is dropped off because the lithium battery positive pole slurry uses the Ketjen superconducting carbon black is solved, the dosage of conductive additive is small, the dried positive pole material is not easy to drop off, and the specific capacity of the lithium battery material is improved.

Description

technical field [0001] The invention relates to a lithium battery cathode slurry containing Ketjen superconducting carbon black, a preparation method and application thereof. Background technique [0002] Lithium-ion batteries have the characteristics of high energy, long life, low pollution, light weight, long life, and no memory effect, and are currently widely used as power sources for portable electronic devices. [0003] An important step in preparing the positive electrode of lithium-ion batteries is the preparation of positive electrode slurry, which is a complex system containing positive active materials, conductive agents, binders and solvents. The complex system of positive electrode slurry is in a metastable state, and abnormal phenomena such as flocculation, segregation, and precipitation are prone to occur. [0004] Most of the conductive agents used in the currently disclosed lithium ion positive electrode slurry use acetylene black or graphite, etc. Ketjen s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/1397
CPCY02E60/122Y02E60/10
Inventor 徐云龙张洁赵崇军钱秀珍马新胜吴秋芳
Owner SHANGHAI HUAMING HI TECH GRP
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