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Method for preparing organic titanium-plant vinegar potassium salt organic fertilizer through salting-out process

A technology for planting vinegar potassium salt and organic titanium, applied in the application, fertilization device, fertilizer mixture and other directions, can solve the problems of undiscovered, miscellaneous belt, etc., and achieve the effect of excellent stability

Inactive Publication Date: 2013-12-11
FUJIAN CHAODA GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0017] Above patent document discloses directly the chloride of water-soluble titanium, or the sulfate salt of titanium as the raw material of synthetic organic titanium citric acid chelate compound, the weak point of its existence is that in the organic titanium citric acid chelate synthesized Miscellaneous with a large number of chloride ions or sulfide ions
[0036] No reports of multifunctional organic fertilizers combining organic titanium and vegetable vinegar compound salts have been found; no reports have been found of using alkaline (pH ≥ 8) vegetable vinegar compound potassium salts as salt precipitation neutralizers to neutralize salt precipitation to prepare organic titanium- Report on Vegetable Vinegar Compound Potassium Salt Multifunctional Fertilizer

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] (1) Preparation of metatitanic acid:

[0064] a. Add 1000ml of ice water at 0°C~5°C to a 1500ml beaker, and add 10ml of hydrochloric acid and 20ml of titanium tetrachloride dropwise under the stirring of an electric stirrer to generate a titanium tetrachloride hydrochloric acid solution. The sodium hydroxide solution neutralizes the titanium tetrachloride hydrochloric acid solution, the temperature of the solution is controlled at ≤5°C, and the pH value is 7.0~8.0, so that metatitanic acid is precipitated in cold water at ≤5°C;

[0065] B, the newly precipitated metatitanic acid is washed with distilled water to remove chloride ions;

[0066] c. After the metatitanic acid that has been washed to remove chloride ions is removed by a centrifuge to remove part of the adsorbed water, it can be used for acid-soluble chelation.

[0067] (2) Preparation of titanium citrate chelate:

[0068] a. Preparation of citric acid-metatitanic acid suspension mixture:

[0069] The ti...

Embodiment 2

[0082] (1) Preparation of metatitanic acid:

[0083] a. Add 1000ml of ice water at 0°C~5°C to a 1500ml beaker, and add 10ml of hydrochloric acid and 20ml of titanium tetrachloride dropwise under the stirring of an electric stirrer to generate a titanium tetrachloride hydrochloric acid solution. The sodium hydroxide solution neutralizes the titanium tetrachloride hydrochloric acid solution, the temperature of the solution is controlled at ≤5°C, and the pH value is 7.0~8.0, so that metatitanic acid is precipitated in cold water at ≤5°C;

[0084] B, the newly precipitated metatitanic acid is washed with distilled water to remove chloride ions;

[0085] c. After the metatitanic acid that has been washed to remove chloride ions is removed by a centrifuge to remove part of the adsorbed water, it can be used for acid-soluble chelation.

[0086] (2) Preparation of titanium citrate chelate:

[0087] a. Preparation of citric acid-metatitanic acid suspension mixture:

[0088] The ti...

Embodiment 3

[0101] (1) Preparation of metatitanic acid:

[0102] a. Add 1000ml of ice water at 0°C~5°C to a 1500ml beaker, and add 10ml of hydrochloric acid and 20ml of titanium tetrachloride dropwise under the stirring of an electric stirrer to generate a titanium tetrachloride hydrochloric acid solution. The sodium hydroxide solution neutralizes the titanium tetrachloride hydrochloric acid solution, the temperature of the solution is controlled at ≤5°C, and the pH value is 7.0~8.0, so that metatitanic acid is precipitated in cold water at ≤5°C;

[0103] B, the newly precipitated metatitanic acid is washed with distilled water to remove chloride ions;

[0104] c. After the metatitanic acid that has been washed to remove chloride ions is removed by a centrifuge to remove part of the adsorbed water, it can be used for acid-soluble chelation.

[0105] (2) Preparation of titanium citrate chelate:

[0106] a. Preparation of citric acid-metatitanic acid suspension mixture:

[0107] The ti...

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Abstract

The invention relates to a method for preparing an organic titanium-plant vinegar potassium salt organic fertilizer through a salting-out process. The method is characterized by comprising the following steps of: preparing a newly precipitated metatitanic acid by neutralizing an iced solution of a titanium salt with an alkali; using the newly precipitated metatitanic acid to substitute chlorides and sulfates of titanium for being used as a raw material for synthesizing citric acid titanium; taking the newly precipitated metatitanic acid as a titanium source, taking citric acid as an acid solvent and a chelating agent, and synthesizing the citric acid titanium through a microwave hot-melting chelating process; and preparing the organic titanium-plant vinegar potassium salt organic fertilizer by performing neutralization and salting-out on a saturated solution of the citric acid titanium through alkaline plant vinegar compound potassium. According to the method disclosed by the invention, the citric acid titanium with excellent stability and water solubility, which is prepared by microwave hot-melting and full chelating, is taken as a synergist of a plant vinegar potassium organic fertilizer and a crop growth promoting agent.

Description

technical field [0001] The invention belongs to the technical field of fertilizers, and in particular relates to a method for manufacturing an organic titanium-vegetable vinegar potassium salt organic fertilizer. Background technique [0002] Fertilizer is a strategic material to ensure national food security, and the material basis for maintaining and improving soil fertility to achieve sustainable agricultural development. [0003] Chemical fertilizers are still an important means of production in agricultural production at present, and the absorption and utilization rate of chemical fertilizers in the soil by plants is very low. According to the measurement of my country's current comprehensive agricultural science and technology level, the utilization rate of agricultural crop fertilization in my country is only about 30%, causing a large number of Fertilizer loss and waste and environmental pollution. [0004] The research and development of new fertilizers with high ab...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G3/00
Inventor 徐福乐翁莹冰张美娟林秀翁仁发
Owner FUJIAN CHAODA GROUP
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